Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide Salts
Abstract Photothermal sensing is crucial for the creation of smart integrated devices. All‐inorganic metal halide perovskites with the formula CsPbX3 (X═Cl, Br, I) have excellent photo‐physical performance, offering exciting opportunities for flexible electronics. Hence, a supersaturated precipitati...
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| Format: | Article |
| Language: | English |
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Wiley-VCH
2025-02-01
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| Series: | Advanced Physics Research |
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| Online Access: | https://doi.org/10.1002/apxr.202400099 |
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| author | Dandan Yang Tianzhu Zhao Zixing Peng Xiudi Xiao Guoping Dong |
| author_facet | Dandan Yang Tianzhu Zhao Zixing Peng Xiudi Xiao Guoping Dong |
| author_sort | Dandan Yang |
| collection | DOAJ |
| description | Abstract Photothermal sensing is crucial for the creation of smart integrated devices. All‐inorganic metal halide perovskites with the formula CsPbX3 (X═Cl, Br, I) have excellent photo‐physical performance, offering exciting opportunities for flexible electronics. Hence, a supersaturated precipitation strategy is proposed for the preparation of salt‐shelled metal halide solids. The well‐designed CsPbX3@MX (M═K, Cs) products exhibit bright narrow visible emissions and favorable thermal stability up to 195 °C. Co‐doping with Ni2+ and Mn2+ ions, the CsPbCl3@KCl products have realized dual‐mode thermometry. Utilizing the blue emission from the CsPbCl3 host and the red emission from the Mn2+ ion, a fluorescence intensity ratio technique is obtained to monitor the temperature of good stability and repeatability. Based on the regular fluorescence decay of Mn2+ ions with rising temperature, the lifetime of Mn2+ ions can also be used for temperature sensing. It is believed that such stable metal halides with dual‐mode thermometry will provide a new sight for optical thermometers and, more importantly, will unleash the possibility of a broad variety of applications in lightweight and integrated functional devices. |
| format | Article |
| id | doaj-art-de36cf8de7b84bf1bcabc35ae4e7b36a |
| institution | DOAJ |
| issn | 2751-1200 |
| language | English |
| publishDate | 2025-02-01 |
| publisher | Wiley-VCH |
| record_format | Article |
| series | Advanced Physics Research |
| spelling | doaj-art-de36cf8de7b84bf1bcabc35ae4e7b36a2025-08-20T03:05:39ZengWiley-VCHAdvanced Physics Research2751-12002025-02-0142n/an/a10.1002/apxr.202400099Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide SaltsDandan Yang0Tianzhu Zhao1Zixing Peng2Xiudi Xiao3Guoping Dong4State Key Laboratory of Luminescent Materials and Devices South China University of Technology Guangzhou 510640 ChinaState Key Laboratory of Luminescent Materials and Devices South China University of Technology Guangzhou 510640 ChinaDepartment of Chemistry University of Manchester Manchester M13 9PL UKState Key Laboratory of Luminescent Materials and Devices South China University of Technology Guangzhou 510640 ChinaState Key Laboratory of Luminescent Materials and Devices South China University of Technology Guangzhou 510640 ChinaAbstract Photothermal sensing is crucial for the creation of smart integrated devices. All‐inorganic metal halide perovskites with the formula CsPbX3 (X═Cl, Br, I) have excellent photo‐physical performance, offering exciting opportunities for flexible electronics. Hence, a supersaturated precipitation strategy is proposed for the preparation of salt‐shelled metal halide solids. The well‐designed CsPbX3@MX (M═K, Cs) products exhibit bright narrow visible emissions and favorable thermal stability up to 195 °C. Co‐doping with Ni2+ and Mn2+ ions, the CsPbCl3@KCl products have realized dual‐mode thermometry. Utilizing the blue emission from the CsPbCl3 host and the red emission from the Mn2+ ion, a fluorescence intensity ratio technique is obtained to monitor the temperature of good stability and repeatability. Based on the regular fluorescence decay of Mn2+ ions with rising temperature, the lifetime of Mn2+ ions can also be used for temperature sensing. It is believed that such stable metal halides with dual‐mode thermometry will provide a new sight for optical thermometers and, more importantly, will unleash the possibility of a broad variety of applications in lightweight and integrated functional devices.https://doi.org/10.1002/apxr.202400099dopingdual‐mode thermometrymetal halide coatingoptical thermometryperovskite nanocrystals |
| spellingShingle | Dandan Yang Tianzhu Zhao Zixing Peng Xiudi Xiao Guoping Dong Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide Salts Advanced Physics Research doping dual‐mode thermometry metal halide coating optical thermometry perovskite nanocrystals |
| title | Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide Salts |
| title_full | Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide Salts |
| title_fullStr | Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide Salts |
| title_full_unstemmed | Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide Salts |
| title_short | Dual‐Mode Optical Thermometers Based on the Thermal‐Stable Perovskite Nanocrystals Embedded in Robust Metal Halide Salts |
| title_sort | dual mode optical thermometers based on the thermal stable perovskite nanocrystals embedded in robust metal halide salts |
| topic | doping dual‐mode thermometry metal halide coating optical thermometry perovskite nanocrystals |
| url | https://doi.org/10.1002/apxr.202400099 |
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