Thermodynamic modeling of the Hf-N system

Hf-N based alloys have been widely used and studied in the fields of electronic devices and cutting tools industry. A thermodynamic description of this system is essential for further materials development. By means of CALPHAD method, a thermodynamic modeling of the Hf-N system was carried out based...

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Main Authors: Pang M., Peng Y., Zhou P., Du Y.
Format: Article
Language:English
Published: University of Belgrade, Technical Faculty, Bor 2018-01-01
Series:Journal of Mining and Metallurgy. Section B: Metallurgy
Subjects:
Online Access:http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391700055P.pdf
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author Pang M.
Peng Y.
Zhou P.
Du Y.
author_facet Pang M.
Peng Y.
Zhou P.
Du Y.
author_sort Pang M.
collection DOAJ
description Hf-N based alloys have been widely used and studied in the fields of electronic devices and cutting tools industry. A thermodynamic description of this system is essential for further materials development. By means of CALPHAD method, a thermodynamic modeling of the Hf-N system was carried out based on the available phase diagram data as well as thermodynamic property data. The Fcc phase is modeled as (Hf, Va)1(N, Va)1 to cover the composition range since the solubility of nitrogen in Fcc phase is reported up to about 52 at.%. A set of self-consistent thermodynamic parameters for the Hf-N system has been obtained. The computed phase diagrams and thermodynamic quantities using the present parameters agree well with the experimental data.
format Article
id doaj-art-cdeeaadf678c49b7a0479a48fd5f7579
institution Kabale University
issn 1450-5339
2217-7175
language English
publishDate 2018-01-01
publisher University of Belgrade, Technical Faculty, Bor
record_format Article
series Journal of Mining and Metallurgy. Section B: Metallurgy
spelling doaj-art-cdeeaadf678c49b7a0479a48fd5f75792025-02-02T00:16:35ZengUniversity of Belgrade, Technical Faculty, BorJournal of Mining and Metallurgy. Section B: Metallurgy1450-53392217-71752018-01-0154111111810.2298/JMMB170520055P1450-53391700055PThermodynamic modeling of the Hf-N systemPang M.0Peng Y.1Zhou P.2Du Y.3Central South University, State Key Lab of Powder Metallurgy, Changsha, ChinaHunan University of Technology, College of Metallurgy and Material Engineering, Zhuzhou, ChinaHunan University of Science and Technology, School of Mechanical and Electrical Engineering, Xiangtan, ChinaaCentral South University, State Key Lab of Powder Metallurgy, Changsha, ChinaHf-N based alloys have been widely used and studied in the fields of electronic devices and cutting tools industry. A thermodynamic description of this system is essential for further materials development. By means of CALPHAD method, a thermodynamic modeling of the Hf-N system was carried out based on the available phase diagram data as well as thermodynamic property data. The Fcc phase is modeled as (Hf, Va)1(N, Va)1 to cover the composition range since the solubility of nitrogen in Fcc phase is reported up to about 52 at.%. A set of self-consistent thermodynamic parameters for the Hf-N system has been obtained. The computed phase diagrams and thermodynamic quantities using the present parameters agree well with the experimental data.http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391700055P.pdfCALPHADHf-Nphase diagramHafnium nitrides
spellingShingle Pang M.
Peng Y.
Zhou P.
Du Y.
Thermodynamic modeling of the Hf-N system
Journal of Mining and Metallurgy. Section B: Metallurgy
CALPHAD
Hf-N
phase diagram
Hafnium nitrides
title Thermodynamic modeling of the Hf-N system
title_full Thermodynamic modeling of the Hf-N system
title_fullStr Thermodynamic modeling of the Hf-N system
title_full_unstemmed Thermodynamic modeling of the Hf-N system
title_short Thermodynamic modeling of the Hf-N system
title_sort thermodynamic modeling of the hf n system
topic CALPHAD
Hf-N
phase diagram
Hafnium nitrides
url http://www.doiserbia.nb.rs/img/doi/1450-5339/2018/1450-53391700055P.pdf
work_keys_str_mv AT pangm thermodynamicmodelingofthehfnsystem
AT pengy thermodynamicmodelingofthehfnsystem
AT zhoup thermodynamicmodelingofthehfnsystem
AT duy thermodynamicmodelingofthehfnsystem