Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteries
Layered P2-type oxide compounds are an essential class of cathode materials for Na-ion batteries because of their superior capacity, average working potential, enhanced diffusivity of Na+ ions, and air stability compared to the O3-type oxides. Among the P2-type oxides, Na0.67Ni0.33Mn0.67O2 (NNMO) is...
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Elsevier
2025-07-01
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| Series: | Next Energy |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S2949821X25000869 |
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| author | Ananya Kumar Sreeraj Puravankara |
| author_facet | Ananya Kumar Sreeraj Puravankara |
| author_sort | Ananya Kumar |
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| description | Layered P2-type oxide compounds are an essential class of cathode materials for Na-ion batteries because of their superior capacity, average working potential, enhanced diffusivity of Na+ ions, and air stability compared to the O3-type oxides. Among the P2-type oxides, Na0.67Ni0.33Mn0.67O2 (NNMO) is one of the most explored materials because of its superior electrochemical performance. The inherent problem of low capacity retention because of phase changes during high-voltage cycling and Na+/vacancy ordering is still a considerable challenge for P2-type oxide cathodes. In this work, we have doped NNMO with Zr4+ ions at the Ni site to improve the compound's cycle stability. Partial substitution of Ni2+ ions with Zr4+ breaks the Na+/vacancy ordering and increases the interslab distance in the lattice, allowing easy movement of Na+ ions. These effects boost the cycle stability and the rate kinetics at higher rates. Herein, we report Na0.67Ni0.29Zr0.02Mn0.67O2, which delivers 80 mAh g−1 at 1 C rate and retains 90.1% of it after 500 cycles. At 5 C, it delivers 62 mAh g−1 after 700 cycles, showing an outstanding retention of 75.6%. Interestingly, a full cell made with commercial hard carbon anode delivers 74 mAh g−1 in the initial cycle and retains 65.7% after 50 cycles at 1 C, demonstrating an energy density of 229 Wh kg−1. |
| format | Article |
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| language | English |
| publishDate | 2025-07-01 |
| publisher | Elsevier |
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| spelling | doaj-art-e0e8d593d0e841d7a0c5f9c17c544fbc2025-08-20T02:17:25ZengElsevierNext Energy2949-821X2025-07-01810032310.1016/j.nxener.2025.100323Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteriesAnanya Kumar0Sreeraj Puravankara1School of Energy Science and Engineering, IIT Kharagpur, Kharagpur, West Bengal, 721302, IndiaCorresponding author.; School of Energy Science and Engineering, IIT Kharagpur, Kharagpur, West Bengal, 721302, IndiaLayered P2-type oxide compounds are an essential class of cathode materials for Na-ion batteries because of their superior capacity, average working potential, enhanced diffusivity of Na+ ions, and air stability compared to the O3-type oxides. Among the P2-type oxides, Na0.67Ni0.33Mn0.67O2 (NNMO) is one of the most explored materials because of its superior electrochemical performance. The inherent problem of low capacity retention because of phase changes during high-voltage cycling and Na+/vacancy ordering is still a considerable challenge for P2-type oxide cathodes. In this work, we have doped NNMO with Zr4+ ions at the Ni site to improve the compound's cycle stability. Partial substitution of Ni2+ ions with Zr4+ breaks the Na+/vacancy ordering and increases the interslab distance in the lattice, allowing easy movement of Na+ ions. These effects boost the cycle stability and the rate kinetics at higher rates. Herein, we report Na0.67Ni0.29Zr0.02Mn0.67O2, which delivers 80 mAh g−1 at 1 C rate and retains 90.1% of it after 500 cycles. At 5 C, it delivers 62 mAh g−1 after 700 cycles, showing an outstanding retention of 75.6%. Interestingly, a full cell made with commercial hard carbon anode delivers 74 mAh g−1 in the initial cycle and retains 65.7% after 50 cycles at 1 C, demonstrating an energy density of 229 Wh kg−1.http://www.sciencedirect.com/science/article/pii/S2949821X25000869Na-ion batteryNa0.67Ni0.33Mn0.67O2Zirconium dopingP2-type oxide cathodesHigh rate capability |
| spellingShingle | Ananya Kumar Sreeraj Puravankara Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteries Next Energy Na-ion battery Na0.67Ni0.33Mn0.67O2 Zirconium doping P2-type oxide cathodes High rate capability |
| title | Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteries |
| title_full | Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteries |
| title_fullStr | Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteries |
| title_full_unstemmed | Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteries |
| title_short | Enhanced high-rate performance of Zr-doped P2-Na0.67Ni0.33Mn0.67O2 cathode for sodium-ion batteries |
| title_sort | enhanced high rate performance of zr doped p2 na0 67ni0 33mn0 67o2 cathode for sodium ion batteries |
| topic | Na-ion battery Na0.67Ni0.33Mn0.67O2 Zirconium doping P2-type oxide cathodes High rate capability |
| url | http://www.sciencedirect.com/science/article/pii/S2949821X25000869 |
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