Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous Solution
Indian jujuba seed powder (IJSP) has been investigated as a low-cost and an eco-friendly biosorbent, prepared for the removal of Acid Blue 25 (AB25) from aqueous solution. The prepared biomaterial was characterized by using FTIR and scanning electron microscopic studies. The eff...
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2014-01-01
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Series: | The Scientific World Journal |
Online Access: | http://dx.doi.org/10.1155/2014/184058 |
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author | L. Sivarama Krishna A. Sreenath Reddy W. Y. Wan Zuhairi M. R. Taha A. Varada Reddy |
author_facet | L. Sivarama Krishna A. Sreenath Reddy W. Y. Wan Zuhairi M. R. Taha A. Varada Reddy |
author_sort | L. Sivarama Krishna |
collection | DOAJ |
description | Indian jujuba seed powder (IJSP) has been investigated as a low-cost and an eco-friendly biosorbent, prepared for the removal of Acid Blue 25 (AB25) from aqueous solution. The prepared biomaterial was characterized by using FTIR and scanning electron microscopic studies. The effect of operation variables, such as IJSP dosage, contact time, concentration, pH, and temperature on the removal of AB25 was investigated, using batch biosorption technique. Removal efficiency increased with increase of IJSP dosage but decreased with increase of temperature. The equilibrium data were analyzed by the Langmuir and the Freundlich isotherm models. The data fitted well with the Langmuir model with a maximum biosorption capacity of 54.95 mg g−1. The pseudo-second-order kinetics was the best for the biosorption of AB25 by IJSP, with good correlation. Thermodynamic parameters such as standard free energy change (ΔG0), standard enthalpy changes (ΔH0), and standard entropy changes (ΔS0) were analyzed. The removal of AB25 from aqueous solution by IJSP was a spontaneous and exothermic adsorption process. The results suggest that IJSP is a potential low-cost and an eco-friendly biosorbent for the AB25 removal from synthetic AB25 wastewater. |
format | Article |
id | doaj-art-cff2aae25ea1452aa9d662239747f575 |
institution | Kabale University |
issn | 2356-6140 1537-744X |
language | English |
publishDate | 2014-01-01 |
publisher | Wiley |
record_format | Article |
series | The Scientific World Journal |
spelling | doaj-art-cff2aae25ea1452aa9d662239747f5752025-02-03T05:50:51ZengWileyThe Scientific World Journal2356-61401537-744X2014-01-01201410.1155/2014/184058184058Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous SolutionL. Sivarama Krishna0A. Sreenath Reddy1W. Y. Wan Zuhairi2M. R. Taha3A. Varada Reddy4Geology Programme, School for Environmental Sciences and Natural Resources, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaAnalytical Division, Department of Chemistry, Sri Venkateswara University, Tirupati, Andhra Pradesh 517 502, IndiaGeology Programme, School for Environmental Sciences and Natural Resources, Faculty of Science and Technology, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaDepartment of Civil and Structural Engineering, Universiti Kebangsaan Malaysia, 43600 Bangi, Selangor, MalaysiaAnalytical Division, Department of Chemistry, Sri Venkateswara University, Tirupati, Andhra Pradesh 517 502, IndiaIndian jujuba seed powder (IJSP) has been investigated as a low-cost and an eco-friendly biosorbent, prepared for the removal of Acid Blue 25 (AB25) from aqueous solution. The prepared biomaterial was characterized by using FTIR and scanning electron microscopic studies. The effect of operation variables, such as IJSP dosage, contact time, concentration, pH, and temperature on the removal of AB25 was investigated, using batch biosorption technique. Removal efficiency increased with increase of IJSP dosage but decreased with increase of temperature. The equilibrium data were analyzed by the Langmuir and the Freundlich isotherm models. The data fitted well with the Langmuir model with a maximum biosorption capacity of 54.95 mg g−1. The pseudo-second-order kinetics was the best for the biosorption of AB25 by IJSP, with good correlation. Thermodynamic parameters such as standard free energy change (ΔG0), standard enthalpy changes (ΔH0), and standard entropy changes (ΔS0) were analyzed. The removal of AB25 from aqueous solution by IJSP was a spontaneous and exothermic adsorption process. The results suggest that IJSP is a potential low-cost and an eco-friendly biosorbent for the AB25 removal from synthetic AB25 wastewater.http://dx.doi.org/10.1155/2014/184058 |
spellingShingle | L. Sivarama Krishna A. Sreenath Reddy W. Y. Wan Zuhairi M. R. Taha A. Varada Reddy Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous Solution The Scientific World Journal |
title | Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous Solution |
title_full | Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous Solution |
title_fullStr | Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous Solution |
title_full_unstemmed | Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous Solution |
title_short | Indian Jujuba Seed Powder as an Eco-Friendly and a Low-Cost Biosorbent for Removal of Acid Blue 25 from Aqueous Solution |
title_sort | indian jujuba seed powder as an eco friendly and a low cost biosorbent for removal of acid blue 25 from aqueous solution |
url | http://dx.doi.org/10.1155/2014/184058 |
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