Thermodynamic modeling of the Hf-N system
Hf-N based alloys have been widely used and studied in the fields of electronic devices and cutting tools industry. A thermodynamic description of this system is essential for further materials development. By means of CALPHAD method, a thermodynamic modeling of the Hf-N system was carried out based...
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University of Belgrade, Technical Faculty, Bor
2018-01-01
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Series: | Journal of Mining and Metallurgy. Section B: Metallurgy |
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Online Access: | http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391700055P.pdf |
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author | Pang M. Peng Y. Zhou P. Du Y. |
author_facet | Pang M. Peng Y. Zhou P. Du Y. |
author_sort | Pang M. |
collection | DOAJ |
description | Hf-N based alloys have been widely used and studied in the fields of electronic devices and cutting tools industry. A thermodynamic description of this system is essential for further materials development. By means of CALPHAD method, a thermodynamic modeling of the Hf-N system was carried out based on the available phase diagram data as well as thermodynamic property data. The Fcc phase is modeled as (Hf, Va)1(N, Va)1 to cover the composition range since the solubility of nitrogen in Fcc phase is reported up to about 52 at.%. A set of self-consistent thermodynamic parameters for the Hf-N system has been obtained. The computed phase diagrams and thermodynamic quantities using the present parameters agree well with the experimental data. |
format | Article |
id | doaj-art-cdeeaadf678c49b7a0479a48fd5f7579 |
institution | Kabale University |
issn | 1450-5339 2217-7175 |
language | English |
publishDate | 2018-01-01 |
publisher | University of Belgrade, Technical Faculty, Bor |
record_format | Article |
series | Journal of Mining and Metallurgy. Section B: Metallurgy |
spelling | doaj-art-cdeeaadf678c49b7a0479a48fd5f75792025-02-02T00:16:35ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752018-01-0154111111810.2298/JMMB170520055P1450-53391700055PThermodynamic modeling of the Hf-N systemPang M.0Peng Y.1Zhou P.2Du Y.3Central South University, State Key Lab of Powder Metallurgy, Changsha, ChinaHunan University of Technology, College of Metallurgy and Material Engineering, Zhuzhou, ChinaHunan University of Science and Technology, School of Mechanical and Electrical Engineering, Xiangtan, ChinaaCentral South University, State Key Lab of Powder Metallurgy, Changsha, ChinaHf-N based alloys have been widely used and studied in the fields of electronic devices and cutting tools industry. A thermodynamic description of this system is essential for further materials development. By means of CALPHAD method, a thermodynamic modeling of the Hf-N system was carried out based on the available phase diagram data as well as thermodynamic property data. The Fcc phase is modeled as (Hf, Va)1(N, Va)1 to cover the composition range since the solubility of nitrogen in Fcc phase is reported up to about 52 at.%. A set of self-consistent thermodynamic parameters for the Hf-N system has been obtained. The computed phase diagrams and thermodynamic quantities using the present parameters agree well with the experimental data.http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391700055P.pdfCALPHADHf-Nphase diagramHafnium nitrides |
spellingShingle | Pang M. Peng Y. Zhou P. Du Y. Thermodynamic modeling of the Hf-N system Journal of Mining and Metallurgy. Section B: Metallurgy CALPHAD Hf-N phase diagram Hafnium nitrides |
title | Thermodynamic modeling of the Hf-N system |
title_full | Thermodynamic modeling of the Hf-N system |
title_fullStr | Thermodynamic modeling of the Hf-N system |
title_full_unstemmed | Thermodynamic modeling of the Hf-N system |
title_short | Thermodynamic modeling of the Hf-N system |
title_sort | thermodynamic modeling of the hf n system |
topic | CALPHAD Hf-N phase diagram Hafnium nitrides |
url | http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391700055P.pdf |
work_keys_str_mv | AT pangm thermodynamicmodelingofthehfnsystem AT pengy thermodynamicmodelingofthehfnsystem AT zhoup thermodynamicmodelingofthehfnsystem AT duy thermodynamicmodelingofthehfnsystem |