Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide Nanoparticles
This work introduces a Nafion-coated copper(I) oxide nanoparticle electrode (Nafion/Cu2O/GC) designed for the electrochemical detection of methanol (CH3OH). The responses of the composite material toward CH3OH were enhanced by the selective permeation of CH3OH through the hydrophilic channels of the...
Saved in:
| Main Authors: | , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2024-01-01
|
| Series: | Journal of Analytical Methods in Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2024/1809578 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832542982751911936 |
|---|---|
| author | Pantipa Sawatmuenwai Keerakit Kaewket Kamonwad Ngamchuea |
| author_facet | Pantipa Sawatmuenwai Keerakit Kaewket Kamonwad Ngamchuea |
| author_sort | Pantipa Sawatmuenwai |
| collection | DOAJ |
| description | This work introduces a Nafion-coated copper(I) oxide nanoparticle electrode (Nafion/Cu2O/GC) designed for the electrochemical detection of methanol (CH3OH). The responses of the composite material toward CH3OH were enhanced by the selective permeation of CH3OH through the hydrophilic channels of the Nafion membrane in combination with the electroactivity of Cu2O nanoparticles. The sensor displayed a linear detection range of 0.33–100 mM CH3OH with a sensitivity of 0.17 μA·mM−1 and a detection limit (3 s/m) of 0.10 mM. It exhibited excellent reproducibility with a relative standard deviation of <5%. The sensor’s practical applicability was demonstrated through recovery studies on hand sanitizer samples, achieving ca. 100% recovery. The sensor was further used to elucidate CH3OH adsorption on activated carbon, revealing that the process conforms to the Langmuir isotherm model. |
| format | Article |
| id | doaj-art-dae80d621bdd42eb9c168571237f3a17 |
| institution | Kabale University |
| issn | 2090-8873 |
| language | English |
| publishDate | 2024-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Analytical Methods in Chemistry |
| spelling | doaj-art-dae80d621bdd42eb9c168571237f3a172025-02-03T12:02:18ZengWileyJournal of Analytical Methods in Chemistry2090-88732024-01-01202410.1155/2024/1809578Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide NanoparticlesPantipa Sawatmuenwai0Keerakit Kaewket1Kamonwad Ngamchuea2School of ChemistrySchool of ChemistrySchool of ChemistryThis work introduces a Nafion-coated copper(I) oxide nanoparticle electrode (Nafion/Cu2O/GC) designed for the electrochemical detection of methanol (CH3OH). The responses of the composite material toward CH3OH were enhanced by the selective permeation of CH3OH through the hydrophilic channels of the Nafion membrane in combination with the electroactivity of Cu2O nanoparticles. The sensor displayed a linear detection range of 0.33–100 mM CH3OH with a sensitivity of 0.17 μA·mM−1 and a detection limit (3 s/m) of 0.10 mM. It exhibited excellent reproducibility with a relative standard deviation of <5%. The sensor’s practical applicability was demonstrated through recovery studies on hand sanitizer samples, achieving ca. 100% recovery. The sensor was further used to elucidate CH3OH adsorption on activated carbon, revealing that the process conforms to the Langmuir isotherm model.http://dx.doi.org/10.1155/2024/1809578 |
| spellingShingle | Pantipa Sawatmuenwai Keerakit Kaewket Kamonwad Ngamchuea Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide Nanoparticles Journal of Analytical Methods in Chemistry |
| title | Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide Nanoparticles |
| title_full | Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide Nanoparticles |
| title_fullStr | Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide Nanoparticles |
| title_full_unstemmed | Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide Nanoparticles |
| title_short | Electrochemical Analysis of Methanol with Nafion-Coated Copper Oxide Nanoparticles |
| title_sort | electrochemical analysis of methanol with nafion coated copper oxide nanoparticles |
| url | http://dx.doi.org/10.1155/2024/1809578 |
| work_keys_str_mv | AT pantipasawatmuenwai electrochemicalanalysisofmethanolwithnafioncoatedcopperoxidenanoparticles AT keerakitkaewket electrochemicalanalysisofmethanolwithnafioncoatedcopperoxidenanoparticles AT kamonwadngamchuea electrochemicalanalysisofmethanolwithnafioncoatedcopperoxidenanoparticles |