Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature Gradient

A stochastic energetics framework is applied to examine how periodically shifting the frequency of a time-dependent oscillating temperature gradient affects heat transport in a nanoscale molecular model. We specifically examine the effects that frequency switching, i.e., instantaneously changing the...

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Main Authors: Renai Chen, Galen T. Craven
Format: Article
Language:English
Published: MDPI AG 2024-12-01
Series:Entropy
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Online Access:https://www.mdpi.com/1099-4300/27/1/18
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author Renai Chen
Galen T. Craven
author_facet Renai Chen
Galen T. Craven
author_sort Renai Chen
collection DOAJ
description A stochastic energetics framework is applied to examine how periodically shifting the frequency of a time-dependent oscillating temperature gradient affects heat transport in a nanoscale molecular model. We specifically examine the effects that frequency switching, i.e., instantaneously changing the oscillation frequency of the temperature gradient, has on the shape of the heat transport hysteresis curves generated by a particle connected to two thermal baths, each with a temperature that is oscillating in time. Analytical expressions are derived for the energy fluxes in/out of the system and the baths, with excellent agreement observed between the analytical expressions and the results from nonequilibrium molecular dynamics simulations. We find that the shape of the heat transport hysteresis curves can be significantly altered by shifting the frequency between fast and slow oscillation regimes. We also observe the emergence of features in the hysteresis curves such as pinched loops and complex multi-loop patterns due to the frequency shifting. The presented results have implications in the design of thermal neuromorphic devices such as thermal memristors and thermal memcapacitors.
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spelling doaj-art-dab7ffeeefd047d283ae39eb72abf6c52025-01-24T13:31:41ZengMDPI AGEntropy1099-43002024-12-012711810.3390/e27010018Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature GradientRenai Chen0Galen T. Craven1Theoretical Division and Center for Nonlinear Studies, Los Alamos National Laboratory, Los Alamos, NM 87545, USATheoretical Division, Los Alamos National Laboratory, Los Alamos, NM 87545, USAA stochastic energetics framework is applied to examine how periodically shifting the frequency of a time-dependent oscillating temperature gradient affects heat transport in a nanoscale molecular model. We specifically examine the effects that frequency switching, i.e., instantaneously changing the oscillation frequency of the temperature gradient, has on the shape of the heat transport hysteresis curves generated by a particle connected to two thermal baths, each with a temperature that is oscillating in time. Analytical expressions are derived for the energy fluxes in/out of the system and the baths, with excellent agreement observed between the analytical expressions and the results from nonequilibrium molecular dynamics simulations. We find that the shape of the heat transport hysteresis curves can be significantly altered by shifting the frequency between fast and slow oscillation regimes. We also observe the emergence of features in the hysteresis curves such as pinched loops and complex multi-loop patterns due to the frequency shifting. The presented results have implications in the design of thermal neuromorphic devices such as thermal memristors and thermal memcapacitors.https://www.mdpi.com/1099-4300/27/1/18memristormemcapacitorheat transport
spellingShingle Renai Chen
Galen T. Craven
Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature Gradient
Entropy
memristor
memcapacitor
heat transport
title Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature Gradient
title_full Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature Gradient
title_fullStr Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature Gradient
title_full_unstemmed Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature Gradient
title_short Heat Transport Hysteresis Generated Through Frequency Switching of a Time-Dependent Temperature Gradient
title_sort heat transport hysteresis generated through frequency switching of a time dependent temperature gradient
topic memristor
memcapacitor
heat transport
url https://www.mdpi.com/1099-4300/27/1/18
work_keys_str_mv AT renaichen heattransporthysteresisgeneratedthroughfrequencyswitchingofatimedependenttemperaturegradient
AT galentcraven heattransporthysteresisgeneratedthroughfrequencyswitchingofatimedependenttemperaturegradient