Optical Spectra and Color Nature of Lithium Amphiboles

Optical absorption spectra of two lithium amphiboles of the pedrisite group from rare-metal peg-matites of the Sangilen rare-metal province in the southeastern part of Tyva have been studied. One of them – a limit magnesian fluoro-sodium pedrisite of yellow-green color – was taken from the rocks hos...

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Main Authors: S.I. Konovalenko, A.I. Bakhtin, A.G. Nikolaev
Format: Article
Language:English
Published: Kazan Federal University 2016-03-01
Series:Учёные записки Казанского университета: Серия Естественные науки
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Online Access:http://kpfu.ru/portal/docs/F_1533347785/158_1_est_7.pdf
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author S.I. Konovalenko
A.I. Bakhtin
A.G. Nikolaev
author_facet S.I. Konovalenko
A.I. Bakhtin
A.G. Nikolaev
author_sort S.I. Konovalenko
collection DOAJ
description Optical absorption spectra of two lithium amphiboles of the pedrisite group from rare-metal peg-matites of the Sangilen rare-metal province in the southeastern part of Tyva have been studied. One of them – a limit magnesian fluoro-sodium pedrisite of yellow-green color – was taken from the rocks hosting pegmatites, and another one – fluoro-sodium ferro-pedrisite of violet-blue color – was taken from pegmatites as such. It has been demonstrated that the color of the yellow-green mineral is associated with absorption bands of Cr3+ ions in the octahedral coordination. Absorption bands of Cr3+ ions in the spectrum of fluoro-sodium pedrisite are formed by a transmission window in the yellow-green region of the spectrum. Therefore, the color of this sample is yellow-green. The color of violet-blue pedrisite is de-fined by intensive absorption bands of charge transfer Fe2+ → Fe3+ 550, 680 nm. Very strong absorption bands of 550 and 680 nm are formed by a transmission window in the violet-blue region of the spectrum. Thus, the color of ferro-pedrisite is violet-blue.
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publishDate 2016-03-01
publisher Kazan Federal University
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series Учёные записки Казанского университета: Серия Естественные науки
spelling doaj-art-d4749143d1b94de09be2974811f1f2542025-02-03T10:46:06ZengKazan Federal UniversityУчёные записки Казанского университета: Серия Естественные науки1815-61692500-218X2016-03-01158194100Optical Spectra and Color Nature of Lithium AmphibolesS.I. Konovalenko0A.I. Bakhtin1A.G. Nikolaev2National Research Тomsk State University, Тomsk, 634050 RussiaKazan Federal University, Kazan, 420008 RussiaKazan Federal University, Kazan, 420008 RussiaOptical absorption spectra of two lithium amphiboles of the pedrisite group from rare-metal peg-matites of the Sangilen rare-metal province in the southeastern part of Tyva have been studied. One of them – a limit magnesian fluoro-sodium pedrisite of yellow-green color – was taken from the rocks hosting pegmatites, and another one – fluoro-sodium ferro-pedrisite of violet-blue color – was taken from pegmatites as such. It has been demonstrated that the color of the yellow-green mineral is associated with absorption bands of Cr3+ ions in the octahedral coordination. Absorption bands of Cr3+ ions in the spectrum of fluoro-sodium pedrisite are formed by a transmission window in the yellow-green region of the spectrum. Therefore, the color of this sample is yellow-green. The color of violet-blue pedrisite is de-fined by intensive absorption bands of charge transfer Fe2+ → Fe3+ 550, 680 nm. Very strong absorption bands of 550 and 680 nm are formed by a transmission window in the violet-blue region of the spectrum. Thus, the color of ferro-pedrisite is violet-blue.http://kpfu.ru/portal/docs/F_1533347785/158_1_est_7.pdfoptical spectrafluoro-sodium pedrisitefluoro-sodium ferro-pedrisitecolor nature
spellingShingle S.I. Konovalenko
A.I. Bakhtin
A.G. Nikolaev
Optical Spectra and Color Nature of Lithium Amphiboles
Учёные записки Казанского университета: Серия Естественные науки
optical spectra
fluoro-sodium pedrisite
fluoro-sodium ferro-pedrisite
color nature
title Optical Spectra and Color Nature of Lithium Amphiboles
title_full Optical Spectra and Color Nature of Lithium Amphiboles
title_fullStr Optical Spectra and Color Nature of Lithium Amphiboles
title_full_unstemmed Optical Spectra and Color Nature of Lithium Amphiboles
title_short Optical Spectra and Color Nature of Lithium Amphiboles
title_sort optical spectra and color nature of lithium amphiboles
topic optical spectra
fluoro-sodium pedrisite
fluoro-sodium ferro-pedrisite
color nature
url http://kpfu.ru/portal/docs/F_1533347785/158_1_est_7.pdf
work_keys_str_mv AT sikonovalenko opticalspectraandcolornatureoflithiumamphiboles
AT aibakhtin opticalspectraandcolornatureoflithiumamphiboles
AT agnikolaev opticalspectraandcolornatureoflithiumamphiboles