Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime
The reactions of methyl(2-pyridyl)ketone oxime, (py)C(Me)NOH, with manganese(II) sulfate monohydrate have been investigated. The reaction between equimolar quantities of MnSO4⋅H2O and (py)C(Me)NOH in H2O lead to the dinuclear complex [Mn2(SO4)2{(py)C(Me)NOH}4]⋅(py)C(Me)NOH, 1⋅(py)C(Me)NOH, while em...
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | Bioinorganic Chemistry and Applications |
| Online Access: | http://dx.doi.org/10.1155/2010/960571 |
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| author | Constantinos G. Efthymiou Vassilios Nastopoulos Catherine Raptopoulou Anastasios Tasiopoulos Spyros P. Perlepes Constantina Papatriantafyllopoulou |
| author_facet | Constantinos G. Efthymiou Vassilios Nastopoulos Catherine Raptopoulou Anastasios Tasiopoulos Spyros P. Perlepes Constantina Papatriantafyllopoulou |
| author_sort | Constantinos G. Efthymiou |
| collection | DOAJ |
| description | The reactions of methyl(2-pyridyl)ketone oxime, (py)C(Me)NOH, with manganese(II) sulfate monohydrate have been investigated. The reaction between equimolar quantities of MnSO4⋅H2O and (py)C(Me)NOH in H2O lead to the dinuclear complex [Mn2(SO4)2{(py)C(Me)NOH}4]⋅(py)C(Me)NOH, 1⋅(py)C(Me)NOH, while employment of NaOMe as base affords the compound [Mn(HCO2)2{(py)C(Me)NOH}2] (2). The structures of both compounds have been determined by single crystal X-ray diffraction. In both complexes, the organic ligand chelates through its nitrogen atoms. The IR data are discussed in terms of the nature of bonding and the structures of the two complexes. |
| format | Article |
| id | doaj-art-d2db78be363540edbac6c8a32801a20b |
| institution | Kabale University |
| issn | 1565-3633 1687-479X |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Bioinorganic Chemistry and Applications |
| spelling | doaj-art-d2db78be363540edbac6c8a32801a20b2025-02-03T06:00:41ZengWileyBioinorganic Chemistry and Applications1565-36331687-479X2010-01-01201010.1155/2010/960571960571Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone OximeConstantinos G. Efthymiou0Vassilios Nastopoulos1Catherine Raptopoulou2Anastasios Tasiopoulos3Spyros P. Perlepes4Constantina Papatriantafyllopoulou5Department of Chemistry, University of Patras, 265 04 Patras, GreeceDepartment of Chemistry, University of Patras, 265 04 Patras, GreeceInstitute of Materials Science, National Centre of Scientific Research “Demokritos”, 153 10 Aghia Paraskevi Attikis, GreeceDepartment of Chemistry, University of Cyprus, 1678 Nicosia, CyprusDepartment of Chemistry, University of Patras, 265 04 Patras, GreeceDepartment of Chemistry, University of Florida, Gainesville, FL 32611-7200, USAThe reactions of methyl(2-pyridyl)ketone oxime, (py)C(Me)NOH, with manganese(II) sulfate monohydrate have been investigated. The reaction between equimolar quantities of MnSO4⋅H2O and (py)C(Me)NOH in H2O lead to the dinuclear complex [Mn2(SO4)2{(py)C(Me)NOH}4]⋅(py)C(Me)NOH, 1⋅(py)C(Me)NOH, while employment of NaOMe as base affords the compound [Mn(HCO2)2{(py)C(Me)NOH}2] (2). The structures of both compounds have been determined by single crystal X-ray diffraction. In both complexes, the organic ligand chelates through its nitrogen atoms. The IR data are discussed in terms of the nature of bonding and the structures of the two complexes.http://dx.doi.org/10.1155/2010/960571 |
| spellingShingle | Constantinos G. Efthymiou Vassilios Nastopoulos Catherine Raptopoulou Anastasios Tasiopoulos Spyros P. Perlepes Constantina Papatriantafyllopoulou Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime Bioinorganic Chemistry and Applications |
| title | Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime |
| title_full | Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime |
| title_fullStr | Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime |
| title_full_unstemmed | Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime |
| title_short | Mononuclear and Dinuclear Manganese(II) Complexes from the Use of Methyl(2-pyridyl)ketone Oxime |
| title_sort | mononuclear and dinuclear manganese ii complexes from the use of methyl 2 pyridyl ketone oxime |
| url | http://dx.doi.org/10.1155/2010/960571 |
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