Platinum-Functionalized Hierarchically Structured Flower-like Nickel Ferrite Sheets for High-Performance Acetone Sensing

Acetone detection is crucial for non-invasive health monitoring and environmental safety, so there is an urgent demand to develop high-performance gas sensors. Here, platinum (Pt)-functionalized layered flower-like nickel ferrite (NiFe<sub>2</sub>O<sub>4</sub>) sheets were ef...

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Main Authors: Ziwen Yang, Zhen Sun, Yuhao Su, Caixuan Sun, Peishuo Wang, Shaobin Yang, Xueli Yang, Guofeng Pan
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Chemosensors
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Online Access:https://www.mdpi.com/2227-9040/13/7/234
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Summary:Acetone detection is crucial for non-invasive health monitoring and environmental safety, so there is an urgent demand to develop high-performance gas sensors. Here, platinum (Pt)-functionalized layered flower-like nickel ferrite (NiFe<sub>2</sub>O<sub>4</sub>) sheets were efficiently fabricated via facile hydrothermal synthesis and wet chemical reduction processes. When the Ni/Fe molar ratio is 1:1, the sensing material forms a Ni/NiO/NiFe<sub>2</sub>O<sub>4</sub> composite, with performance further optimized by tuning Pt loading. At 1.5% Pt mass fraction, the sensor shows a high acetone response (R<sub>g</sub>/R<sub>a</sub> = 58.33 at 100 ppm), a 100 ppb detection limit, fast response/recovery times (7/245 s at 100 ppm), and excellent selectivity. The enhancement in performance originates from the synergistic effect of the structure and Pt loading: the layered flower-like morphology facilitates gas diffusion and charge transport, while Pt nanoparticles serve as active sites to lower the activation energy of acetone redox reactions. This work presents a novel strategy for designing high-performance volatile organic compound (VOC) sensors by combining hierarchical nanostructured transition metal ferrites with noble metal modifications.
ISSN:2227-9040