(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation

(C3N2H5)B3O3F2(OH)2: Realizing Large Birefringence via a Synergistic Effect between Anion F/OH‐Ratio Optimization and Cation Activation

Borates have emerged as a significant resource for exploring birefringent materials in the UV frequency region. The π‐conjugated planar anions, such as the [BO3], [B2O5], and [B3O6] units, exhibiting strong polarizability anisotropy, are traditionally good structural models. Both fluorination and hy...

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Bibliographic Details
Main Authors: Chenhui Hu, Chunjie Shen, Huan Zhou, Jian Han, Zhihua Yang, Kenneth R. Poeppelmeier, Feng Zhang, Shilie Pan
Format: Article
Language:English
Published: Wiley-VCH 2024-12-01
Series:Small Structures
Subjects:
birefringent materials
borates
cation activation
fluorination
hydroxylation
targeted design
Online Access:https://doi.org/10.1002/sstr.202400296
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