Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPS
Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate (NORSM) was found to perform an exceptional synergistic effect with tris(2,4,6-tribromophenoxy)-1,3,5-triazine (TTBPC)/Sb2O3 in HIPS. The LOI of fire retardant HIPS (FR-HIPS) with 16 wt% of TTBPC/Sb2O3 increased from 23.8% to 25.2%, the flame...
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| Format: | Article |
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Wiley
2020-01-01
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| Series: | Advances in Materials Science and Engineering |
| Online Access: | http://dx.doi.org/10.1155/2020/6384530 |
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| author | Hongzhi Wu Junhong Liu Qi Zhang Mingmei Sun Jingwei Yang Linsheng Tang |
| author_facet | Hongzhi Wu Junhong Liu Qi Zhang Mingmei Sun Jingwei Yang Linsheng Tang |
| author_sort | Hongzhi Wu |
| collection | DOAJ |
| description | Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate (NORSM) was found to perform an exceptional synergistic effect with tris(2,4,6-tribromophenoxy)-1,3,5-triazine (TTBPC)/Sb2O3 in HIPS. The LOI of fire retardant HIPS (FR-HIPS) with 16 wt% of TTBPC/Sb2O3 increased from 23.8% to 25.2%, the flame retardant rating of FR-HIPS was improved from UL 94 V-2 to UL 94 V-0, and various heat release parameters such as peak heat release rate, total heat release, and mean effective heat of combustion were greatly lowered by combining NORSM of 0.50 wt%. The Py-GC/MS results revealed that NORSM induced the role of synergistic effect; the main mechanisms were as follows: the active radicals such as methoxy radicals and aminyl radicals produced by the pyrolysis of NORSM promote the release of bromine radicals from TTBPC and the formation of HBr and CO2, which improves the flame retardancy of TTBPC/Sb2O3; the above active radicals, together with HBr, quench active free radicals, such as the hydroxyl radical (OH), and decompose the free radical source, which interrupts the chain reaction during combustion and results in a more efficient flame retardant effect in gaseous phase. |
| format | Article |
| id | doaj-art-df7c9600fa974c4bb53479ba9be9cb59 |
| institution | Kabale University |
| issn | 1687-8434 1687-8442 |
| language | English |
| publishDate | 2020-01-01 |
| publisher | Wiley |
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| series | Advances in Materials Science and Engineering |
| spelling | doaj-art-df7c9600fa974c4bb53479ba9be9cb592025-02-03T01:01:29ZengWileyAdvances in Materials Science and Engineering1687-84341687-84422020-01-01202010.1155/2020/63845306384530Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPSHongzhi Wu0Junhong Liu1Qi Zhang2Mingmei Sun3Jingwei Yang4Linsheng Tang5State Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, ChinaState Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, ChinaState Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, ChinaState Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, ChinaState Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, ChinaState Key Laboratory Base of Eco-chemical Engineering, College of Chemical Engineering, Qingdao University of Science and Technology, Qingdao 266042, ChinaBis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate (NORSM) was found to perform an exceptional synergistic effect with tris(2,4,6-tribromophenoxy)-1,3,5-triazine (TTBPC)/Sb2O3 in HIPS. The LOI of fire retardant HIPS (FR-HIPS) with 16 wt% of TTBPC/Sb2O3 increased from 23.8% to 25.2%, the flame retardant rating of FR-HIPS was improved from UL 94 V-2 to UL 94 V-0, and various heat release parameters such as peak heat release rate, total heat release, and mean effective heat of combustion were greatly lowered by combining NORSM of 0.50 wt%. The Py-GC/MS results revealed that NORSM induced the role of synergistic effect; the main mechanisms were as follows: the active radicals such as methoxy radicals and aminyl radicals produced by the pyrolysis of NORSM promote the release of bromine radicals from TTBPC and the formation of HBr and CO2, which improves the flame retardancy of TTBPC/Sb2O3; the above active radicals, together with HBr, quench active free radicals, such as the hydroxyl radical (OH), and decompose the free radical source, which interrupts the chain reaction during combustion and results in a more efficient flame retardant effect in gaseous phase.http://dx.doi.org/10.1155/2020/6384530 |
| spellingShingle | Hongzhi Wu Junhong Liu Qi Zhang Mingmei Sun Jingwei Yang Linsheng Tang Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPS Advances in Materials Science and Engineering |
| title | Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPS |
| title_full | Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPS |
| title_fullStr | Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPS |
| title_full_unstemmed | Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPS |
| title_short | Synergistic Fire Retardancy of Bis(1-methoxy-2,2,6,6-tetramethylpiperidin-4-yl)sebacate and Tris(2,4,6-tribromophenoxy)-1,3,5-triazine/Sb2O3 in HIPS |
| title_sort | synergistic fire retardancy of bis 1 methoxy 2 2 6 6 tetramethylpiperidin 4 yl sebacate and tris 2 4 6 tribromophenoxy 1 3 5 triazine sb2o3 in hips |
| url | http://dx.doi.org/10.1155/2020/6384530 |
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