4-Bromo-N,N′-diphenylbenzimidamide N′-oxide

The title compound, C19H15BrN2O, crystallizes with two similar molecules in the asymmetric unit. The extended structure features dimers linked by pairs of N—H...O and C—H...O hydrogen bonds. The HNCNO moiety of the title compound shows delocalization over the N—C—N part, as evidenced by the similar...

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Main Authors: Arindam Saha, Daniel Chartrand, Mihaela Cibian, Thierry Maris, Garry S. Hanan
Format: Article
Language:English
Published: International Union of Crystallography 2024-10-01
Series:IUCrData
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Online Access:https://journals.iucr.org/paper?S2414314624009684
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author Arindam Saha
Daniel Chartrand
Mihaela Cibian
Thierry Maris
Garry S. Hanan
author_facet Arindam Saha
Daniel Chartrand
Mihaela Cibian
Thierry Maris
Garry S. Hanan
author_sort Arindam Saha
collection DOAJ
description The title compound, C19H15BrN2O, crystallizes with two similar molecules in the asymmetric unit. The extended structure features dimers linked by pairs of N—H...O and C—H...O hydrogen bonds. The HNCNO moiety of the title compound shows delocalization over the N—C—N part, as evidenced by the similar C—N bond distances.
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issn 2414-3146
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publishDate 2024-10-01
publisher International Union of Crystallography
record_format Article
series IUCrData
spelling doaj-art-d2c0eb2d3478444c836a0e02c38c6bc52025-08-20T02:26:40ZengInternational Union of CrystallographyIUCrData2414-31462024-10-01910x24096810.1107/S2414314624009684hb44874-Bromo-N,N′-diphenylbenzimidamide N′-oxideArindam Saha0Daniel Chartrand1Mihaela Cibian2Thierry Maris3Garry S. Hanan4Département de Chimie, Université de Montréal, Complexe des sciences, 1375, Avenue Thérèse-Lavoie-Roux, Montréal, Québec H2V 0B3, CanadaDépartement de Chimie, Université de Montréal, Complexe des sciences, 1375, Avenue Thérèse-Lavoie-Roux, Montréal, Québec H2V 0B3, CanadaDépartement de biochimie, chimie, physique et science forensique, Université du Québec à Trois-Rivières. 3351, boul. des Forges, CP 500, Trois-Rivières, Québec, G9A 5H7, CanadaDépartement de Chimie, Université de Montréal, Complexe des sciences, 1375, Avenue Thérèse-Lavoie-Roux, Montréal, Québec H2V 0B3, CanadaDépartement de Chimie, Université de Montréal, Complexe des sciences, 1375, Avenue Thérèse-Lavoie-Roux, Montréal, Québec H2V 0B3, CanadaThe title compound, C19H15BrN2O, crystallizes with two similar molecules in the asymmetric unit. The extended structure features dimers linked by pairs of N—H...O and C—H...O hydrogen bonds. The HNCNO moiety of the title compound shows delocalization over the N—C—N part, as evidenced by the similar C—N bond distances.https://journals.iucr.org/paper?S2414314624009684amidine n-oxidesligand synthesiscrystal structure
spellingShingle Arindam Saha
Daniel Chartrand
Mihaela Cibian
Thierry Maris
Garry S. Hanan
4-Bromo-N,N′-diphenylbenzimidamide N′-oxide
IUCrData
amidine n-oxides
ligand synthesis
crystal structure
title 4-Bromo-N,N′-diphenylbenzimidamide N′-oxide
title_full 4-Bromo-N,N′-diphenylbenzimidamide N′-oxide
title_fullStr 4-Bromo-N,N′-diphenylbenzimidamide N′-oxide
title_full_unstemmed 4-Bromo-N,N′-diphenylbenzimidamide N′-oxide
title_short 4-Bromo-N,N′-diphenylbenzimidamide N′-oxide
title_sort 4 bromo n n diphenylbenzimidamide n oxide
topic amidine n-oxides
ligand synthesis
crystal structure
url https://journals.iucr.org/paper?S2414314624009684
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AT danielchartrand 4bromonndiphenylbenzimidamidenoxide
AT mihaelacibian 4bromonndiphenylbenzimidamidenoxide
AT thierrymaris 4bromonndiphenylbenzimidamidenoxide
AT garryshanan 4bromonndiphenylbenzimidamidenoxide