Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel process
Abstract Zinc oxide nanoparticles (ZnO NPs) are prepared by sol–gel process, using both polyethylene glycol (PEG-400) as surfactant and propyltrimethoxysilane (PTMS) as capping agent. Surface modification is performed in situ procedure. The physical parameters such as strain and stress values are ca...
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| Format: | Article |
| Language: | English |
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Oxford International Collaboration Centre Press (OICC press)
2018-10-01
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| Series: | Journal of Theoretical and Applied Physics |
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| Online Access: | http://link.springer.com/article/10.1007/s40094-018-0303-2 |
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| author | Djahnit Leila López-González Mar Belhadj Fatima Naitbouda Abddelyamine Benosmane Ali Haddaoui Nacereddine |
| author_facet | Djahnit Leila López-González Mar Belhadj Fatima Naitbouda Abddelyamine Benosmane Ali Haddaoui Nacereddine |
| author_sort | Djahnit Leila |
| collection | DOAJ |
| description | Abstract Zinc oxide nanoparticles (ZnO NPs) are prepared by sol–gel process, using both polyethylene glycol (PEG-400) as surfactant and propyltrimethoxysilane (PTMS) as capping agent. Surface modification is performed in situ procedure. The physical parameters such as strain and stress values are calculated via the Williamson–Hall plot (W&H) assuming a uniform deformation model (UDM) and uniform stress deformation model, and by the size and strain plot method (SSP). The results show that the crystallite size estimated from Scherrer’s formula, (W&H), (UDM), (SSP) and the particle size estimated from DSL are inter-correlated, which confirm the small size and the isotropic nature of our ZnO NPs. The FTIR spectroscopy illustrates that PEG-400 and PTMS could be adsorbed at the ZnO NPs surface. The distinct emission peak in the blue band is located at 490 nm and E 2 (high) mode is situated at 436 cm−1. Both results confirm the oxygen deficiency in the ZnO NPs. |
| format | Article |
| id | doaj-art-d6ddcfdf2bdd44969f458ffb6a4e3610 |
| institution | Kabale University |
| issn | 2251-7227 2251-7235 |
| language | English |
| publishDate | 2018-10-01 |
| publisher | Oxford International Collaboration Centre Press (OICC press) |
| record_format | Article |
| series | Journal of Theoretical and Applied Physics |
| spelling | doaj-art-d6ddcfdf2bdd44969f458ffb6a4e36102025-08-20T03:49:04ZengOxford International Collaboration Centre Press (OICC press)Journal of Theoretical and Applied Physics2251-72272251-72352018-10-0112315916710.1007/s40094-018-0303-2Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel processDjahnit Leila0López-González Mar1Belhadj Fatima2Naitbouda Abddelyamine3Benosmane Ali4Haddaoui Nacereddine5Laboratoire de Physico-Chimie des Hauts Polymères, Université de Ferhat Abbes, Sétif-1Instituto de Ciencia y Tecnología de Polímeros (ICTP-CSIC)Département de Chimie, Université de Hassiba BenboualiCentre de Développement des Technologies AvancéesDépartement de Chimie, Université de Hassiba BenboualiLaboratoire de Physico-Chimie des Hauts Polymères, Université de Ferhat Abbes, Sétif-1Abstract Zinc oxide nanoparticles (ZnO NPs) are prepared by sol–gel process, using both polyethylene glycol (PEG-400) as surfactant and propyltrimethoxysilane (PTMS) as capping agent. Surface modification is performed in situ procedure. The physical parameters such as strain and stress values are calculated via the Williamson–Hall plot (W&H) assuming a uniform deformation model (UDM) and uniform stress deformation model, and by the size and strain plot method (SSP). The results show that the crystallite size estimated from Scherrer’s formula, (W&H), (UDM), (SSP) and the particle size estimated from DSL are inter-correlated, which confirm the small size and the isotropic nature of our ZnO NPs. The FTIR spectroscopy illustrates that PEG-400 and PTMS could be adsorbed at the ZnO NPs surface. The distinct emission peak in the blue band is located at 490 nm and E 2 (high) mode is situated at 436 cm−1. Both results confirm the oxygen deficiency in the ZnO NPs.http://link.springer.com/article/10.1007/s40094-018-0303-2Sol–gel synthesisZinc oxidePEG-400PropyltrimethoxysilaneNanoparticlesDRX |
| spellingShingle | Djahnit Leila López-González Mar Belhadj Fatima Naitbouda Abddelyamine Benosmane Ali Haddaoui Nacereddine Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel process Journal of Theoretical and Applied Physics Sol–gel synthesis Zinc oxide PEG-400 Propyltrimethoxysilane Nanoparticles DRX |
| title | Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel process |
| title_full | Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel process |
| title_fullStr | Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel process |
| title_full_unstemmed | Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel process |
| title_short | Effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol–gel process |
| title_sort | effect of polyethylene glycol and propyltrimethoxysilane on structural and optical properties of zinc oxide nanoparticles synthesized by sol gel process |
| topic | Sol–gel synthesis Zinc oxide PEG-400 Propyltrimethoxysilane Nanoparticles DRX |
| url | http://link.springer.com/article/10.1007/s40094-018-0303-2 |
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