Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS Films

A study on the influence of alkaline treatment on the properties of poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT: PSS) film is presented in this paper. The treatment is carried out using ammonia water (AW) solutions with various volumes. We have also examined the performance of o...

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Main Authors: Jiao Li, Hua Zhang, Juncheng Liu, Hui Qi
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/598903
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author Jiao Li
Hua Zhang
Juncheng Liu
Hui Qi
author_facet Jiao Li
Hua Zhang
Juncheng Liu
Hui Qi
author_sort Jiao Li
collection DOAJ
description A study on the influence of alkaline treatment on the properties of poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT: PSS) film is presented in this paper. The treatment is carried out using ammonia water (AW) solutions with various volumes. We have also examined the performance of organic solar cells (OSCs) with the undoped and AW-doped PEDOT:PSS layers. Results show that the acidity of PEDOT:PSS solution can be significantly reduced by adding the AW solution with the optimized volume ratio ≤9%, v/v, while the AW-doped PEDOT:PSS film shows an improved optical transmission and stabilized conductivity. However, compared to the pristine OSC without adding AW to the whole-extraction layer, the AW-doped OSC shows a slight degradation in the power conversion efficiency (from 2.12% to 2.02%), which has been attributed to the decreased Vo c and FF of devices after the addition of AW.
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issn 1110-662X
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language English
publishDate 2012-01-01
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series International Journal of Photoenergy
spelling doaj-art-d6a441185e9d492c95bd53c873c2cb2b2025-02-03T01:11:45ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/598903598903Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS FilmsJiao Li0Hua Zhang1Juncheng Liu2Hui Qi3School of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, ChinaSchool of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, ChinaSchool of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, ChinaSchool of Materials Science and Engineering, Shandong University of Technology, Zibo 255049, ChinaA study on the influence of alkaline treatment on the properties of poly(3,4-ethylenedioxythiophene):poly(4-styrenesulfonate) (PEDOT: PSS) film is presented in this paper. The treatment is carried out using ammonia water (AW) solutions with various volumes. We have also examined the performance of organic solar cells (OSCs) with the undoped and AW-doped PEDOT:PSS layers. Results show that the acidity of PEDOT:PSS solution can be significantly reduced by adding the AW solution with the optimized volume ratio ≤9%, v/v, while the AW-doped PEDOT:PSS film shows an improved optical transmission and stabilized conductivity. However, compared to the pristine OSC without adding AW to the whole-extraction layer, the AW-doped OSC shows a slight degradation in the power conversion efficiency (from 2.12% to 2.02%), which has been attributed to the decreased Vo c and FF of devices after the addition of AW.http://dx.doi.org/10.1155/2012/598903
spellingShingle Jiao Li
Hua Zhang
Juncheng Liu
Hui Qi
Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS Films
International Journal of Photoenergy
title Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS Films
title_full Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS Films
title_fullStr Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS Films
title_full_unstemmed Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS Films
title_short Influence of Alkaline Treatment with Ammonia Water on the Properties of PEDOT: PSS Films
title_sort influence of alkaline treatment with ammonia water on the properties of pedot pss films
url http://dx.doi.org/10.1155/2012/598903
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AT huiqi influenceofalkalinetreatmentwithammoniawateronthepropertiesofpedotpssfilms