Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blends
Abstract Polypropylene (PP) offers numerous benefits to industrial applications due to its excellent processability and cost‐effectiveness. However, the widespread utilization of this commodity thermoplastic is constrained by its inherently low‐impact resistance. Herein, we suggest a ternary system...
Saved in:
| Main Authors: | , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2025-01-01
|
| Series: | SPE Polymers |
| Subjects: | |
| Online Access: | https://doi.org/10.1002/pls2.10162 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832582709561524224 |
|---|---|
| author | Nariman Rajabifar Payam Yazdandoost Parnian Gholami Dastnaei Amir Rostami |
| author_facet | Nariman Rajabifar Payam Yazdandoost Parnian Gholami Dastnaei Amir Rostami |
| author_sort | Nariman Rajabifar |
| collection | DOAJ |
| description | Abstract Polypropylene (PP) offers numerous benefits to industrial applications due to its excellent processability and cost‐effectiveness. However, the widespread utilization of this commodity thermoplastic is constrained by its inherently low‐impact resistance. Herein, we suggest a ternary system with the addition of ethylene‐butene copolymer (EBC) and multiwalled carbon nanotubes (MWCNTs) to improve the overall performance of PP. We unveil the role of MWCNTs on the crystalline behavior of the PP/EBC blends when various ratios are considered. The calculated half‐time crystallization from the Avrami equation indicates that 1.5 wt% MWCNTs accelerate the crystallization of the PP/EBC blend nearly threefold. The formation of a semisolid microstructure is also reported using the rheological measurements. An upturn in complex viscosity, along with a frequency‐independent storage modulus, indicates strong interactions between MWCNTs and polymer chains. We confirm such robust interactions by employing temperature ramp sweep on the prepared nanocomposites as the decomposition temperature of the materials shifts to higher values. The dynamic mechanical analysis further interprets the role of MWCNTs as compatibilizers by bridging the gap between the glassy temperature of PP and EBC components. Highlights Theoretical prediction of the MWCNTs localization in the PP/EBC blends. Depicting the solid‐like behavior and viscosity upturn of PP/EBC/MWCNTs. Decelerating polymer chain relaxation led by nucleation role of MWCNTs. Formation of larger and more imperfect crystals upon the addition of MWCNTs. Faster crystallization kinetics in the PP/EBC/MWCNTs nanocomposites. |
| format | Article |
| id | doaj-art-d4c83247bcd848d09c2f8a2c1c99ff6f |
| institution | Kabale University |
| issn | 2690-3857 |
| language | English |
| publishDate | 2025-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | SPE Polymers |
| spelling | doaj-art-d4c83247bcd848d09c2f8a2c1c99ff6f2025-01-29T12:52:33ZengWileySPE Polymers2690-38572025-01-0161n/an/a10.1002/pls2.10162Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blendsNariman Rajabifar0Payam Yazdandoost1Parnian Gholami Dastnaei2Amir Rostami3Department of Polymer Engineering and Color Technology Amirkabir University of Technology (Tehran Polytechnic) Tehran IranDepartment of Chemical Engineering, Mahshahr Branch Islamic Azad University Mahshahr IranDepartment of Chemical Engineering, Mahshahr Branch Islamic Azad University Mahshahr IranDepartment of Chemical Engineering Persian Gulf University Bushehr IranAbstract Polypropylene (PP) offers numerous benefits to industrial applications due to its excellent processability and cost‐effectiveness. However, the widespread utilization of this commodity thermoplastic is constrained by its inherently low‐impact resistance. Herein, we suggest a ternary system with the addition of ethylene‐butene copolymer (EBC) and multiwalled carbon nanotubes (MWCNTs) to improve the overall performance of PP. We unveil the role of MWCNTs on the crystalline behavior of the PP/EBC blends when various ratios are considered. The calculated half‐time crystallization from the Avrami equation indicates that 1.5 wt% MWCNTs accelerate the crystallization of the PP/EBC blend nearly threefold. The formation of a semisolid microstructure is also reported using the rheological measurements. An upturn in complex viscosity, along with a frequency‐independent storage modulus, indicates strong interactions between MWCNTs and polymer chains. We confirm such robust interactions by employing temperature ramp sweep on the prepared nanocomposites as the decomposition temperature of the materials shifts to higher values. The dynamic mechanical analysis further interprets the role of MWCNTs as compatibilizers by bridging the gap between the glassy temperature of PP and EBC components. Highlights Theoretical prediction of the MWCNTs localization in the PP/EBC blends. Depicting the solid‐like behavior and viscosity upturn of PP/EBC/MWCNTs. Decelerating polymer chain relaxation led by nucleation role of MWCNTs. Formation of larger and more imperfect crystals upon the addition of MWCNTs. Faster crystallization kinetics in the PP/EBC/MWCNTs nanocomposites.https://doi.org/10.1002/pls2.10162carbon nanotubecrystallinitymechanical propertiespolyolefinrandom copolymersrheology |
| spellingShingle | Nariman Rajabifar Payam Yazdandoost Parnian Gholami Dastnaei Amir Rostami Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blends SPE Polymers carbon nanotube crystallinity mechanical properties polyolefin random copolymers rheology |
| title | Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blends |
| title_full | Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blends |
| title_fullStr | Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blends |
| title_full_unstemmed | Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blends |
| title_short | Carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of PP/EBC blends |
| title_sort | carbon nanotube manipulates crystallization kinetics and viscoelastic behavior of pp ebc blends |
| topic | carbon nanotube crystallinity mechanical properties polyolefin random copolymers rheology |
| url | https://doi.org/10.1002/pls2.10162 |
| work_keys_str_mv | AT narimanrajabifar carbonnanotubemanipulatescrystallizationkineticsandviscoelasticbehaviorofppebcblends AT payamyazdandoost carbonnanotubemanipulatescrystallizationkineticsandviscoelasticbehaviorofppebcblends AT parniangholamidastnaei carbonnanotubemanipulatescrystallizationkineticsandviscoelasticbehaviorofppebcblends AT amirrostami carbonnanotubemanipulatescrystallizationkineticsandviscoelasticbehaviorofppebcblends |