Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction

Well-aligned ZnO nanorod arrays with room temperature ferromagnetism were prepared on glass substrate through hydrothermal method. The as-prepared nanorod arrays were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), photoluminescence...

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Main Authors: Jiangni Yun, Rui Qu, Zhiyong Zhang, Jun Li
Format: Article
Language:English
Published: Wiley 2014-01-01
Series:Advances in Condensed Matter Physics
Online Access:http://dx.doi.org/10.1155/2014/627975
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author Jiangni Yun
Rui Qu
Zhiyong Zhang
Jun Li
author_facet Jiangni Yun
Rui Qu
Zhiyong Zhang
Jun Li
author_sort Jiangni Yun
collection DOAJ
description Well-aligned ZnO nanorod arrays with room temperature ferromagnetism were prepared on glass substrate through hydrothermal method. The as-prepared nanorod arrays were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), photoluminescence (PL) spectrum, and magnetization measurements. The XRD and SEM results indicated that the ZnO nanorods are with the wurtzite structure and exhibit preferential (002) orientation with c-axis perpendicular to the substrate surface. The PL results suggested that the possible defect in the as-prepared ZnO nanorod arrays might be VZn, Oi, or OZn. The first-principles calculations reveal that the room temperature ferromagnetism may result from the VZn defects present in the ZnO nanorod and the hybridization of the Zn 3d states with O 2p states is responsible for the half-metallic ferromagnetism in ZnO nanorod.
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institution Kabale University
issn 1687-8108
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spelling doaj-art-dcc5fe6b68294678a9be721d561c55712025-02-03T05:59:31ZengWileyAdvances in Condensed Matter Physics1687-81081687-81242014-01-01201410.1155/2014/627975627975Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal ReactionJiangni Yun0Rui Qu1Zhiyong Zhang2Jun Li3School of Information Science and Technology, Northwest University, Xi’an 710127, ChinaSchool of Information Science and Technology, Northwest University, Xi’an 710127, ChinaSchool of Information Science and Technology, Northwest University, Xi’an 710127, ChinaSchool of Information Science and Technology, Northwest University, Xi’an 710127, ChinaWell-aligned ZnO nanorod arrays with room temperature ferromagnetism were prepared on glass substrate through hydrothermal method. The as-prepared nanorod arrays were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectroscopy (EDS), photoluminescence (PL) spectrum, and magnetization measurements. The XRD and SEM results indicated that the ZnO nanorods are with the wurtzite structure and exhibit preferential (002) orientation with c-axis perpendicular to the substrate surface. The PL results suggested that the possible defect in the as-prepared ZnO nanorod arrays might be VZn, Oi, or OZn. The first-principles calculations reveal that the room temperature ferromagnetism may result from the VZn defects present in the ZnO nanorod and the hybridization of the Zn 3d states with O 2p states is responsible for the half-metallic ferromagnetism in ZnO nanorod.http://dx.doi.org/10.1155/2014/627975
spellingShingle Jiangni Yun
Rui Qu
Zhiyong Zhang
Jun Li
Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction
Advances in Condensed Matter Physics
title Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction
title_full Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction
title_fullStr Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction
title_full_unstemmed Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction
title_short Magnetic Properties of Well-Aligned ZnO Nanorod Arrays Grown by a Simple Hydrothermal Reaction
title_sort magnetic properties of well aligned zno nanorod arrays grown by a simple hydrothermal reaction
url http://dx.doi.org/10.1155/2014/627975
work_keys_str_mv AT jiangniyun magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction
AT ruiqu magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction
AT zhiyongzhang magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction
AT junli magneticpropertiesofwellalignedznonanorodarraysgrownbyasimplehydrothermalreaction