Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive Components

Olive oil is the main fat source of the Mediterranean diet. This seasoning ingredient is highly appreciated for its unique taste, functional properties, and positive impact on human health. The determination of chemical composition is a demanding task in order to fully characterize this precious foo...

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Main Authors: C. Camerlingo, M. Portaccio, I. Delfino, M. Lepore
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2019/9537419
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author C. Camerlingo
M. Portaccio
I. Delfino
M. Lepore
author_facet C. Camerlingo
M. Portaccio
I. Delfino
M. Lepore
author_sort C. Camerlingo
collection DOAJ
description Olive oil is the main fat source of the Mediterranean diet. This seasoning ingredient is highly appreciated for its unique taste, functional properties, and positive impact on human health. The determination of chemical composition is a demanding task in order to fully characterize this precious food product, ensure its quality, and prevent fraudulent practices. Among innovative techniques proposed for the oil analysis, surface-enhanced Raman spectroscopy (SERS) can be an extremely useful tool for olive oil characterization. In this frame, we have investigated five noncommercial olive oils produced in different parts of South Italy by using a commercial Raman microspectroscopy apparatus and home-made signal-enhancing SERS substrates. A wavelet-based data analysis has allowed us to efficiently remove the background and the noise from the acquired spectra. The analysis of these SERS spectra has enabled the quantification of the relative contents of carotene, oleic acid, and phenols. These relative contents differ in the examined samples. In addition, SERS response in the lipid region has indicated differences in the relative abundance of saturated fatty acids. The present results confirm the validity of the SERS technique as a rapid, nondestructive, and reliable analytical technique for identifying olive oil bioactive components.
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spelling doaj-art-d99fa7b5068140e1ac344fe97f76d6cb2025-02-03T05:58:53ZengWileyJournal of Chemistry2090-90632090-90712019-01-01201910.1155/2019/95374199537419Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive ComponentsC. Camerlingo0M. Portaccio1I. Delfino2M. Lepore3CNR-SPIN, Pozzuoli, ItalyDipartimento di Medicina Sperimentale, Università della Campania “Luigi Vanvitelli”, Napoli, ItalyDipartimento di Scienze Ecologiche e Biologiche, Università della Tuscia, Viterbo, ItalyDipartimento di Medicina Sperimentale, Università della Campania “Luigi Vanvitelli”, Napoli, ItalyOlive oil is the main fat source of the Mediterranean diet. This seasoning ingredient is highly appreciated for its unique taste, functional properties, and positive impact on human health. The determination of chemical composition is a demanding task in order to fully characterize this precious food product, ensure its quality, and prevent fraudulent practices. Among innovative techniques proposed for the oil analysis, surface-enhanced Raman spectroscopy (SERS) can be an extremely useful tool for olive oil characterization. In this frame, we have investigated five noncommercial olive oils produced in different parts of South Italy by using a commercial Raman microspectroscopy apparatus and home-made signal-enhancing SERS substrates. A wavelet-based data analysis has allowed us to efficiently remove the background and the noise from the acquired spectra. The analysis of these SERS spectra has enabled the quantification of the relative contents of carotene, oleic acid, and phenols. These relative contents differ in the examined samples. In addition, SERS response in the lipid region has indicated differences in the relative abundance of saturated fatty acids. The present results confirm the validity of the SERS technique as a rapid, nondestructive, and reliable analytical technique for identifying olive oil bioactive components.http://dx.doi.org/10.1155/2019/9537419
spellingShingle C. Camerlingo
M. Portaccio
I. Delfino
M. Lepore
Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive Components
Journal of Chemistry
title Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive Components
title_full Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive Components
title_fullStr Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive Components
title_full_unstemmed Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive Components
title_short Surface-Enhanced Raman Spectroscopy for Monitoring Extravirgin Olive Oil Bioactive Components
title_sort surface enhanced raman spectroscopy for monitoring extravirgin olive oil bioactive components
url http://dx.doi.org/10.1155/2019/9537419
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AT mportaccio surfaceenhancedramanspectroscopyformonitoringextravirginoliveoilbioactivecomponents
AT idelfino surfaceenhancedramanspectroscopyformonitoringextravirginoliveoilbioactivecomponents
AT mlepore surfaceenhancedramanspectroscopyformonitoringextravirginoliveoilbioactivecomponents