The fluorescence analysis of laser photolysis of phenols in water
Photolysis of phenol and p-chlorophenol exposed to KrCl- and Nd-YAG laser light is studied by electron spectroscopy and fluorescence and quantum chemical techniques. The decrease of the quantum yield of phenol fluorescence with increase in the excitation energy is not related to dynamic changes in t...
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| Main Authors: | , , , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2002-01-01
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| Series: | International Journal of Photoenergy |
| Online Access: | http://dx.doi.org/10.1155/S1110662X02000120 |
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| author | O. Tchaikovskaya I. Sokolova O. Bazyl V. Swetlichnyi T. Kopylova G. Mayer N. Sultimova |
| author_facet | O. Tchaikovskaya I. Sokolova O. Bazyl V. Swetlichnyi T. Kopylova G. Mayer N. Sultimova |
| author_sort | O. Tchaikovskaya |
| collection | DOAJ |
| description | Photolysis of phenol and p-chlorophenol exposed to KrCl- and Nd-YAG laser light is studied
by electron spectroscopy and fluorescence and quantum chemical techniques. The decrease of the quantum
yield of phenol fluorescence with increase in the excitation energy is not related to dynamic changes in
the intramolecular photophysical processes; rather this is a result of increased photoreaction efficiency.
Chlorine substitution for para-state of phenol is shown to strengthen the OH-bond in excitation into the
long wavelength absorption band. |
| format | Article |
| id | doaj-art-d54dbcbec6654e9cac63dd28ab4f0287 |
| institution | Kabale University |
| issn | 1110-662X |
| language | English |
| publishDate | 2002-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Photoenergy |
| spelling | doaj-art-d54dbcbec6654e9cac63dd28ab4f02872025-02-03T01:12:33ZengWileyInternational Journal of Photoenergy1110-662X2002-01-0142798310.1155/S1110662X02000120The fluorescence analysis of laser photolysis of phenols in waterO. Tchaikovskaya0I. Sokolova1O. Bazyl2V. Swetlichnyi3T. Kopylova4G. Mayer5N. Sultimova6Siberian Physical Technical Institute, 1, Novo-Sobornaia sq., Tomsk 634050, RussiaSiberian Physical Technical Institute, 1, Novo-Sobornaia sq., Tomsk 634050, RussiaSiberian Physical Technical Institute, 1, Novo-Sobornaia sq., Tomsk 634050, RussiaSiberian Physical Technical Institute, 1, Novo-Sobornaia sq., Tomsk 634050, RussiaSiberian Physical Technical Institute, 1, Novo-Sobornaia sq., Tomsk 634050, RussiaTomsk State University, 36, Lenin av, Tomsk 634050, RussiaTomsk State University, 36, Lenin av, Tomsk 634050, RussiaPhotolysis of phenol and p-chlorophenol exposed to KrCl- and Nd-YAG laser light is studied by electron spectroscopy and fluorescence and quantum chemical techniques. The decrease of the quantum yield of phenol fluorescence with increase in the excitation energy is not related to dynamic changes in the intramolecular photophysical processes; rather this is a result of increased photoreaction efficiency. Chlorine substitution for para-state of phenol is shown to strengthen the OH-bond in excitation into the long wavelength absorption band.http://dx.doi.org/10.1155/S1110662X02000120 |
| spellingShingle | O. Tchaikovskaya I. Sokolova O. Bazyl V. Swetlichnyi T. Kopylova G. Mayer N. Sultimova The fluorescence analysis of laser photolysis of phenols in water International Journal of Photoenergy |
| title | The fluorescence analysis of laser photolysis of phenols in water |
| title_full | The fluorescence analysis of laser photolysis of phenols in water |
| title_fullStr | The fluorescence analysis of laser photolysis of phenols in water |
| title_full_unstemmed | The fluorescence analysis of laser photolysis of phenols in water |
| title_short | The fluorescence analysis of laser photolysis of phenols in water |
| title_sort | fluorescence analysis of laser photolysis of phenols in water |
| url | http://dx.doi.org/10.1155/S1110662X02000120 |
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