Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells

Activated carbons (ACs) were prepared from apricot stone shells impregnated with H 3 PO 4 , followed by carbonization at 400–500°C. Fixed-bed removal of two dyestuffs, i.e. Direct Red 99 (DR) and Reactive Orange 11 (RO) was followed at constant bed height and flow rate. Several column characteristic...

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Main Authors: Laila B. Khalil, Badie S. Girgis
Format: Article
Language:English
Published: SAGE Publishing 1998-05-01
Series:Adsorption Science & Technology
Online Access:https://doi.org/10.1177/026361749801600507
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author Laila B. Khalil
Badie S. Girgis
author_facet Laila B. Khalil
Badie S. Girgis
author_sort Laila B. Khalil
collection DOAJ
description Activated carbons (ACs) were prepared from apricot stone shells impregnated with H 3 PO 4 , followed by carbonization at 400–500°C. Fixed-bed removal of two dyestuffs, i.e. Direct Red 99 (DR) and Reactive Orange 11 (RO) was followed at constant bed height and flow rate. Several column characteristics were evaluated from the breakthrough curves obtained including: the volume and loading at breakpoint, the height of the mass transfer zone, the bed service time, the time and loading at exhaustion, and the fractional bed loadings at various stages. The bed performance with RO was better than for DR, which was ascribed to a screening effect towards the larger DR molecules and to enhanced adsorption arising from the polyhalogenated nature of the RO molecule. The removal of colour was favoured as the porosity of the AC developed, being particularly related to its mesoporosity and total pore volume.
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institution Kabale University
issn 0263-6174
2048-4038
language English
publishDate 1998-05-01
publisher SAGE Publishing
record_format Article
series Adsorption Science & Technology
spelling doaj-art-c5794c9dc5ae48839e439b3f3f0b0c672025-02-03T10:07:33ZengSAGE PublishingAdsorption Science & Technology0263-61742048-40381998-05-011610.1177/026361749801600507Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone ShellsLaila B. KhalilBadie S. GirgisActivated carbons (ACs) were prepared from apricot stone shells impregnated with H 3 PO 4 , followed by carbonization at 400–500°C. Fixed-bed removal of two dyestuffs, i.e. Direct Red 99 (DR) and Reactive Orange 11 (RO) was followed at constant bed height and flow rate. Several column characteristics were evaluated from the breakthrough curves obtained including: the volume and loading at breakpoint, the height of the mass transfer zone, the bed service time, the time and loading at exhaustion, and the fractional bed loadings at various stages. The bed performance with RO was better than for DR, which was ascribed to a screening effect towards the larger DR molecules and to enhanced adsorption arising from the polyhalogenated nature of the RO molecule. The removal of colour was favoured as the porosity of the AC developed, being particularly related to its mesoporosity and total pore volume.https://doi.org/10.1177/026361749801600507
spellingShingle Laila B. Khalil
Badie S. Girgis
Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells
Adsorption Science & Technology
title Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells
title_full Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells
title_fullStr Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells
title_full_unstemmed Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells
title_short Column Removal of Some Dyestuffs by Activated Carbons Derived from Apricot Stone Shells
title_sort column removal of some dyestuffs by activated carbons derived from apricot stone shells
url https://doi.org/10.1177/026361749801600507
work_keys_str_mv AT lailabkhalil columnremovalofsomedyestuffsbyactivatedcarbonsderivedfromapricotstoneshells
AT badiesgirgis columnremovalofsomedyestuffsbyactivatedcarbonsderivedfromapricotstoneshells