Synthesis and Characterization of Trivalent Cerium Complexes of p-tert-Butylcalix[4,6,8]Arenes: Effect of Organic Solvents

Reaction of Ce3+ with p-tert-butylcalix[n]arene (n=4,6,8) yields purple crystalline complexes structurally as [Ce(p-tert-butylcalix[4]arene-3H)2(NO3)(DMF)x](2 − x)DMF (1), [Ce(p-tert-butylcalix[6]arene-4H)2(NO3)(DMF)x](3 − x)DMF (2), and [Ce(p-tert-butylcalix[8]arene-7H)2(NO3)(DMF)6] (3), where DMF=...

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Bibliographic Details
Main Author: Md. Hasan Zahir
Format: Article
Language:English
Published: Wiley 2013-01-01
Series:Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2013/494392
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