Luminescence and a new approach for detecting heat treatment of geuda sapphire

<p>For decades, unraveling the heat treatment of sapphire has been a challenging issue. The present study offers new aspects that support the detection of heat treatment of sapphire. Natural geuda sapphire exhibits orange to red luminescence under longwave ultraviolet (LWUV; 365 nm) light, whi...

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Main Authors: T. Pluthametwisute, L. Nasdala, C. Chanmuang N., M. Wildner, E. Libowitzky, G. Giester, E. G. Zoysa, C. Jakkawanvibul, W. Suwanmanee, T. Sripoonjan, T. Tengchaisri, B. Wanthanachaisaeng, C. Sutthirat
Format: Article
Language:English
Published: Copernicus Publications 2025-01-01
Series:Solid Earth
Online Access:https://se.copernicus.org/articles/16/81/2025/se-16-81-2025.pdf
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Summary:<p>For decades, unraveling the heat treatment of sapphire has been a challenging issue. The present study offers new aspects that support the detection of heat treatment of sapphire. Natural geuda sapphire exhibits orange to red luminescence under longwave ultraviolet (LWUV; 365 nm) light, while heated geuda sapphire shows blue luminescence under shortwave ultraviolet (SWUV; 225 nm) light. The presence of melt inclusions in dissolved silks serves as an indicator of sapphire heat treatment. Fourier-transform infrared (FTIR) spectroscopy alone is insufficient for distinguishing unheated from heated sapphire. By combining orange to red luminescence with blue luminescence and melt inclusions, we provide a practical method for accurately differentiating natural gem-quality sapphire and heated gem-quality sapphire.</p>
ISSN:1869-9510
1869-9529