Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction
Well-aligned ZnO nanorod arrays with room temperature ferromagnetism were prepared on glass substrate through hydrothermal method. The as-prepared nanorod arrays were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), photoluminescence...
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Wiley
2014-01-01
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Series: | Advances in Condensed Matter Physics |
Online Access: | http://dx.doi.org/10.1155/2014/627975 |
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author | Jiangni Yun Rui Qu Zhiyong Zhang Jun Li |
author_facet | Jiangni Yun Rui Qu Zhiyong Zhang Jun Li |
author_sort | Jiangni Yun |
collection | DOAJ |
description | Well-aligned ZnO nanorod arrays with room temperature ferromagnetism were prepared on glass substrate through hydrothermal method. The as-prepared nanorod arrays were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), photoluminescence (PL) spectrum, and magnetization measurements. The XRD and SEM results indicated that the ZnO nanorods are with the wurtzite structure and exhibit preferential (002) orientation with c-axis perpendicular to the substrate surface. The PL results suggested that the possible defect in the as-prepared ZnO nanorod arrays might be VZn, Oi, or OZn. The first-principles calculations reveal that the room temperature ferromagnetism may result from the VZn defects present in the ZnO nanorod and the hybridization of the Zn 3d states with O 2p states is responsible for the half-metallic ferromagnetism in ZnO nanorod. |
format | Article |
id | doaj-art-dcc5fe6b68294678a9be721d561c5571 |
institution | Kabale University |
issn | 1687-8108 1687-8124 |
language | English |
publishDate | 2014-01-01 |
publisher | Wiley |
record_format | Article |
series | Advances in Condensed Matter Physics |
spelling | doaj-art-dcc5fe6b68294678a9be721d561c55712025-02-03T05:59:31ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242014-01-01201410.1155/2014/627975627975Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal ReactionJiangni Yun0Rui Qu1Zhiyong Zhang2Jun Li3School of Information Science and Technology, Northwest University, Xi’an 710127, ChinaSchool of Information Science and Technology, Northwest University, Xi’an 710127, ChinaSchool of Information Science and Technology, Northwest University, Xi’an 710127, ChinaSchool of Information Science and Technology, Northwest University, Xi’an 710127, ChinaWell-aligned ZnO nanorod arrays with room temperature ferromagnetism were prepared on glass substrate through hydrothermal method. The as-prepared nanorod arrays were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), photoluminescence (PL) spectrum, and magnetization measurements. The XRD and SEM results indicated that the ZnO nanorods are with the wurtzite structure and exhibit preferential (002) orientation with c-axis perpendicular to the substrate surface. The PL results suggested that the possible defect in the as-prepared ZnO nanorod arrays might be VZn, Oi, or OZn. The first-principles calculations reveal that the room temperature ferromagnetism may result from the VZn defects present in the ZnO nanorod and the hybridization of the Zn 3d states with O 2p states is responsible for the half-metallic ferromagnetism in ZnO nanorod.http://dx.doi.org/10.1155/2014/627975 |
spellingShingle | Jiangni Yun Rui Qu Zhiyong Zhang Jun Li Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction Advances in Condensed Matter Physics |
title | Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction |
title_full | Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction |
title_fullStr | Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction |
title_full_unstemmed | Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction |
title_short | Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction |
title_sort | magnetic properties of well aligned zno nanorod arrays grown by a simple hydrothermal reaction |
url | http://dx.doi.org/10.1155/2014/627975 |
work_keys_str_mv | AT jiangniyun magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction AT ruiqu magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction AT zhiyongzhang magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction AT junli magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction |