High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic Application

This work summarizes progresses achieved in the physical chemistry aspects of the growth of anodic oxides under high-field conditions for the synthesis of semiconducting thin solid films and their implementation as photocatalytic materials. We discuss the scope and mechanisms for anodic oxide growth...

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Main Authors: Ronald Vargas, David Carvajal, Brunella Galavis, Alberto Maimone, Lorean Madriz, Benjamín R. Scharifker
Format: Article
Language:English
Published: Wiley 2019-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2019/2571906
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author Ronald Vargas
David Carvajal
Brunella Galavis
Alberto Maimone
Lorean Madriz
Benjamín R. Scharifker
author_facet Ronald Vargas
David Carvajal
Brunella Galavis
Alberto Maimone
Lorean Madriz
Benjamín R. Scharifker
author_sort Ronald Vargas
collection DOAJ
description This work summarizes progresses achieved in the physical chemistry aspects of the growth of anodic oxides under high-field conditions for the synthesis of semiconducting thin solid films and their implementation as photocatalytic materials. We discuss the scope and mechanisms for anodic oxide growth, describing the development of kinetic models and the correlations between theory and kinetic data, leading to fundamental information to characterize the primary processes occurring during the anodization of valve metals under high fields. The main features related to the widely used self-assembly of nanostructures by valve metal anodization are highlighted and briefly discussed. This is followed by general considerations of heterogeneous photocatalysis on these functional materials, considering the kinetics of the heterogeneous catalytic processes involved and the overall photoelectrochemical performance. High control of the characteristics of the materials obtained with the method described, combined with the possibility of electrochemically assisting photocatalysis, allows application of this technology to the treatment of wastewaters, energy conversion, and related fields.
format Article
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issn 1110-662X
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language English
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series International Journal of Photoenergy
spelling doaj-art-c7a76a81ebf14d19bf8154a02ca8646f2025-02-03T01:26:49ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2019-01-01201910.1155/2019/25719062571906High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic ApplicationRonald Vargas0David Carvajal1Brunella Galavis2Alberto Maimone3Lorean Madriz4Benjamín R. Scharifker5Departamento de Química, Universidad Simón Bolívar, Apartado 89000, Caracas 1080A, VenezuelaDepartamento de Química, Universidad Simón Bolívar, Apartado 89000, Caracas 1080A, VenezuelaDepartamento de Ciencia de los Materiales, Universidad Simón Bolívar, Apartado 89000, Caracas 1080A, VenezuelaDepartamento de Ciencia de los Materiales, Universidad Simón Bolívar, Apartado 89000, Caracas 1080A, VenezuelaDepartamento de Química, Universidad Simón Bolívar, Apartado 89000, Caracas 1080A, VenezuelaDepartamento de Química, Universidad Simón Bolívar, Apartado 89000, Caracas 1080A, VenezuelaThis work summarizes progresses achieved in the physical chemistry aspects of the growth of anodic oxides under high-field conditions for the synthesis of semiconducting thin solid films and their implementation as photocatalytic materials. We discuss the scope and mechanisms for anodic oxide growth, describing the development of kinetic models and the correlations between theory and kinetic data, leading to fundamental information to characterize the primary processes occurring during the anodization of valve metals under high fields. The main features related to the widely used self-assembly of nanostructures by valve metal anodization are highlighted and briefly discussed. This is followed by general considerations of heterogeneous photocatalysis on these functional materials, considering the kinetics of the heterogeneous catalytic processes involved and the overall photoelectrochemical performance. High control of the characteristics of the materials obtained with the method described, combined with the possibility of electrochemically assisting photocatalysis, allows application of this technology to the treatment of wastewaters, energy conversion, and related fields.http://dx.doi.org/10.1155/2019/2571906
spellingShingle Ronald Vargas
David Carvajal
Brunella Galavis
Alberto Maimone
Lorean Madriz
Benjamín R. Scharifker
High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic Application
International Journal of Photoenergy
title High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic Application
title_full High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic Application
title_fullStr High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic Application
title_full_unstemmed High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic Application
title_short High-Field Growth of Semiconducting Anodic Oxide Films on Metal Surfaces for Photocatalytic Application
title_sort high field growth of semiconducting anodic oxide films on metal surfaces for photocatalytic application
url http://dx.doi.org/10.1155/2019/2571906
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AT albertomaimone highfieldgrowthofsemiconductinganodicoxidefilmsonmetalsurfacesforphotocatalyticapplication
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