Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic Medium
The influence of N-(l-morpholinobenzyl)urea (MBU) on corrosion inhibition of mild steel in 1 M HCl was studied by weight loss, effect of temperature, potentiodynamic polarization and electrochemical impedance spectroscopy. The experimental results showed that the inhibition efficiency increases wit...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/892548 |
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| author | M. Anwar Sathiq A. Jamal Abdul Nasser P. Mohamed Sirajudeen |
| author_facet | M. Anwar Sathiq A. Jamal Abdul Nasser P. Mohamed Sirajudeen |
| author_sort | M. Anwar Sathiq |
| collection | DOAJ |
| description | The influence of N-(l-morpholinobenzyl)urea (MBU) on corrosion inhibition of mild steel in 1 M HCl was studied by weight loss, effect of temperature, potentiodynamic polarization and electrochemical impedance spectroscopy. The experimental results showed that the inhibition efficiency increases with increasing of MBU concentrations but decreases with increasing temperatures. The adsorption of MBU on the mild steel surface obeyed the Temkin’s adsorption isotherm. Potentiodynamic polarization curves showed that MBU acted as a cathodic inhibitor predominantly in hydrochloric acid. This was supported by the impedance measurements which showed a change in the charge transfer resistance and double layer capacitance indicating adsorption of MBU on the mild steel surface. Protective film formation against the acid attack is confirmed by SEM. |
| format | Article |
| id | doaj-art-dfadb694248c4767b38973c953cb764e |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-dfadb694248c4767b38973c953cb764e2025-02-03T01:29:59ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-018262162810.1155/2011/892548Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic MediumM. Anwar Sathiq0A. Jamal Abdul Nasser1P. Mohamed Sirajudeen2PG and Research Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli-620020, Tamilnadu, IndiaPG and Research Department of Chemistry, Jamal Mohamed College (Autonomous), Tiruchirappalli-620020, Tamilnadu, IndiaPG and Research Department of Chemistry, Khadir Mohideen College, Adirampattinum-614701, Tamilnadu, IndiaThe influence of N-(l-morpholinobenzyl)urea (MBU) on corrosion inhibition of mild steel in 1 M HCl was studied by weight loss, effect of temperature, potentiodynamic polarization and electrochemical impedance spectroscopy. The experimental results showed that the inhibition efficiency increases with increasing of MBU concentrations but decreases with increasing temperatures. The adsorption of MBU on the mild steel surface obeyed the Temkin’s adsorption isotherm. Potentiodynamic polarization curves showed that MBU acted as a cathodic inhibitor predominantly in hydrochloric acid. This was supported by the impedance measurements which showed a change in the charge transfer resistance and double layer capacitance indicating adsorption of MBU on the mild steel surface. Protective film formation against the acid attack is confirmed by SEM.http://dx.doi.org/10.1155/2011/892548 |
| spellingShingle | M. Anwar Sathiq A. Jamal Abdul Nasser P. Mohamed Sirajudeen Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic Medium E-Journal of Chemistry |
| title | Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic Medium |
| title_full | Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic Medium |
| title_fullStr | Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic Medium |
| title_full_unstemmed | Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic Medium |
| title_short | Adsorption and Corrosion Inhibition Effect of N-(l-Morpholinobenzyl)urea onMild Steel in Acidic Medium |
| title_sort | adsorption and corrosion inhibition effect of n l morpholinobenzyl urea onmild steel in acidic medium |
| url | http://dx.doi.org/10.1155/2011/892548 |
| work_keys_str_mv | AT manwarsathiq adsorptionandcorrosioninhibitioneffectofnlmorpholinobenzylureaonmildsteelinacidicmedium AT ajamalabdulnasser adsorptionandcorrosioninhibitioneffectofnlmorpholinobenzylureaonmildsteelinacidicmedium AT pmohamedsirajudeen adsorptionandcorrosioninhibitioneffectofnlmorpholinobenzylureaonmildsteelinacidicmedium |