Investigating the Selective Control of Photoassociation of Yb2
The selective control of photoassociation of Yb2 is investigated in theory. Based on ab initio to rationalize Franck–Condon filtering, the optimal target states of photoassociation have been obtained. The corresponding vibrational transitions from X1Σ+g to the excited state (A1Σu+, B1Πu, C1Σu+, and...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2021-01-01
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| Series: | International Journal of Optics |
| Online Access: | http://dx.doi.org/10.1155/2021/6859330 |
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| _version_ | 1832561388351913984 |
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| author | Junxia Cheng Bo Tian Siyu Li Jia Wang Shenjiang Wu |
| author_facet | Junxia Cheng Bo Tian Siyu Li Jia Wang Shenjiang Wu |
| author_sort | Junxia Cheng |
| collection | DOAJ |
| description | The selective control of photoassociation of Yb2 is investigated in theory. Based on ab initio to rationalize Franck–Condon filtering, the optimal target states of photoassociation have been obtained. The corresponding vibrational transitions from X1Σ+g to the excited state (A1Σu+, B1Πu, C1Σu+, and D1Πu) are v′ = 23, 50, 55, and 0, respectively. By using quantum wave packet dynamic methods, we calculated the yields with time evaluation for the selected target states. The projections of time-dependent wave functions of initial states on the target vibrational eigenstates reflected the synthetic yields of Yb2. For target A1Σu+, we used Gaussian pulse to make the yield of v′ = 23 up to 97% at 725 fs. After a laser pulse, the positive chirp promoted the yield of vibrational states to increase, but the negative chirp inhibited its decrease. For the D1Πu state, when laser intensity is 1.0 × 1014 W/cm2, the purity and yield of target state v′ = 0 reached the maximum at 1350 fs. That is to say, changing the laser parameters and pulse shapes could control the photochemical reaction along our desired direction. These conditions will provide an important reference and suggest a scheme for a feasible photoassociation of further experimental and theoretical research studies. Current study may promote an important step toward the realization of highly accurate quantum manipulation and material synthesis. |
| format | Article |
| id | doaj-art-d2a66728a08e4d49bf59f808d16974ad |
| institution | Kabale University |
| issn | 1687-9384 1687-9392 |
| language | English |
| publishDate | 2021-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | International Journal of Optics |
| spelling | doaj-art-d2a66728a08e4d49bf59f808d16974ad2025-02-03T01:25:14ZengWileyInternational Journal of Optics1687-93841687-93922021-01-01202110.1155/2021/68593306859330Investigating the Selective Control of Photoassociation of Yb2Junxia Cheng0Bo Tian1Siyu Li2Jia Wang3Shenjiang Wu4School of Photo-Electrical Engineering, Xi’an Technological University, Xi’an 710021, ChinaCollege of Aerospace and Civil Engineering, Haerbin Engineering University, Haerbin 150001, ChinaSchool of Photo-Electrical Engineering, Xi’an Technological University, Xi’an 710021, ChinaSchool of Photo-Electrical Engineering, Xi’an Technological University, Xi’an 710021, ChinaSchool of Photo-Electrical Engineering, Xi’an Technological University, Xi’an 710021, ChinaThe selective control of photoassociation of Yb2 is investigated in theory. Based on ab initio to rationalize Franck–Condon filtering, the optimal target states of photoassociation have been obtained. The corresponding vibrational transitions from X1Σ+g to the excited state (A1Σu+, B1Πu, C1Σu+, and D1Πu) are v′ = 23, 50, 55, and 0, respectively. By using quantum wave packet dynamic methods, we calculated the yields with time evaluation for the selected target states. The projections of time-dependent wave functions of initial states on the target vibrational eigenstates reflected the synthetic yields of Yb2. For target A1Σu+, we used Gaussian pulse to make the yield of v′ = 23 up to 97% at 725 fs. After a laser pulse, the positive chirp promoted the yield of vibrational states to increase, but the negative chirp inhibited its decrease. For the D1Πu state, when laser intensity is 1.0 × 1014 W/cm2, the purity and yield of target state v′ = 0 reached the maximum at 1350 fs. That is to say, changing the laser parameters and pulse shapes could control the photochemical reaction along our desired direction. These conditions will provide an important reference and suggest a scheme for a feasible photoassociation of further experimental and theoretical research studies. Current study may promote an important step toward the realization of highly accurate quantum manipulation and material synthesis.http://dx.doi.org/10.1155/2021/6859330 |
| spellingShingle | Junxia Cheng Bo Tian Siyu Li Jia Wang Shenjiang Wu Investigating the Selective Control of Photoassociation of Yb2 International Journal of Optics |
| title | Investigating the Selective Control of Photoassociation of Yb2 |
| title_full | Investigating the Selective Control of Photoassociation of Yb2 |
| title_fullStr | Investigating the Selective Control of Photoassociation of Yb2 |
| title_full_unstemmed | Investigating the Selective Control of Photoassociation of Yb2 |
| title_short | Investigating the Selective Control of Photoassociation of Yb2 |
| title_sort | investigating the selective control of photoassociation of yb2 |
| url | http://dx.doi.org/10.1155/2021/6859330 |
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