Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar Cells

We report on the development and application of n-type hydrogenated microcrystalline silicon oxide films (n μc-SiO:H) in hydrogenated amorphous silicon oxide/hydrogenated microcrystalline silicon (a-SiO:H/μc-Si:H) micromorph solar cells. The n μc-SiO:H films with high optical bandgap and low refract...

Full description

Saved in:
Bibliographic Details
Main Authors: Amornrat Limmanee, Songkiate Kittisontirak, Sorapong Inthisang, Taweewat Krajangsang, Jaran Sritharathikhun, Kobsak Sriprapha
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2013/513284
Tags: Add Tag
No Tags, Be the first to tag this record!
_version_ 1832550310245040128
author Amornrat Limmanee
Songkiate Kittisontirak
Sorapong Inthisang
Taweewat Krajangsang
Jaran Sritharathikhun
Kobsak Sriprapha
author_facet Amornrat Limmanee
Songkiate Kittisontirak
Sorapong Inthisang
Taweewat Krajangsang
Jaran Sritharathikhun
Kobsak Sriprapha
author_sort Amornrat Limmanee
collection DOAJ
description We report on the development and application of n-type hydrogenated microcrystalline silicon oxide films (n μc-SiO:H) in hydrogenated amorphous silicon oxide/hydrogenated microcrystalline silicon (a-SiO:H/μc-Si:H) micromorph solar cells. The n μc-SiO:H films with high optical bandgap and low refractive index could be obtained when a ratio of carbon dioxide (CO2) to silane (SiH4) flow rate was raised; however, a trade-off against electrical property was observed. We applied the n μc-SiO:H films in the top a-SiO:H cell and investigated the changes in cell performance with respect to the electrical and optical properties of the films. It was found that all photovoltaic parameters of the micromorph silicon solar cells using the n top μc-SiO:H layer enhanced with increasing the CO2/SiH4 ratio up to 0.23, where the highest initial cell efficiency of 10.7% was achieved. The enhancement of the open circuit voltage (Voc) was likely to be due to a reduction of reverse bias at subcell connection—n top/p bottom interface—and a better tunnel recombination junction contributed to the improvement in the fill factor (FF). Furthermore, the quantum efficiency (QE) results also have demonstrated intermediate-reflector function of the n μc-SiO:H films.
format Article
id doaj-art-df091eddc12243ffa97ba0b7783169cb
institution Kabale University
issn 1110-662X
1687-529X
language English
publishDate 2013-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-df091eddc12243ffa97ba0b7783169cb2025-02-03T06:07:14ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2013-01-01201310.1155/2013/513284513284Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar CellsAmornrat Limmanee0Songkiate Kittisontirak1Sorapong Inthisang2Taweewat Krajangsang3Jaran Sritharathikhun4Kobsak Sriprapha5Solar Energy Technology Laboratory, National Electronics and Computer Technology Center, National Science and Technology Development Agency, 112 Thailand Science Park, Phahonyothin Road, Klong 1, Klong Luang, Pathum Thani 12120, ThailandSolar Energy Technology Laboratory, National Electronics and Computer Technology Center, National Science and Technology Development Agency, 112 Thailand Science Park, Phahonyothin Road, Klong 1, Klong Luang, Pathum Thani 12120, ThailandSolar Energy Technology Laboratory, National Electronics and Computer Technology Center, National Science and Technology Development Agency, 112 Thailand Science Park, Phahonyothin Road, Klong 1, Klong Luang, Pathum Thani 12120, ThailandSolar Energy Technology Laboratory, National Electronics and Computer Technology Center, National Science and Technology Development Agency, 112 Thailand Science Park, Phahonyothin Road, Klong 1, Klong Luang, Pathum Thani 12120, ThailandSolar Energy Technology Laboratory, National Electronics and Computer Technology Center, National Science and Technology Development Agency, 112 Thailand Science Park, Phahonyothin Road, Klong 1, Klong Luang, Pathum Thani 12120, ThailandSolar Energy Technology Laboratory, National Electronics and Computer Technology Center, National Science and Technology Development Agency, 112 Thailand Science Park, Phahonyothin Road, Klong 1, Klong Luang, Pathum Thani 12120, ThailandWe report on the development and application of n-type hydrogenated microcrystalline silicon oxide films (n μc-SiO:H) in hydrogenated amorphous silicon oxide/hydrogenated microcrystalline silicon (a-SiO:H/μc-Si:H) micromorph solar cells. The n μc-SiO:H films with high optical bandgap and low refractive index could be obtained when a ratio of carbon dioxide (CO2) to silane (SiH4) flow rate was raised; however, a trade-off against electrical property was observed. We applied the n μc-SiO:H films in the top a-SiO:H cell and investigated the changes in cell performance with respect to the electrical and optical properties of the films. It was found that all photovoltaic parameters of the micromorph silicon solar cells using the n top μc-SiO:H layer enhanced with increasing the CO2/SiH4 ratio up to 0.23, where the highest initial cell efficiency of 10.7% was achieved. The enhancement of the open circuit voltage (Voc) was likely to be due to a reduction of reverse bias at subcell connection—n top/p bottom interface—and a better tunnel recombination junction contributed to the improvement in the fill factor (FF). Furthermore, the quantum efficiency (QE) results also have demonstrated intermediate-reflector function of the n μc-SiO:H films.http://dx.doi.org/10.1155/2013/513284
spellingShingle Amornrat Limmanee
Songkiate Kittisontirak
Sorapong Inthisang
Taweewat Krajangsang
Jaran Sritharathikhun
Kobsak Sriprapha
Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar Cells
International Journal of Photoenergy
title Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar Cells
title_full Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar Cells
title_fullStr Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar Cells
title_full_unstemmed Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar Cells
title_short Advantages of N-Type Hydrogenated Microcrystalline Silicon Oxide Films for Micromorph Silicon Solar Cells
title_sort advantages of n type hydrogenated microcrystalline silicon oxide films for micromorph silicon solar cells
url http://dx.doi.org/10.1155/2013/513284
work_keys_str_mv AT amornratlimmanee advantagesofntypehydrogenatedmicrocrystallinesiliconoxidefilmsformicromorphsiliconsolarcells
AT songkiatekittisontirak advantagesofntypehydrogenatedmicrocrystallinesiliconoxidefilmsformicromorphsiliconsolarcells
AT soraponginthisang advantagesofntypehydrogenatedmicrocrystallinesiliconoxidefilmsformicromorphsiliconsolarcells
AT taweewatkrajangsang advantagesofntypehydrogenatedmicrocrystallinesiliconoxidefilmsformicromorphsiliconsolarcells
AT jaransritharathikhun advantagesofntypehydrogenatedmicrocrystallinesiliconoxidefilmsformicromorphsiliconsolarcells
AT kobsaksriprapha advantagesofntypehydrogenatedmicrocrystallinesiliconoxidefilmsformicromorphsiliconsolarcells