THE EXTENDED LAW OF CORRESPONDING - STATES AND THE INTERMOLECULAR POTENTIALS FOR Ar-Ar, Ar-Kr AND Kr-Kr

An inversion procedure is used to obtain from the extended principle of corresponding - states the pair interaction potentials for argon, krypton and its mixture over a tetnperature range from absolute zero to the onset of ionization. The experimentally-reduced viscosity collision integrals obtained...

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Bibliographic Details
Format: Article
Language:English
Published: University of Tehran 1995-06-01
Series:Journal of Sciences, Islamic Republic of Iran
Online Access:https://jsciences.ut.ac.ir/article_31415_a4656f099a4c16afeb228ff287b8dc32.pdf
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Summary:An inversion procedure is used to obtain from the extended principle of corresponding - states the pair interaction potentials for argon, krypton and its mixture over a tetnperature range from absolute zero to the onset of ionization. The experimentally-reduced viscosity collision integrals obtained from the corresponding - states correlation have been inverted directly to give the reduced-intermolecular potential energy curves corresponding to the collision integrals. These directly determined potentials are in good agreement with the potentials independently obtained from the molecular-beam scattering measurements, which were fitted by ESMSV for Ar-Ar and Kr-Kr and by SMSV for Ar-Kr
ISSN:1016-1104
2345-6914