Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical Erosion

The issue of rock deterioration in chemical environments has drawn much attention in recent years in the rock engineering community. In this study, a series of 30 freeze-thaw cycling tests are conducted on sandstone samples soaked in H2SO4 solution and in pure water, prior to the application of nucl...

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Main Authors: Jielin Li, Rennie B. Kaunda, Longyin Zhu, Keping Zhou, Feng Gao
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:Advances in Civil Engineering
Online Access:http://dx.doi.org/10.1155/2019/9687843
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author Jielin Li
Rennie B. Kaunda
Longyin Zhu
Keping Zhou
Feng Gao
author_facet Jielin Li
Rennie B. Kaunda
Longyin Zhu
Keping Zhou
Feng Gao
author_sort Jielin Li
collection DOAJ
description The issue of rock deterioration in chemical environments has drawn much attention in recent years in the rock engineering community. In this study, a series of 30 freeze-thaw cycling tests are conducted on sandstone samples soaked in H2SO4 solution and in pure water, prior to the application of nuclear magnetic resonance (NMR) on the rock specimens. The porosity of the sandstone, the distribution of transverse relaxation time T2, and the NMR images are acquired after each freeze-thaw cycle. The pore size distribution curves of the sandstone after freeze-thaw cycles, four categories of pore scale, and the features of freeze-thaw deterioration for pores of different sizes in H2SO4 solution and pure water are established. The result shows that, with the influence of the acid environment and the freeze-thaw cycles, the mass of the samples largely deteriorates. As the freeze-thaw cycles increase, the porosity of rocks increases approximately linearly. The distribution of the NMR T2 develops gradually from 4 peaks to 5 or even to 6. Magnetic resonance imaging (MRI) dynamically displays the process of the freeze-thaw deterioration of the microstructure inside the sandstones under acid conditions. The results also show pore expansion in rocks under the coupling effects of chemistry and the freeze-thaw cycles, which differ largely from the freeze-thaw deterioration of the rock specimens placed in pure water.
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spelling doaj-art-ce6f639bea574a2eba6b0d316e6b39162025-02-03T07:24:42ZengWileyAdvances in Civil Engineering1687-80861687-80942019-01-01201910.1155/2019/96878439687843Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical ErosionJielin Li0Rennie B. Kaunda1Longyin Zhu2Keping Zhou3Feng Gao4School of Resources and Safety Engineering, Central South University, Changsha, Hunan 410083, ChinaDepartment of Mining Engineering, Colorado School of Mines, 1600 Illinois Street, Golden, Colorado 80401, USASchool of Resources and Safety Engineering, Central South University, Changsha, Hunan 410083, ChinaSchool of Resources and Safety Engineering, Central South University, Changsha, Hunan 410083, ChinaSchool of Resources and Safety Engineering, Central South University, Changsha, Hunan 410083, ChinaThe issue of rock deterioration in chemical environments has drawn much attention in recent years in the rock engineering community. In this study, a series of 30 freeze-thaw cycling tests are conducted on sandstone samples soaked in H2SO4 solution and in pure water, prior to the application of nuclear magnetic resonance (NMR) on the rock specimens. The porosity of the sandstone, the distribution of transverse relaxation time T2, and the NMR images are acquired after each freeze-thaw cycle. The pore size distribution curves of the sandstone after freeze-thaw cycles, four categories of pore scale, and the features of freeze-thaw deterioration for pores of different sizes in H2SO4 solution and pure water are established. The result shows that, with the influence of the acid environment and the freeze-thaw cycles, the mass of the samples largely deteriorates. As the freeze-thaw cycles increase, the porosity of rocks increases approximately linearly. The distribution of the NMR T2 develops gradually from 4 peaks to 5 or even to 6. Magnetic resonance imaging (MRI) dynamically displays the process of the freeze-thaw deterioration of the microstructure inside the sandstones under acid conditions. The results also show pore expansion in rocks under the coupling effects of chemistry and the freeze-thaw cycles, which differ largely from the freeze-thaw deterioration of the rock specimens placed in pure water.http://dx.doi.org/10.1155/2019/9687843
spellingShingle Jielin Li
Rennie B. Kaunda
Longyin Zhu
Keping Zhou
Feng Gao
Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical Erosion
Advances in Civil Engineering
title Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical Erosion
title_full Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical Erosion
title_fullStr Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical Erosion
title_full_unstemmed Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical Erosion
title_short Experimental Study of the Pore Structure Deterioration of Sandstones under Freeze-Thaw Cycles and Chemical Erosion
title_sort experimental study of the pore structure deterioration of sandstones under freeze thaw cycles and chemical erosion
url http://dx.doi.org/10.1155/2019/9687843
work_keys_str_mv AT jielinli experimentalstudyoftheporestructuredeteriorationofsandstonesunderfreezethawcyclesandchemicalerosion
AT renniebkaunda experimentalstudyoftheporestructuredeteriorationofsandstonesunderfreezethawcyclesandchemicalerosion
AT longyinzhu experimentalstudyoftheporestructuredeteriorationofsandstonesunderfreezethawcyclesandchemicalerosion
AT kepingzhou experimentalstudyoftheporestructuredeteriorationofsandstonesunderfreezethawcyclesandchemicalerosion
AT fenggao experimentalstudyoftheporestructuredeteriorationofsandstonesunderfreezethawcyclesandchemicalerosion