Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide Derivative

The effect of coadsorption with deoxycholic acid (DCA) on the performance of dye-sensitized solar cell based on perylene monoimide derivative (PCA) as sensitizer and liquid electrolyte had been investigated. The current-voltage characteristics under illumination and incident photon to current effici...

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Main Authors: Ganesh D. Sharma, Rajnish Kurchania, Richard J. Ball, Mahesh S. Roy, John A. Mikroyannidis
Format: Article
Language:English
Published: Wiley 2012-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2012/983081
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author Ganesh D. Sharma
Rajnish Kurchania
Richard J. Ball
Mahesh S. Roy
John A. Mikroyannidis
author_facet Ganesh D. Sharma
Rajnish Kurchania
Richard J. Ball
Mahesh S. Roy
John A. Mikroyannidis
author_sort Ganesh D. Sharma
collection DOAJ
description The effect of coadsorption with deoxycholic acid (DCA) on the performance of dye-sensitized solar cell based on perylene monoimide derivative (PCA) as sensitizer and liquid electrolyte had been investigated. The current-voltage characteristics under illumination and incident photon to current efficiency (IPCE) spectra of the DSSCs showed that the coadsorption of DCA with the PCA dye results in a significant improvement in short circuit photocurrent and slight increase in the open circuit photovoltage, which lead to an overall power conversion efficiency. The enhancement of short circuit current was attributed to the increased electron injection efficiency from the excited state of PCA into the conduction band of TiO2 and charge collection efficiency. The current-voltage characteristics in dark indicates a positive shift in the conduction which also supports the enhancement in the photocurrent. The coadsorption with DCA suppressed charge recombination as indicated from the electrochemical impedance spectra and thus improved the open circuit photovoltage.
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institution Kabale University
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language English
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series International Journal of Photoenergy
spelling doaj-art-c952e5e80f584be6b0649274459f37922025-02-03T01:10:43ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2012-01-01201210.1155/2012/983081983081Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide DerivativeGanesh D. Sharma0Rajnish Kurchania1Richard J. Ball2Mahesh S. Roy3John A. Mikroyannidis4Molecular Electronic and Optoelectronic Device Laboratory, Physics Department, JNV University, Jodhpur 342005, IndiaDepartment of Physics, Maulana Azad National Institute of Technology (MANIT), Bhopal 462051, IndiaDepartment of Architecture and Civil Engineering, University of Bath, Bath BA2 7AY, UKDefence Laboratory, Jodhpur 342011, IndiaChemical Technology Laboratory, Department of Chemistry, University of Patras, 26500 Patras, GreeceThe effect of coadsorption with deoxycholic acid (DCA) on the performance of dye-sensitized solar cell based on perylene monoimide derivative (PCA) as sensitizer and liquid electrolyte had been investigated. The current-voltage characteristics under illumination and incident photon to current efficiency (IPCE) spectra of the DSSCs showed that the coadsorption of DCA with the PCA dye results in a significant improvement in short circuit photocurrent and slight increase in the open circuit photovoltage, which lead to an overall power conversion efficiency. The enhancement of short circuit current was attributed to the increased electron injection efficiency from the excited state of PCA into the conduction band of TiO2 and charge collection efficiency. The current-voltage characteristics in dark indicates a positive shift in the conduction which also supports the enhancement in the photocurrent. The coadsorption with DCA suppressed charge recombination as indicated from the electrochemical impedance spectra and thus improved the open circuit photovoltage.http://dx.doi.org/10.1155/2012/983081
spellingShingle Ganesh D. Sharma
Rajnish Kurchania
Richard J. Ball
Mahesh S. Roy
John A. Mikroyannidis
Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide Derivative
International Journal of Photoenergy
title Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide Derivative
title_full Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide Derivative
title_fullStr Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide Derivative
title_full_unstemmed Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide Derivative
title_short Effect of Deoxycholic Acid on the Performance of Liquid Electrolyte Dye-Sensitized Solar Cells Using a Perylene Monoimide Derivative
title_sort effect of deoxycholic acid on the performance of liquid electrolyte dye sensitized solar cells using a perylene monoimide derivative
url http://dx.doi.org/10.1155/2012/983081
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