CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to Application
CO<sub>2</sub>-responsive polymers have emerged as a significant class of smart materials, distinguished by their ability to reversibly alter their properties upon exposure to CO<sub>2</sub>. Due to CO<sub>2</sub>’s abundant availability, low cost, non-toxicity, e...
Saved in:
| Main Authors: | , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
MDPI AG
2025-05-01
|
| Series: | Molecules |
| Subjects: | |
| Online Access: | https://www.mdpi.com/1420-3049/30/11/2350 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1850160989781098496 |
|---|---|
| author | Mahshab Sheraz Rui Wang |
| author_facet | Mahshab Sheraz Rui Wang |
| author_sort | Mahshab Sheraz |
| collection | DOAJ |
| description | CO<sub>2</sub>-responsive polymers have emerged as a significant class of smart materials, distinguished by their ability to reversibly alter their properties upon exposure to CO<sub>2</sub>. Due to CO<sub>2</sub>’s abundant availability, low cost, non-toxicity, energy efficiency, and excellent biocompatibility, these polymers offer remarkable environmental and practical advantages. This review succinctly explores recent advancements in the synthesis, mechanisms, and applications of CO<sub>2</sub>-responsive polymers, emphasizing the pivotal roles of specific acidic and basic functional groups such as carboxylic acids, phenolic groups, amines, amidines, guanidines, and imidazoles. Advanced polymerization techniques including free radical polymerization (FRP), atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), and nitroxide-mediated polymerization (NMP) are critically evaluated for their precision and flexibility in polymer design. Significant applications in smart separation, carbon capture, drug delivery, desalination, emulsions, tissue engineering, and sensing technologies are discussed comprehensively. Although substantial progress has been made, ongoing challenges include enhancing response speed, durability, sustainability, and economic viability. Future research is recommended to focus on innovative polymer structures, computational modeling, hybrid materials, and greener synthesis methods. This review aims to inspire continued exploration and practical utilization of CO<sub>2</sub>-responsive polymers to address pressing environmental and technological needs. |
| format | Article |
| id | doaj-art-e07e053e8d5b447590b92a4eec6225a2 |
| institution | OA Journals |
| issn | 1420-3049 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | MDPI AG |
| record_format | Article |
| series | Molecules |
| spelling | doaj-art-e07e053e8d5b447590b92a4eec6225a22025-08-20T02:23:00ZengMDPI AGMolecules1420-30492025-05-013011235010.3390/molecules30112350CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to ApplicationMahshab Sheraz0Rui Wang1School of Environmental Science and Engineering, Shandong University, Qingdao 266237, ChinaSchool of Environmental Science and Engineering, Shandong University, Qingdao 266237, ChinaCO<sub>2</sub>-responsive polymers have emerged as a significant class of smart materials, distinguished by their ability to reversibly alter their properties upon exposure to CO<sub>2</sub>. Due to CO<sub>2</sub>’s abundant availability, low cost, non-toxicity, energy efficiency, and excellent biocompatibility, these polymers offer remarkable environmental and practical advantages. This review succinctly explores recent advancements in the synthesis, mechanisms, and applications of CO<sub>2</sub>-responsive polymers, emphasizing the pivotal roles of specific acidic and basic functional groups such as carboxylic acids, phenolic groups, amines, amidines, guanidines, and imidazoles. Advanced polymerization techniques including free radical polymerization (FRP), atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT), and nitroxide-mediated polymerization (NMP) are critically evaluated for their precision and flexibility in polymer design. Significant applications in smart separation, carbon capture, drug delivery, desalination, emulsions, tissue engineering, and sensing technologies are discussed comprehensively. Although substantial progress has been made, ongoing challenges include enhancing response speed, durability, sustainability, and economic viability. Future research is recommended to focus on innovative polymer structures, computational modeling, hybrid materials, and greener synthesis methods. This review aims to inspire continued exploration and practical utilization of CO<sub>2</sub>-responsive polymers to address pressing environmental and technological needs.https://www.mdpi.com/1420-3049/30/11/2350CO<sub>2</sub>-responsive polymersadvanced radical polymerizationfunctional group-induced transitionsreversible polymer behaviorssmart applications |
| spellingShingle | Mahshab Sheraz Rui Wang CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to Application Molecules CO<sub>2</sub>-responsive polymers advanced radical polymerization functional group-induced transitions reversible polymer behaviors smart applications |
| title | CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to Application |
| title_full | CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to Application |
| title_fullStr | CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to Application |
| title_full_unstemmed | CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to Application |
| title_short | CO<sub>2</sub>-Responsive Vinyl Polymers: From Synthesis to Application |
| title_sort | co sub 2 sub responsive vinyl polymers from synthesis to application |
| topic | CO<sub>2</sub>-responsive polymers advanced radical polymerization functional group-induced transitions reversible polymer behaviors smart applications |
| url | https://www.mdpi.com/1420-3049/30/11/2350 |
| work_keys_str_mv | AT mahshabsheraz cosub2subresponsivevinylpolymersfromsynthesistoapplication AT ruiwang cosub2subresponsivevinylpolymersfromsynthesistoapplication |