PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyond
This study investigated the occurrence of perfluoroalkyl and polyfluoroalkyl substances (PFAS), including anionic, cationic, and zwitterionic compounds, in drinking water. Between 2021–2023, an expanded list of 76 target PFAS was screened in tap water samples mainly from Canada, but also including t...
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Elsevier
2025-01-01
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| Series: | Environment International |
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| Online Access: | http://www.sciencedirect.com/science/article/pii/S0160412025000017 |
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| author | Termeh Teymoorian Gabriel Munoz Sébastien Sauvé |
| author_facet | Termeh Teymoorian Gabriel Munoz Sébastien Sauvé |
| author_sort | Termeh Teymoorian |
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| description | This study investigated the occurrence of perfluoroalkyl and polyfluoroalkyl substances (PFAS), including anionic, cationic, and zwitterionic compounds, in drinking water. Between 2021–2023, an expanded list of 76 target PFAS was screened in tap water samples mainly from Canada, but also including tap water samples from the Eastern United States, Mexico, South America (Argentina), the Caribbean (Dominican Republic, Cuba), Africa (Algeria, Cameroon, Central African Republic, Morocco, Rwanda, Tunisia), Europe (France, Greece, Italy, Spain, and the United Kingdom) and Asia (Japan, Vietnam, Iran, and Türkiye). An additional ∼ 200 suspect-target PFAS were screened using high-resolution Orbitrap mass spectrometry. The results revealed widespread contamination of PFAS in tap water. The most frequent were perfluorobutane sulfonate (PFBS), perfluorooctane sulfonate (PFOS), and perfluorobutanoic acid (PFBA) with detection rates of ≥ 79 %. Several PFAS not currently included in EPA methods for drinking water revealed region-specific trends. For instance, emerging zwitterionic 6:2 fluorotelomer sulfonamidopropyl betaine (6:2 FTAB) was found at the highest levels in cities of France, British Columbia (Canada), and the UK. The occurrence of FTAB likely reflects shifts from PFOS-based aqueous film-forming foams (AFFF) in the past decades, and possibly other uses. Short-chain perfluoroalkyl sulfonamides (FBSA, FHxSA) were also globally recurrent. Bistriflimide, a counterion often used in the composition of ionic liquids and in the production of lithium-ion batteries, was detected in 46 % of the samples. The highest levels of total PFAS in drinking water were linked to contamination from fluorochemical industries (surface water), AFFF use (groundwater), and landfills (groundwater). This database of 275 PFAS x 153 samples provides valuable insights toward refining the lists of relevant PFAS to be monitored in drinking water. |
| format | Article |
| id | doaj-art-df2f4f9dcc8c49e0aa67f56a1c5e831a |
| institution | Kabale University |
| issn | 0160-4120 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Elsevier |
| record_format | Article |
| series | Environment International |
| spelling | doaj-art-df2f4f9dcc8c49e0aa67f56a1c5e831a2025-01-24T04:44:13ZengElsevierEnvironment International0160-41202025-01-01195109250PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyondTermeh Teymoorian0Gabriel Munoz1Sébastien Sauvé2Département de Chimie, Université de Montréal, Montreal, QC, CanadaDépartement de Chimie, Université de Montréal, Montreal, QC, CanadaCorresponding author.; Département de Chimie, Université de Montréal, Montreal, QC, CanadaThis study investigated the occurrence of perfluoroalkyl and polyfluoroalkyl substances (PFAS), including anionic, cationic, and zwitterionic compounds, in drinking water. Between 2021–2023, an expanded list of 76 target PFAS was screened in tap water samples mainly from Canada, but also including tap water samples from the Eastern United States, Mexico, South America (Argentina), the Caribbean (Dominican Republic, Cuba), Africa (Algeria, Cameroon, Central African Republic, Morocco, Rwanda, Tunisia), Europe (France, Greece, Italy, Spain, and the United Kingdom) and Asia (Japan, Vietnam, Iran, and Türkiye). An additional ∼ 200 suspect-target PFAS were screened using high-resolution Orbitrap mass spectrometry. The results revealed widespread contamination of PFAS in tap water. The most frequent were perfluorobutane sulfonate (PFBS), perfluorooctane sulfonate (PFOS), and perfluorobutanoic acid (PFBA) with detection rates of ≥ 79 %. Several PFAS not currently included in EPA methods for drinking water revealed region-specific trends. For instance, emerging zwitterionic 6:2 fluorotelomer sulfonamidopropyl betaine (6:2 FTAB) was found at the highest levels in cities of France, British Columbia (Canada), and the UK. The occurrence of FTAB likely reflects shifts from PFOS-based aqueous film-forming foams (AFFF) in the past decades, and possibly other uses. Short-chain perfluoroalkyl sulfonamides (FBSA, FHxSA) were also globally recurrent. Bistriflimide, a counterion often used in the composition of ionic liquids and in the production of lithium-ion batteries, was detected in 46 % of the samples. The highest levels of total PFAS in drinking water were linked to contamination from fluorochemical industries (surface water), AFFF use (groundwater), and landfills (groundwater). This database of 275 PFAS x 153 samples provides valuable insights toward refining the lists of relevant PFAS to be monitored in drinking water.http://www.sciencedirect.com/science/article/pii/S0160412025000017PFASDrinking waterTap waterSuspect screeningPrecursors |
| spellingShingle | Termeh Teymoorian Gabriel Munoz Sébastien Sauvé PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyond Environment International PFAS Drinking water Tap water Suspect screening Precursors |
| title | PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyond |
| title_full | PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyond |
| title_fullStr | PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyond |
| title_full_unstemmed | PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyond |
| title_short | PFAS contamination in tap water: Target and suspect screening of zwitterionic, cationic, and anionic species across Canada and beyond |
| title_sort | pfas contamination in tap water target and suspect screening of zwitterionic cationic and anionic species across canada and beyond |
| topic | PFAS Drinking water Tap water Suspect screening Precursors |
| url | http://www.sciencedirect.com/science/article/pii/S0160412025000017 |
| work_keys_str_mv | AT termehteymoorian pfascontaminationintapwatertargetandsuspectscreeningofzwitterioniccationicandanionicspeciesacrosscanadaandbeyond AT gabrielmunoz pfascontaminationintapwatertargetandsuspectscreeningofzwitterioniccationicandanionicspeciesacrosscanadaandbeyond AT sebastiensauve pfascontaminationintapwatertargetandsuspectscreeningofzwitterioniccationicandanionicspeciesacrosscanadaandbeyond |