Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate Hexahydrate
Chemical preparation, x-ray characterization, IR spectroscopy and thermal analysis of a new sulfate (C7H12O2NH2)4(SO4)2.6H2O, are reported. The atomic arrangement can be described by layers formed by sulfate anions (SO -24) and water molecules connected by hydrogen bonds O-H…O. These inorganic layer...
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| Format: | Article |
| Language: | English |
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Wiley
2011-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2011/572080 |
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| author | H. Marouani M. Rzaigui S. S. Al-Deyab |
| author_facet | H. Marouani M. Rzaigui S. S. Al-Deyab |
| author_sort | H. Marouani |
| collection | DOAJ |
| description | Chemical preparation, x-ray characterization, IR spectroscopy and thermal analysis of a new sulfate (C7H12O2NH2)4(SO4)2.6H2O, are reported. The atomic arrangement can be described by layers formed by sulfate anions (SO -24) and water molecules connected by hydrogen bonds O-H…O. These inorganic layers are developed around ab planes at z = 0 and z = 1/2 and are interconnected by the H-bonds created by organic groups. All the hydrogen bonds, the Van der waals contacts and electrostatic interactions between the different entities give rise to a three-dimensional network in the structure and add stability to this compound. The thermal behaviour and the IR spectroscopic studies of this new sulfate are discussed. |
| format | Article |
| id | doaj-art-d3465c6d028349359601959fc6d66d04 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2011-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-d3465c6d028349359601959fc6d66d042025-02-03T05:58:26ZengWileyE-Journal of Chemistry0973-49452090-98102011-01-01841930193610.1155/2011/572080Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate HexahydrateH. Marouani0M. Rzaigui1S. S. Al-Deyab2Laboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, TunisiaLaboratoire de Chimie des Matériaux, Faculté des Sciences de Bizerte, 7021 Zarzouna, TunisiaPetrochemical Research Chair, College of Science, King Saud University, Riadh, Saudi ArabiaChemical preparation, x-ray characterization, IR spectroscopy and thermal analysis of a new sulfate (C7H12O2NH2)4(SO4)2.6H2O, are reported. The atomic arrangement can be described by layers formed by sulfate anions (SO -24) and water molecules connected by hydrogen bonds O-H…O. These inorganic layers are developed around ab planes at z = 0 and z = 1/2 and are interconnected by the H-bonds created by organic groups. All the hydrogen bonds, the Van der waals contacts and electrostatic interactions between the different entities give rise to a three-dimensional network in the structure and add stability to this compound. The thermal behaviour and the IR spectroscopic studies of this new sulfate are discussed.http://dx.doi.org/10.1155/2011/572080 |
| spellingShingle | H. Marouani M. Rzaigui S. S. Al-Deyab Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate Hexahydrate E-Journal of Chemistry |
| title | Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate Hexahydrate |
| title_full | Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate Hexahydrate |
| title_fullStr | Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate Hexahydrate |
| title_full_unstemmed | Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate Hexahydrate |
| title_short | Synthesis and Characterization of Tetrakis(4-oxo-piperidinium ethylene acetal) Bis Sulfate Hexahydrate |
| title_sort | synthesis and characterization of tetrakis 4 oxo piperidinium ethylene acetal bis sulfate hexahydrate |
| url | http://dx.doi.org/10.1155/2011/572080 |
| work_keys_str_mv | AT hmarouani synthesisandcharacterizationoftetrakis4oxopiperidiniumethyleneacetalbissulfatehexahydrate AT mrzaigui synthesisandcharacterizationoftetrakis4oxopiperidiniumethyleneacetalbissulfatehexahydrate AT ssaldeyab synthesisandcharacterizationoftetrakis4oxopiperidiniumethyleneacetalbissulfatehexahydrate |