Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis

This investigation focuses on the synergistic performance improvement in graphene/MWCNT reinforced Polyaryletherketone (PAEK) - carbon fiber (CF) multi-scale composites. FTIR revealed the chemical interactions while HRTEM, XRD and 3D X-ray microscopy gave insight into nanofiller dispersion and micro...

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Main Authors: Sarath Kumar Painkal, Meera Balachandran, Karingamanna Jayanarayanan, Nagaarjun Sridhar, Sanjeev Kumar
Format: Article
Language:English
Published: KeAi Communications Co., Ltd. 2025-01-01
Series:Advanced Industrial and Engineering Polymer Research
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Online Access:http://www.sciencedirect.com/science/article/pii/S2542504824000101
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author Sarath Kumar Painkal
Meera Balachandran
Karingamanna Jayanarayanan
Nagaarjun Sridhar
Sanjeev Kumar
author_facet Sarath Kumar Painkal
Meera Balachandran
Karingamanna Jayanarayanan
Nagaarjun Sridhar
Sanjeev Kumar
author_sort Sarath Kumar Painkal
collection DOAJ
description This investigation focuses on the synergistic performance improvement in graphene/MWCNT reinforced Polyaryletherketone (PAEK) - carbon fiber (CF) multi-scale composites. FTIR revealed the chemical interactions while HRTEM, XRD and 3D X-ray microscopy gave insight into nanofiller dispersion and microstructural features. The functional groups on nanofillers along with structural features integrated various components of the multi-scale composites by formation of graphene/MWCNT/CF complex network that provided larger interfacial area, bridging effect and physico-chemical interaction with PAEK while restricting its segmental mobility. Multi-scale composites displayed significantly improved strength, fracture toughness, interlaminar shear strength, glass transition temperature and tribological performance. Under dynamic load, graphene/MWCNT reinforcement of matrix and CF synergistically increases the storage modulus and energy absorption characteristics. Wear and fracture surface morphology of nano and multi-scale composites showed ductile failure confirming interfacial adhesion. The failure behavior in experimental studies was supported by Abaqus/Explicit-based FEM models of fracture toughness response. This work provides a promising avenue to develop next generation high performance thermoplastic composites for structural applications.
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institution Kabale University
issn 2542-5048
language English
publishDate 2025-01-01
publisher KeAi Communications Co., Ltd.
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series Advanced Industrial and Engineering Polymer Research
spelling doaj-art-dc4ee624f86b4f1fa0c2dce2350457112025-01-18T05:05:01ZengKeAi Communications Co., Ltd.Advanced Industrial and Engineering Polymer Research2542-50482025-01-01812036Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysisSarath Kumar Painkal0Meera Balachandran1Karingamanna Jayanarayanan2Nagaarjun Sridhar3Sanjeev Kumar4Department of Chemical Engineering and Materials Science, Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, India; Centre of Excellence in Advanced Materials & Green Technologies (CoE-AMGT), Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, IndiaDepartment of Chemical Engineering and Materials Science, Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, India; Centre of Excellence in Advanced Materials & Green Technologies (CoE-AMGT), Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, India; Corresponding author. Department of Chemical Engineering and Materials Science, Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, India.Department of Chemical Engineering and Materials Science, Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, India; Centre of Excellence in Advanced Materials & Green Technologies (CoE-AMGT), Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, India; Corresponding author. Department of Chemical Engineering and Materials Science, Amrita School of Engineering, Coimbatore Amrita Vishwa Vidyapeetham, 641112, India.Nagaarjun Sridhar, Research Microscopy Solutions, Carl Zeiss India (Bangalore) Pvt. Ltd., ZEISS Group, Bangalore, 560099, IndiaSanjeev Kumar, CASD, Vikram Sarabhai Space Centre, Thiruvananthapuram, 695022, IndiaThis investigation focuses on the synergistic performance improvement in graphene/MWCNT reinforced Polyaryletherketone (PAEK) - carbon fiber (CF) multi-scale composites. FTIR revealed the chemical interactions while HRTEM, XRD and 3D X-ray microscopy gave insight into nanofiller dispersion and microstructural features. The functional groups on nanofillers along with structural features integrated various components of the multi-scale composites by formation of graphene/MWCNT/CF complex network that provided larger interfacial area, bridging effect and physico-chemical interaction with PAEK while restricting its segmental mobility. Multi-scale composites displayed significantly improved strength, fracture toughness, interlaminar shear strength, glass transition temperature and tribological performance. Under dynamic load, graphene/MWCNT reinforcement of matrix and CF synergistically increases the storage modulus and energy absorption characteristics. Wear and fracture surface morphology of nano and multi-scale composites showed ductile failure confirming interfacial adhesion. The failure behavior in experimental studies was supported by Abaqus/Explicit-based FEM models of fracture toughness response. This work provides a promising avenue to develop next generation high performance thermoplastic composites for structural applications.http://www.sciencedirect.com/science/article/pii/S2542504824000101Polyaryletherketone (PAEK)Carbon fibersGrapheneMWCNTMulti-scale compositeFinite element analysis
spellingShingle Sarath Kumar Painkal
Meera Balachandran
Karingamanna Jayanarayanan
Nagaarjun Sridhar
Sanjeev Kumar
Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis
Advanced Industrial and Engineering Polymer Research
Polyaryletherketone (PAEK)
Carbon fibers
Graphene
MWCNT
Multi-scale composite
Finite element analysis
title Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis
title_full Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis
title_fullStr Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis
title_full_unstemmed Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis
title_short Synergistic enhancement in mechanical properties of graphene/MWCNT reinforced Polyaryletherketone – carbon fiber multi-scale composites: Experimental studies and finite element analysis
title_sort synergistic enhancement in mechanical properties of graphene mwcnt reinforced polyaryletherketone carbon fiber multi scale composites experimental studies and finite element analysis
topic Polyaryletherketone (PAEK)
Carbon fibers
Graphene
MWCNT
Multi-scale composite
Finite element analysis
url http://www.sciencedirect.com/science/article/pii/S2542504824000101
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