Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone Reservoirs

Currently enhanced oil recovery (EOR) technology is getting more attention by many countries since energy crises are getting worse and frightening. Polymer flooding by hydrophobically associated polyacrylamides (HAPAM) and its modified silica nanocomposite are a widely implemented technique through...

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Main Authors: A. N. El-hoshoudy, S. E. M. Desouky, M. Y. Elkady, A. M. Alsabagh, M. A. Betiha, S. Mahmoud
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2015/318708
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author A. N. El-hoshoudy
S. E. M. Desouky
M. Y. Elkady
A. M. Alsabagh
M. A. Betiha
S. Mahmoud
author_facet A. N. El-hoshoudy
S. E. M. Desouky
M. Y. Elkady
A. M. Alsabagh
M. A. Betiha
S. Mahmoud
author_sort A. N. El-hoshoudy
collection DOAJ
description Currently enhanced oil recovery (EOR) technology is getting more attention by many countries since energy crises are getting worse and frightening. Polymer flooding by hydrophobically associated polyacrylamides (HAPAM) and its modified silica nanocomposite are a widely implemented technique through enhanced oil recovery (EOR) technology. This polymers class can be synthesized by copolymerization of acrylamide (AM), reactive surfmer, functionalized silica nanoparticles, and a hydrophobic cross-linker moiety in the presence of water soluble initiator via heterogeneous emulsion polymerization technique, to form latexes that can be applied during polymer flooding. Chemical structure of the prepared copolymers was proven through different techniques such as Fourier transform infrared spectroscopy (FTIR), and nuclear magnetic spectroscopy (1H&13C-NMR), and molecular weight was measured by gel permeation chromatography. Study of the effects of monomer, surfmer, cross-linker, silica, and initiator concentrations as well as reaction temperature was investigated to determine optimum polymerization conditions through single factor and orthogonal experiments. Evaluation of the prepared copolymers for enhancing recovered oil amount was evaluated by carrying out flooding experiments on one-dimensional sandstone model to determine recovery factor.
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institution Kabale University
issn 1687-9422
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language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series International Journal of Polymer Science
spelling doaj-art-e0d99cb288db4e72a765e2b8353acd372025-02-03T01:03:49ZengWileyInternational Journal of Polymer Science1687-94221687-94302015-01-01201510.1155/2015/318708318708Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone ReservoirsA. N. El-hoshoudy0S. E. M. Desouky1M. Y. Elkady2A. M. Alsabagh3M. A. Betiha4S. Mahmoud5Egyptian Petroleum Research Institute, Nasr City, Cairo 11727, EgyptEgyptian Petroleum Research Institute, Nasr City, Cairo 11727, EgyptDepartment of Chemistry, Faculty of Science, Ain shams University, Cairo, EgyptEgyptian Petroleum Research Institute, Nasr City, Cairo 11727, EgyptEgyptian Petroleum Research Institute, Nasr City, Cairo 11727, EgyptEgyptian Petroleum Research Institute, Nasr City, Cairo 11727, EgyptCurrently enhanced oil recovery (EOR) technology is getting more attention by many countries since energy crises are getting worse and frightening. Polymer flooding by hydrophobically associated polyacrylamides (HAPAM) and its modified silica nanocomposite are a widely implemented technique through enhanced oil recovery (EOR) technology. This polymers class can be synthesized by copolymerization of acrylamide (AM), reactive surfmer, functionalized silica nanoparticles, and a hydrophobic cross-linker moiety in the presence of water soluble initiator via heterogeneous emulsion polymerization technique, to form latexes that can be applied during polymer flooding. Chemical structure of the prepared copolymers was proven through different techniques such as Fourier transform infrared spectroscopy (FTIR), and nuclear magnetic spectroscopy (1H&13C-NMR), and molecular weight was measured by gel permeation chromatography. Study of the effects of monomer, surfmer, cross-linker, silica, and initiator concentrations as well as reaction temperature was investigated to determine optimum polymerization conditions through single factor and orthogonal experiments. Evaluation of the prepared copolymers for enhancing recovered oil amount was evaluated by carrying out flooding experiments on one-dimensional sandstone model to determine recovery factor.http://dx.doi.org/10.1155/2015/318708
spellingShingle A. N. El-hoshoudy
S. E. M. Desouky
M. Y. Elkady
A. M. Alsabagh
M. A. Betiha
S. Mahmoud
Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone Reservoirs
International Journal of Polymer Science
title Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone Reservoirs
title_full Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone Reservoirs
title_fullStr Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone Reservoirs
title_full_unstemmed Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone Reservoirs
title_short Investigation of Optimum Polymerization Conditions for Synthesis of Cross-Linked Polyacrylamide-Amphoteric Surfmer Nanocomposites for Polymer Flooding in Sandstone Reservoirs
title_sort investigation of optimum polymerization conditions for synthesis of cross linked polyacrylamide amphoteric surfmer nanocomposites for polymer flooding in sandstone reservoirs
url http://dx.doi.org/10.1155/2015/318708
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