Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide
The electrochemical behaviour of the complex of Cu(II) with 4-chlorobenzylidene-4-aminoacetanilide (CAA) was studied. It was observed that CAA forms 1:1 complex with Cu(II) in between pH 6.5 to 7.1. It was found that the reduction process of Cu(II)- CAA complex is two electron reversible reduction p...
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Wiley
2012-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2012/656598 |
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| author | Riyaz Ahmad Dar Krishna Kumar Raj |
| author_facet | Riyaz Ahmad Dar Krishna Kumar Raj |
| author_sort | Riyaz Ahmad Dar |
| collection | DOAJ |
| description | The electrochemical behaviour of the complex of Cu(II) with 4-chlorobenzylidene-4-aminoacetanilide (CAA) was studied. It was observed that CAA forms 1:1 complex with Cu(II) in between pH 6.5 to 7.1. It was found that the reduction process of Cu(II)- CAA complex is two electron reversible reduction process at D.M.E. The logarithm value of stability constant of Cu(II)-4-Chlorobenzylidene-4-aminoacetanilide (CAA) complex has been found to be 4.85.The redox properties of the complex was extensively investigated by electrochemical method using cyclic voltammetry (CV).The Cu(II) complexes exhibited quasi-reversible single electron transfer process.The Schiff base and its complex has been screened for their in-vitro antibacterial (Escherichiacoli, Staphylococcus aureus, Vibrio cholerae and Bacillus subtilis) and antifungal (Aspergillus niger and Penicillium liliacinum) activities by minimum inhibitory concentration (MIC) method. |
| format | Article |
| id | doaj-art-db6fbff5a64f47849e28338e002134c1 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2012-01-01 |
| publisher | Wiley |
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| series | E-Journal of Chemistry |
| spelling | doaj-art-db6fbff5a64f47849e28338e002134c12025-02-03T05:58:11ZengWileyE-Journal of Chemistry0973-49452090-98102012-01-019274975510.1155/2012/656598Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilideRiyaz Ahmad Dar0Krishna Kumar Raj1Chemical Technological Laboratory Department of Chemistry, Dr. H.S. Gour University, Sagar (M.P.), IndiaChemical Technological Laboratory Department of Chemistry, Dr. H.S. Gour University, Sagar (M.P.), IndiaThe electrochemical behaviour of the complex of Cu(II) with 4-chlorobenzylidene-4-aminoacetanilide (CAA) was studied. It was observed that CAA forms 1:1 complex with Cu(II) in between pH 6.5 to 7.1. It was found that the reduction process of Cu(II)- CAA complex is two electron reversible reduction process at D.M.E. The logarithm value of stability constant of Cu(II)-4-Chlorobenzylidene-4-aminoacetanilide (CAA) complex has been found to be 4.85.The redox properties of the complex was extensively investigated by electrochemical method using cyclic voltammetry (CV).The Cu(II) complexes exhibited quasi-reversible single electron transfer process.The Schiff base and its complex has been screened for their in-vitro antibacterial (Escherichiacoli, Staphylococcus aureus, Vibrio cholerae and Bacillus subtilis) and antifungal (Aspergillus niger and Penicillium liliacinum) activities by minimum inhibitory concentration (MIC) method.http://dx.doi.org/10.1155/2012/656598 |
| spellingShingle | Riyaz Ahmad Dar Krishna Kumar Raj Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide E-Journal of Chemistry |
| title | Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide |
| title_full | Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide |
| title_fullStr | Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide |
| title_full_unstemmed | Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide |
| title_short | Polarographic Determination and Antimicrobial Activity of Cu(II) Complex with 4-Chlorobenzylidene-4-aminoacetanilide |
| title_sort | polarographic determination and antimicrobial activity of cu ii complex with 4 chlorobenzylidene 4 aminoacetanilide |
| url | http://dx.doi.org/10.1155/2012/656598 |
| work_keys_str_mv | AT riyazahmaddar polarographicdeterminationandantimicrobialactivityofcuiicomplexwith4chlorobenzylidene4aminoacetanilide AT krishnakumarraj polarographicdeterminationandantimicrobialactivityofcuiicomplexwith4chlorobenzylidene4aminoacetanilide |