Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control System

The photocatalytic activity on decomposition of Rhodamine B (RB) of titanate nanotubes (TNTs) synthesized by alkali hydrothermal treatment method was evaluated using a microwave/UV/photocatalyst hybrid system. The effects of each element technique as well as the synergy effects on decomposition of o...

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Main Authors: Sun-Jae Kim, Young-Seak Lee, Byung Hoon Kim, Seong-Gyu Seo, Sung Hoon Park, Sang Chul Jung
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/901907
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author Sun-Jae Kim
Young-Seak Lee
Byung Hoon Kim
Seong-Gyu Seo
Sung Hoon Park
Sang Chul Jung
author_facet Sun-Jae Kim
Young-Seak Lee
Byung Hoon Kim
Seong-Gyu Seo
Sung Hoon Park
Sang Chul Jung
author_sort Sun-Jae Kim
collection DOAJ
description The photocatalytic activity on decomposition of Rhodamine B (RB) of titanate nanotubes (TNTs) synthesized by alkali hydrothermal treatment method was evaluated using a microwave/UV/photocatalyst hybrid system. The effects of each element technique as well as the synergy effects on decomposition of organic material were investigated. When TNTs were ion-exchanged with HCl, Na+ content was reduced from 8.36 wt% to 0.03 wt%, whereas the TNTs calcined at 723 K was phase-transformed into anatase structure. The RB decomposition rate increased with TNTs dosage as well as with microwave intensity. Effect of addition of auxiliary oxidants on photocatalytic decomposition of RB was also investigated. When ozone was added, the decomposition rate increased with the amount of ozone added. When H2O2 was used as the auxiliary oxidant, however, addition of H2O2 exceeding a threshold amount caused reduction of decomposition rate. A synergy effect was observed when H2O2 addition was combined with microwave-assisted photocatalysis.
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language English
publishDate 2012-01-01
publisher Wiley
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series International Journal of Photoenergy
spelling doaj-art-ce6c6dc60c1e442485568a3cd19972042025-02-03T01:00:56ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/901907901907Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control SystemSun-Jae Kim0Young-Seak Lee1Byung Hoon Kim2Seong-Gyu Seo3Sung Hoon Park4Sang Chul Jung5Faculty of Nanotechnology and Advanced Materials Engineering, Sejong University, Seoul 143-747, Republic of KoreaDepartment of Fine Chemical Engineering and Applied Chemistry, Chungnam National University, Daejeon 305-764, Republic of KoreaDepartment of Dental Materials, School of Dentistry, Chosun University, Gwangju 501-759, Republic of KoreaDepartment of Civil and Environmental Engineering, Chonnam National University, Yosu 550-749, Republic of KoreaDepartment of Environmental Engineering, Sunchon National University, Sunchon 540-742, Republic of KoreaDepartment of Environmental Engineering, Sunchon National University, Sunchon 540-742, Republic of KoreaThe photocatalytic activity on decomposition of Rhodamine B (RB) of titanate nanotubes (TNTs) synthesized by alkali hydrothermal treatment method was evaluated using a microwave/UV/photocatalyst hybrid system. The effects of each element technique as well as the synergy effects on decomposition of organic material were investigated. When TNTs were ion-exchanged with HCl, Na+ content was reduced from 8.36 wt% to 0.03 wt%, whereas the TNTs calcined at 723 K was phase-transformed into anatase structure. The RB decomposition rate increased with TNTs dosage as well as with microwave intensity. Effect of addition of auxiliary oxidants on photocatalytic decomposition of RB was also investigated. When ozone was added, the decomposition rate increased with the amount of ozone added. When H2O2 was used as the auxiliary oxidant, however, addition of H2O2 exceeding a threshold amount caused reduction of decomposition rate. A synergy effect was observed when H2O2 addition was combined with microwave-assisted photocatalysis.http://dx.doi.org/10.1155/2012/901907
spellingShingle Sun-Jae Kim
Young-Seak Lee
Byung Hoon Kim
Seong-Gyu Seo
Sung Hoon Park
Sang Chul Jung
Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control System
International Journal of Photoenergy
title Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control System
title_full Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control System
title_fullStr Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control System
title_full_unstemmed Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control System
title_short Photocatalytic Activity of Titanate Nanotube Powders in a Hybrid Pollution Control System
title_sort photocatalytic activity of titanate nanotube powders in a hybrid pollution control system
url http://dx.doi.org/10.1155/2012/901907
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AT seonggyuseo photocatalyticactivityoftitanatenanotubepowdersinahybridpollutioncontrolsystem
AT sunghoonpark photocatalyticactivityoftitanatenanotubepowdersinahybridpollutioncontrolsystem
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