Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole
A coordination complex of cadmium nitrate [Cd(NO3)2] with 2-aminobenzaxole (2AB; C7H6N2O), namely, tetrakis(2-aminobenzoxazole-κN1)bis(nitrato-κO)cadmium(II), [Cd(NO3)2(2AB)4], has been synthesized from ethanol solutions of Cd(NO3)2·H2O and 2AB. The asymmetric unit comprises half a molecule of [Cd(N...
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International Union of Crystallography
2025-06-01
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| Series: | Acta Crystallographica Section E: Crystallographic Communications |
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| Online Access: | https://journals.iucr.org/paper?S2056989025004049 |
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| author | Surayyo Razzoqova Yodgor Ruzimov Akobir Toshov Batirbay Torambetov Aziz Ibragimov Jamshid Ashurov Shakhnoza Kadirova |
| author_facet | Surayyo Razzoqova Yodgor Ruzimov Akobir Toshov Batirbay Torambetov Aziz Ibragimov Jamshid Ashurov Shakhnoza Kadirova |
| author_sort | Surayyo Razzoqova |
| collection | DOAJ |
| description | A coordination complex of cadmium nitrate [Cd(NO3)2] with 2-aminobenzaxole (2AB; C7H6N2O), namely, tetrakis(2-aminobenzoxazole-κN1)bis(nitrato-κO)cadmium(II), [Cd(NO3)2(2AB)4], has been synthesized from ethanol solutions of Cd(NO3)2·H2O and 2AB. The asymmetric unit comprises half a molecule of [Cd(NO3)2(2AB)4], with the CdII atom positioned on a twofold rotation axis. In the completed molecular complex, four 2AB ligands and two nitrate anions each coordinate monodentately to the CdII atom, leading to a distorted octahedral coordination environment. The crystal structure of [Cd(NO3)2(2AB)4] exhibits several N—H...O interactions, resulting in the formation of a layered assembly parallel to (001). Hishfeld surface analysis was used to quantify the intermolecular interactions. |
| format | Article |
| id | doaj-art-d9e860412cbc4e8f8f3cf583b4bb7d32 |
| institution | OA Journals |
| issn | 2056-9890 |
| language | English |
| publishDate | 2025-06-01 |
| publisher | International Union of Crystallography |
| record_format | Article |
| series | Acta Crystallographica Section E: Crystallographic Communications |
| spelling | doaj-art-d9e860412cbc4e8f8f3cf583b4bb7d322025-08-20T02:32:12ZengInternational Union of CrystallographyActa Crystallographica Section E: Crystallographic Communications2056-98902025-06-0181648248510.1107/S2056989025004049wm5756Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazoleSurayyo Razzoqova0Yodgor Ruzimov1Akobir Toshov2Batirbay Torambetov3Aziz Ibragimov4Jamshid Ashurov5Shakhnoza Kadirova6National University of Uzbekistan named after Mirzo Ulugbek, 4 University St., Tashkent, 100174, UzbekistanKhorezm Mamun branch of Uzbekistan Academy of Sciences, 1, Markaz St., Khiva, 220900, UzbekistanNational University of Uzbekistan named after Mirzo Ulugbek, 4 University St., Tashkent, 100174, UzbekistanNational University of Uzbekistan named after Mirzo Ulugbek, 4 University St., Tashkent, 100174, UzbekistanInstitute of General and Inorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek Str 77a, Tashkent 100170, UzbekistanInstitute of Bioorganic Chemistry, Academy of Sciences of Uzbekistan, M. Ulugbek, St, 83, Tashkent, 100125, UzbekistanNational University of Uzbekistan named after Mirzo Ulugbek, 4 University St., Tashkent, 100174, UzbekistanA coordination complex of cadmium nitrate [Cd(NO3)2] with 2-aminobenzaxole (2AB; C7H6N2O), namely, tetrakis(2-aminobenzoxazole-κN1)bis(nitrato-κO)cadmium(II), [Cd(NO3)2(2AB)4], has been synthesized from ethanol solutions of Cd(NO3)2·H2O and 2AB. The asymmetric unit comprises half a molecule of [Cd(NO3)2(2AB)4], with the CdII atom positioned on a twofold rotation axis. In the completed molecular complex, four 2AB ligands and two nitrate anions each coordinate monodentately to the CdII atom, leading to a distorted octahedral coordination environment. The crystal structure of [Cd(NO3)2(2AB)4] exhibits several N—H...O interactions, resulting in the formation of a layered assembly parallel to (001). Hishfeld surface analysis was used to quantify the intermolecular interactions.https://journals.iucr.org/paper?S2056989025004049crystal structuremolecular structurecadmium complex2-aminobenzoxazoleoctahedral coordination |
| spellingShingle | Surayyo Razzoqova Yodgor Ruzimov Akobir Toshov Batirbay Torambetov Aziz Ibragimov Jamshid Ashurov Shakhnoza Kadirova Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole Acta Crystallographica Section E: Crystallographic Communications crystal structure molecular structure cadmium complex 2-aminobenzoxazole octahedral coordination |
| title | Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole |
| title_full | Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole |
| title_fullStr | Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole |
| title_full_unstemmed | Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole |
| title_short | Synthesis, crystal structure and Hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2-aminobenzoxazole |
| title_sort | synthesis crystal structure and hirshfeld surface analysis of a coordination compound of cadmium nitrate with 2 aminobenzoxazole |
| topic | crystal structure molecular structure cadmium complex 2-aminobenzoxazole octahedral coordination |
| url | https://journals.iucr.org/paper?S2056989025004049 |
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