SYNTHESIS OF AMINO DERIVATIVE OF INDENE AND FLUORENE FROM IMIMIUM SALT GENERATED IN ETHEREAL LITHIUM PERCHLORATE SOLUTION
A series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. The yields of the reactions depend on the kind of anion. Addition of...
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| Format: | Article |
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| Language: | English |
| Published: |
University of Tehran
2002-03-01
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| Series: | Journal of Sciences, Islamic Republic of Iran |
| Online Access: | https://jsciences.ut.ac.ir/article_31752_3bf84520d1326fdab37884c7c66fbfa5.pdf |
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| Summary: | A series of amino derivative of 1-indene and 9-fluorene have been synthesized from their corresponding iminium salt, generated in situ in the concentrated ethereal lithium perchlorate solution, and 1-indenyl or 9-fluorenyl anions. The yields of the reactions depend on the kind of anion. Addition of 1-indeny anion to the iminium salt gives the amino derivative of 1-indene, while addition of fluorenyl anion to the iminium salt gives 9-methylenefluorene derivatives as the major product. |
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| ISSN: | 1016-1104 2345-6914 |