Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence Spectroscopy
An effective Hg2+-specific probe 1 was designed and prepared based on Phthalimido Gly modified rhodamine B. The sensing behavior of probe 1 was studied by UV-Vis and fluorescence spectroscopy. Probe 1 showed excellent high selectivity and sensitivity towards Hg2+ over commonly coexistent metal ions...
Saved in:
| Main Authors: | , , , , , |
|---|---|
| Format: | Article |
| Language: | English |
| Published: |
Wiley
2013-01-01
|
| Series: | Journal of Spectroscopy |
| Online Access: | http://dx.doi.org/10.1155/2013/878234 |
| Tags: |
Add Tag
No Tags, Be the first to tag this record!
|
| _version_ | 1832551425172832256 |
|---|---|
| author | Fanyong Yan Meng Wang Donglei Cao Ning Yang Bin Ma Li Chen |
| author_facet | Fanyong Yan Meng Wang Donglei Cao Ning Yang Bin Ma Li Chen |
| author_sort | Fanyong Yan |
| collection | DOAJ |
| description | An effective Hg2+-specific probe 1 was designed and prepared based on Phthalimido Gly modified rhodamine B. The sensing behavior of probe 1 was studied by UV-Vis and fluorescence spectroscopy. Probe 1 showed excellent high selectivity and sensitivity towards Hg2+ over commonly coexistent metal ions in neutral solution, which could be attributed to the Hg2+-triggered ring opening of the spirolactam of the rhodamine moiety and the formation of a 1 : 1 1-Hg2+ complex. The limit of detection (LOD) based on 3δblank/k was calculated to be 2.8 × 10−8 M, as well as an excellent linear relationship with the concentration of Hg2+ in the range from 0.1 × 10−6 to 1.0 × 10−6 mol/L (R2=0.98927). In addition, the effects of pH, coexisting metal ions, and the reversibility were investigated in detail. |
| format | Article |
| id | doaj-art-c747d9ffee574a8abe5f71e0a1e00dc6 |
| institution | Kabale University |
| issn | 2314-4920 2314-4939 |
| language | English |
| publishDate | 2013-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | Journal of Spectroscopy |
| spelling | doaj-art-c747d9ffee574a8abe5f71e0a1e00dc62025-02-03T06:01:30ZengWileyJournal of Spectroscopy2314-49202314-49392013-01-01201310.1155/2013/878234878234Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence SpectroscopyFanyong Yan0Meng Wang1Donglei Cao2Ning Yang3Bin Ma4Li Chen5State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Lab of Fiber Modification & Functional Fiber of Tianjin, Tianjin Polytechnic University, Tianjin 300387, ChinaState Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Lab of Fiber Modification & Functional Fiber of Tianjin, Tianjin Polytechnic University, Tianjin 300387, ChinaState Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Lab of Fiber Modification & Functional Fiber of Tianjin, Tianjin Polytechnic University, Tianjin 300387, ChinaState Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Lab of Fiber Modification & Functional Fiber of Tianjin, Tianjin Polytechnic University, Tianjin 300387, ChinaState Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Lab of Fiber Modification & Functional Fiber of Tianjin, Tianjin Polytechnic University, Tianjin 300387, ChinaState Key Laboratory of Hollow Fiber Membrane Materials and Processes, Key Lab of Fiber Modification & Functional Fiber of Tianjin, Tianjin Polytechnic University, Tianjin 300387, ChinaAn effective Hg2+-specific probe 1 was designed and prepared based on Phthalimido Gly modified rhodamine B. The sensing behavior of probe 1 was studied by UV-Vis and fluorescence spectroscopy. Probe 1 showed excellent high selectivity and sensitivity towards Hg2+ over commonly coexistent metal ions in neutral solution, which could be attributed to the Hg2+-triggered ring opening of the spirolactam of the rhodamine moiety and the formation of a 1 : 1 1-Hg2+ complex. The limit of detection (LOD) based on 3δblank/k was calculated to be 2.8 × 10−8 M, as well as an excellent linear relationship with the concentration of Hg2+ in the range from 0.1 × 10−6 to 1.0 × 10−6 mol/L (R2=0.98927). In addition, the effects of pH, coexisting metal ions, and the reversibility were investigated in detail.http://dx.doi.org/10.1155/2013/878234 |
| spellingShingle | Fanyong Yan Meng Wang Donglei Cao Ning Yang Bin Ma Li Chen Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence Spectroscopy Journal of Spectroscopy |
| title | Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence Spectroscopy |
| title_full | Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence Spectroscopy |
| title_fullStr | Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence Spectroscopy |
| title_full_unstemmed | Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence Spectroscopy |
| title_short | Recognition Preference of Rhodamine Derivative Bearing Phthalimido Gly for Hg2+ by UV-Vis and Fluorescence Spectroscopy |
| title_sort | recognition preference of rhodamine derivative bearing phthalimido gly for hg2 by uv vis and fluorescence spectroscopy |
| url | http://dx.doi.org/10.1155/2013/878234 |
| work_keys_str_mv | AT fanyongyan recognitionpreferenceofrhodaminederivativebearingphthalimidoglyforhg2byuvvisandfluorescencespectroscopy AT mengwang recognitionpreferenceofrhodaminederivativebearingphthalimidoglyforhg2byuvvisandfluorescencespectroscopy AT dongleicao recognitionpreferenceofrhodaminederivativebearingphthalimidoglyforhg2byuvvisandfluorescencespectroscopy AT ningyang recognitionpreferenceofrhodaminederivativebearingphthalimidoglyforhg2byuvvisandfluorescencespectroscopy AT binma recognitionpreferenceofrhodaminederivativebearingphthalimidoglyforhg2byuvvisandfluorescencespectroscopy AT lichen recognitionpreferenceofrhodaminederivativebearingphthalimidoglyforhg2byuvvisandfluorescencespectroscopy |