Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate

This study investigated the conditions for bioadsorption of copper(II) using Halmahera marine algae (Sargassum turbinarioides) encapsulated with calcium alginate by batch method. Physicochemical parameters of biosorption, including contact time, biosorbent mass, pH, and copper(II) concentration, wer...

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Main Authors: Dede Ardiansyah Takdir Abubakar Sanawi, Barlah Rumhayati, Qonitah Fardiyah
Format: Article
Language:English
Published: Department of Chemistry, Universitas Gadjah Mada 2025-01-01
Series:Indonesian Journal of Chemistry
Subjects:
Online Access:https://jurnal.ugm.ac.id/ijc/article/view/99090
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author Dede Ardiansyah Takdir Abubakar Sanawi
Barlah Rumhayati
Qonitah Fardiyah
author_facet Dede Ardiansyah Takdir Abubakar Sanawi
Barlah Rumhayati
Qonitah Fardiyah
author_sort Dede Ardiansyah Takdir Abubakar Sanawi
collection DOAJ
description This study investigated the conditions for bioadsorption of copper(II) using Halmahera marine algae (Sargassum turbinarioides) encapsulated with calcium alginate by batch method. Physicochemical parameters of biosorption, including contact time, biosorbent mass, pH, and copper(II) concentration, were studied to determine the percentage of copper(II) adsorbed. The maximum percentage of copper(II) bioadsorption was 96.4% under the optimum bioadsorption conditions with a contact time of 90 min, a biosorbent mass of 2 g, a solution pH of 5, and a copper(II) concentration of 60 mg/L. The bioadsorption isotherm study showed that the Langmuir model is more suitable for modeling copper(II) bioadsorption, while the bioadsorption kinetics study showed a pseudo-second-order kinetic model. Characterization of the biosorbent using FTIR showed that the biosorbent has active functional groups such as O–H, C–H, S–H, C=O, S=O, and C–O–C, which act as metal ligands, and SEM characterization showed morphological changes in the biosorbent before and after the copper(II) bioadsorption process.
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institution Kabale University
issn 1411-9420
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language English
publishDate 2025-01-01
publisher Department of Chemistry, Universitas Gadjah Mada
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series Indonesian Journal of Chemistry
spelling doaj-art-d8bfe461e98d4b1c96ac5b23a504946e2025-02-03T04:32:43ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782025-01-0125114515610.22146/ijc.9909036578Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium AlginateDede Ardiansyah Takdir Abubakar Sanawi0Barlah Rumhayati1Qonitah Fardiyah2Postgraduate Program, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Brawijaya, Jl. Veteran, Malang 65145, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Brawijaya, Jl. Veteran, Malang 65145, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Brawijaya, Jl. Veteran, Malang 65145, IndonesiaThis study investigated the conditions for bioadsorption of copper(II) using Halmahera marine algae (Sargassum turbinarioides) encapsulated with calcium alginate by batch method. Physicochemical parameters of biosorption, including contact time, biosorbent mass, pH, and copper(II) concentration, were studied to determine the percentage of copper(II) adsorbed. The maximum percentage of copper(II) bioadsorption was 96.4% under the optimum bioadsorption conditions with a contact time of 90 min, a biosorbent mass of 2 g, a solution pH of 5, and a copper(II) concentration of 60 mg/L. The bioadsorption isotherm study showed that the Langmuir model is more suitable for modeling copper(II) bioadsorption, while the bioadsorption kinetics study showed a pseudo-second-order kinetic model. Characterization of the biosorbent using FTIR showed that the biosorbent has active functional groups such as O–H, C–H, S–H, C=O, S=O, and C–O–C, which act as metal ligands, and SEM characterization showed morphological changes in the biosorbent before and after the copper(II) bioadsorption process.https://jurnal.ugm.ac.id/ijc/article/view/99090bioadsorptioncopper(ii)s. turbinariodesencapsulationca-alginate
spellingShingle Dede Ardiansyah Takdir Abubakar Sanawi
Barlah Rumhayati
Qonitah Fardiyah
Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate
Indonesian Journal of Chemistry
bioadsorption
copper(ii)
s. turbinariodes
encapsulation
ca-alginate
title Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate
title_full Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate
title_fullStr Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate
title_full_unstemmed Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate
title_short Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate
title_sort bioadsorption of copper ii using halmahera specific marine algae i sargassum turbinarioides i encapsulated calcium alginate
topic bioadsorption
copper(ii)
s. turbinariodes
encapsulation
ca-alginate
url https://jurnal.ugm.ac.id/ijc/article/view/99090
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AT qonitahfardiyah bioadsorptionofcopperiiusinghalmaheraspecificmarinealgaeisargassumturbinarioidesiencapsulatedcalciumalginate