Efficient adsorption of organic dyes using Fe3O4/carbon sphere nanocomposites: Synthesis and performance evaluation

This study reports the synthesis of Fe3O4/carbon sphere (CS) nanocomposites via a solvothermal method followed by co-precipitation for the efficient adsorption of organic dyes. The structural and morphological characteristics of the nanocomposites were analyzed using scanning electron microscope, X-...

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Bibliographic Details
Main Authors: Ta Duc Khue, Pham Kim Ngoc, Do Thanh Viet, Tran Dang Thanh, Tuan Hong Nguyen, Pham Van Vinh, Dinh Lam Nguyen, Pham Duc Thang, Anh Tuan Duong, Raja Das, Huu Tuan Nguyen
Format: Article
Language:English
Published: Elsevier 2025-06-01
Series:Journal of Science: Advanced Materials and Devices
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Online Access:http://www.sciencedirect.com/science/article/pii/S2468217925000334
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Summary:This study reports the synthesis of Fe3O4/carbon sphere (CS) nanocomposites via a solvothermal method followed by co-precipitation for the efficient adsorption of organic dyes. The structural and morphological characteristics of the nanocomposites were analyzed using scanning electron microscope, X-ray diffraction, and energy-dispersive X-ray spectroscopy, confirming the successful integration of Fe3O4 nanoparticles onto the CS surface. Adsorption kinetics followed the pseudo-second-order model, suggesting chemisorption as the primary mechanism for methylene blue (MB) and rhodamine B (RB) dye removal. The adsorption process aligned well with the Langmuir isotherm model, with optimized nanocomposites achieving nearly 100 % removal of MB and RB within just 5 min. In contrast, Fe3O4 nanoparticles showed poor adsorption, removing less than 10 % of MB and 24 % of RB after 120 min, whereas CS removed 93.5 % of MB and 73 % of RB in the same timeframe. Featuring strong magnetic properties for easy separation, high stability, and exceptional adsorption efficiency, Fe3O4/CS nanocomposites emerge as promising reusable adsorbents for wastewater treatment.
ISSN:2468-2179