Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate
This study investigated the conditions for bioadsorption of copper(II) using Halmahera marine algae (Sargassum turbinarioides) encapsulated with calcium alginate by batch method. Physicochemical parameters of biosorption, including contact time, biosorbent mass, pH, and copper(II) concentration, wer...
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Department of Chemistry, Universitas Gadjah Mada
2025-01-01
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Series: | Indonesian Journal of Chemistry |
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Online Access: | https://jurnal.ugm.ac.id/ijc/article/view/99090 |
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author | Dede Ardiansyah Takdir Abubakar Sanawi Barlah Rumhayati Qonitah Fardiyah |
author_facet | Dede Ardiansyah Takdir Abubakar Sanawi Barlah Rumhayati Qonitah Fardiyah |
author_sort | Dede Ardiansyah Takdir Abubakar Sanawi |
collection | DOAJ |
description | This study investigated the conditions for bioadsorption of copper(II) using Halmahera marine algae (Sargassum turbinarioides) encapsulated with calcium alginate by batch method. Physicochemical parameters of biosorption, including contact time, biosorbent mass, pH, and copper(II) concentration, were studied to determine the percentage of copper(II) adsorbed. The maximum percentage of copper(II) bioadsorption was 96.4% under the optimum bioadsorption conditions with a contact time of 90 min, a biosorbent mass of 2 g, a solution pH of 5, and a copper(II) concentration of 60 mg/L. The bioadsorption isotherm study showed that the Langmuir model is more suitable for modeling copper(II) bioadsorption, while the bioadsorption kinetics study showed a pseudo-second-order kinetic model. Characterization of the biosorbent using FTIR showed that the biosorbent has active functional groups such as O–H, C–H, S–H, C=O, S=O, and C–O–C, which act as metal ligands, and SEM characterization showed morphological changes in the biosorbent before and after the copper(II) bioadsorption process. |
format | Article |
id | doaj-art-d8bfe461e98d4b1c96ac5b23a504946e |
institution | Kabale University |
issn | 1411-9420 2460-1578 |
language | English |
publishDate | 2025-01-01 |
publisher | Department of Chemistry, Universitas Gadjah Mada |
record_format | Article |
series | Indonesian Journal of Chemistry |
spelling | doaj-art-d8bfe461e98d4b1c96ac5b23a504946e2025-02-03T04:32:43ZengDepartment of Chemistry, Universitas Gadjah MadaIndonesian Journal of Chemistry1411-94202460-15782025-01-0125114515610.22146/ijc.9909036578Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium AlginateDede Ardiansyah Takdir Abubakar Sanawi0Barlah Rumhayati1Qonitah Fardiyah2Postgraduate Program, Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Brawijaya, Jl. Veteran, Malang 65145, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Brawijaya, Jl. Veteran, Malang 65145, IndonesiaDepartment of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Brawijaya, Jl. Veteran, Malang 65145, IndonesiaThis study investigated the conditions for bioadsorption of copper(II) using Halmahera marine algae (Sargassum turbinarioides) encapsulated with calcium alginate by batch method. Physicochemical parameters of biosorption, including contact time, biosorbent mass, pH, and copper(II) concentration, were studied to determine the percentage of copper(II) adsorbed. The maximum percentage of copper(II) bioadsorption was 96.4% under the optimum bioadsorption conditions with a contact time of 90 min, a biosorbent mass of 2 g, a solution pH of 5, and a copper(II) concentration of 60 mg/L. The bioadsorption isotherm study showed that the Langmuir model is more suitable for modeling copper(II) bioadsorption, while the bioadsorption kinetics study showed a pseudo-second-order kinetic model. Characterization of the biosorbent using FTIR showed that the biosorbent has active functional groups such as O–H, C–H, S–H, C=O, S=O, and C–O–C, which act as metal ligands, and SEM characterization showed morphological changes in the biosorbent before and after the copper(II) bioadsorption process.https://jurnal.ugm.ac.id/ijc/article/view/99090bioadsorptioncopper(ii)s. turbinariodesencapsulationca-alginate |
spellingShingle | Dede Ardiansyah Takdir Abubakar Sanawi Barlah Rumhayati Qonitah Fardiyah Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate Indonesian Journal of Chemistry bioadsorption copper(ii) s. turbinariodes encapsulation ca-alginate |
title | Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate |
title_full | Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate |
title_fullStr | Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate |
title_full_unstemmed | Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate |
title_short | Bioadsorption of Copper(II) Using Halmahera Specific Marine Algae (<i>Sargassum turbinarioides</i>) Encapsulated Calcium Alginate |
title_sort | bioadsorption of copper ii using halmahera specific marine algae i sargassum turbinarioides i encapsulated calcium alginate |
topic | bioadsorption copper(ii) s. turbinariodes encapsulation ca-alginate |
url | https://jurnal.ugm.ac.id/ijc/article/view/99090 |
work_keys_str_mv | AT dedeardiansyahtakdirabubakarsanawi bioadsorptionofcopperiiusinghalmaheraspecificmarinealgaeisargassumturbinarioidesiencapsulatedcalciumalginate AT barlahrumhayati bioadsorptionofcopperiiusinghalmaheraspecificmarinealgaeisargassumturbinarioidesiencapsulatedcalciumalginate AT qonitahfardiyah bioadsorptionofcopperiiusinghalmaheraspecificmarinealgaeisargassumturbinarioidesiencapsulatedcalciumalginate |