Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanones
A set of novel bicyclo[3.3.1]nonanones, namely, 4-methoxybicyclo[3.3.1]non-3-ene-2,9-dione, C10H12O3 (1), 4,9,9-trimethoxybicyclo[3.3.1]non-3-en-2-ol, C12H20O4 (2), 4-methoxy-6-methyl-1-(3-methylbut-2-en-1-yl)-6-(4-methylpent-3-en-1-yl)bicyclo[3.3.1]non-3-ene-2,9-dione, C22H32O3 (3) and 4-(tert-buty...
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| Format: | Article |
| Language: | English |
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International Union of Crystallography
2025-05-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025003299 |
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| author | Julien A. König Bernd Morgenstern Johann Jauch |
| author_facet | Julien A. König Bernd Morgenstern Johann Jauch |
| author_sort | Julien A. König |
| collection | DOAJ |
| description | A set of novel bicyclo[3.3.1]nonanones, namely, 4-methoxybicyclo[3.3.1]non-3-ene-2,9-dione, C10H12O3 (1), 4,9,9-trimethoxybicyclo[3.3.1]non-3-en-2-ol, C12H20O4 (2), 4-methoxy-6-methyl-1-(3-methylbut-2-en-1-yl)-6-(4-methylpent-3-en-1-yl)bicyclo[3.3.1]non-3-ene-2,9-dione, C22H32O3 (3) and 4-(tert-butyl)-4-hydroxy-2-methoxy-8-methyl-7-(3-methylbut-2-en-1-yl)-8-(4-methylpent-3-en-1-yl)bicyclo[3.3.1]non-2-en-9-one, C26H42O3 (4), were synthesized and structurally elucidated by NMR, HRMS and X-ray crystallography. |
| format | Article |
| id | doaj-art-dbdb4e5d9b244f3da5d85f3d445a682f |
| institution | DOAJ |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-05-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-dbdb4e5d9b244f3da5d85f3d445a682f2025-08-20T03:11:30ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-05-0181540541110.1107/S2056989025003299ev2016Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanonesJulien A. König0Bernd Morgenstern1Johann Jauch2Organic Chemistry II, Saarland University, 66123 Saarbrücken, GermanyService Center X-ray diffraction, Saarland University, 66123 Saarbrücken, GermanyOrganic Chemistry II, Saarland University, 66123 Saarbrücken, GermanyA set of novel bicyclo[3.3.1]nonanones, namely, 4-methoxybicyclo[3.3.1]non-3-ene-2,9-dione, C10H12O3 (1), 4,9,9-trimethoxybicyclo[3.3.1]non-3-en-2-ol, C12H20O4 (2), 4-methoxy-6-methyl-1-(3-methylbut-2-en-1-yl)-6-(4-methylpent-3-en-1-yl)bicyclo[3.3.1]non-3-ene-2,9-dione, C22H32O3 (3) and 4-(tert-butyl)-4-hydroxy-2-methoxy-8-methyl-7-(3-methylbut-2-en-1-yl)-8-(4-methylpent-3-en-1-yl)bicyclo[3.3.1]non-2-en-9-one, C26H42O3 (4), were synthesized and structurally elucidated by NMR, HRMS and X-ray crystallography.https://journals.iucr.org/paper?S2056989025003299polycyclicpolyprenylated acylphloroglucinolppapsbridgehead substitutioncarbocyclescrystal structure |
| spellingShingle | Julien A. König Bernd Morgenstern Johann Jauch Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanones Acta Crystallographica Section E: Crystallographic Communications polycyclic polyprenylated acylphloroglucinol ppaps bridgehead substitution carbocycles crystal structure |
| title | Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanones |
| title_full | Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanones |
| title_fullStr | Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanones |
| title_full_unstemmed | Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanones |
| title_short | Synthesis and crystal structure analysis of substituted bicyclo[3.3.1]nonanones |
| title_sort | synthesis and crystal structure analysis of substituted bicyclo 3 3 1 nonanones |
| topic | polycyclic polyprenylated acylphloroglucinol ppaps bridgehead substitution carbocycles crystal structure |
| url | https://journals.iucr.org/paper?S2056989025003299 |
| work_keys_str_mv | AT julienakonig synthesisandcrystalstructureanalysisofsubstitutedbicyclo331nonanones AT berndmorgenstern synthesisandcrystalstructureanalysisofsubstitutedbicyclo331nonanones AT johannjauch synthesisandcrystalstructureanalysisofsubstitutedbicyclo331nonanones |