The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-Trinitrobenzene
The oxidation of 2,4,6-trinitrotoluene (TNT) to 1,3,5-trinitrobenzene (TNB) in one step, 2,4,6-trinitrobenzoic acid (TNBA), and 2,4,6-trinitrobenzaldehyde (TNBAl) with an ozone-oxygen mixture in different solvents, catalysts, and temperatures has been investigated. Reducing the number of steps in t...
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| Format: | Article |
| Language: | English |
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Wiley
2013-01-01
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| Series: | Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2013/958286 |
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| author | Mohammad Ali Zarei Hasan Tahermansouri Yadollah Bayat |
| author_facet | Mohammad Ali Zarei Hasan Tahermansouri Yadollah Bayat |
| author_sort | Mohammad Ali Zarei |
| collection | DOAJ |
| description | The oxidation of 2,4,6-trinitrotoluene (TNT) to 1,3,5-trinitrobenzene (TNB) in one step, 2,4,6-trinitrobenzoic acid (TNBA), and 2,4,6-trinitrobenzaldehyde (TNBAl) with an ozone-oxygen mixture in different solvents, catalysts, and temperatures has been investigated. Reducing the number of steps in the oxidation of TNT to TNB is the major advantage of this procedure with respect to conventional processes such as chromic acid and potassium permanganate. The oxidation of TNT to TNB was completed in one step as compared to two steps in the conventional approach. The products were obtained with relatively good yield. |
| format | Article |
| id | doaj-art-dd47bfac7843446fb263f37e67a64157 |
| institution | Kabale University |
| issn | 2090-9063 2090-9071 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Chemistry |
| spelling | doaj-art-dd47bfac7843446fb263f37e67a641572025-02-03T06:14:13ZengWileyJournal of Chemistry2090-90632090-90712013-01-01201310.1155/2013/958286958286The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-TrinitrobenzeneMohammad Ali Zarei0Hasan Tahermansouri1Yadollah Bayat2Department of Chemistry and Engineering Chemistry, Malek Ashtar University of Technology, P.O. Box 16765-3454, Tehran, IranDepartment of Chemistry, Ayatollah Amoli Branch, Islamic Azad University, P.O. Box 678, Amol, IranDepartment of Chemistry and Engineering Chemistry, Malek Ashtar University of Technology, P.O. Box 16765-3454, Tehran, IranThe oxidation of 2,4,6-trinitrotoluene (TNT) to 1,3,5-trinitrobenzene (TNB) in one step, 2,4,6-trinitrobenzoic acid (TNBA), and 2,4,6-trinitrobenzaldehyde (TNBAl) with an ozone-oxygen mixture in different solvents, catalysts, and temperatures has been investigated. Reducing the number of steps in the oxidation of TNT to TNB is the major advantage of this procedure with respect to conventional processes such as chromic acid and potassium permanganate. The oxidation of TNT to TNB was completed in one step as compared to two steps in the conventional approach. The products were obtained with relatively good yield.http://dx.doi.org/10.1155/2013/958286 |
| spellingShingle | Mohammad Ali Zarei Hasan Tahermansouri Yadollah Bayat The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-Trinitrobenzene Journal of Chemistry |
| title | The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-Trinitrobenzene |
| title_full | The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-Trinitrobenzene |
| title_fullStr | The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-Trinitrobenzene |
| title_full_unstemmed | The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-Trinitrobenzene |
| title_short | The Oxidation of 2,4,6-Trinitrotoluene with an Ozone-Oxygen Mixture: A Simple Method for Preparation of 1,3,5-Trinitrobenzene |
| title_sort | oxidation of 2 4 6 trinitrotoluene with an ozone oxygen mixture a simple method for preparation of 1 3 5 trinitrobenzene |
| url | http://dx.doi.org/10.1155/2013/958286 |
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