Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate
Singh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °...
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| Main Authors: | , , , , |
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| Format: | Article |
| Language: | English |
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Wiley
2010-01-01
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| Series: | E-Journal of Chemistry |
| Online Access: | http://dx.doi.org/10.1155/2010/451523 |
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| author | Sangita Sharma Bijal Vyas Falguni Thakkar Ketan Patel J. J. Vora |
| author_facet | Sangita Sharma Bijal Vyas Falguni Thakkar Ketan Patel J. J. Vora |
| author_sort | Sangita Sharma |
| collection | DOAJ |
| description | Singh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °C and 35 °C. The rate of hydrolysis decreases with the increase of content of organic solvent at both temperatures. The size of transition state was found to be large as compared to the initial state. The b* was found to be 3.7693Å which is in agreement with the values obtained earlier. |
| format | Article |
| id | doaj-art-c4d2da8ada2b4c0f86a1f88d68cbdec7 |
| institution | Kabale University |
| issn | 0973-4945 2090-9810 |
| language | English |
| publishDate | 2010-01-01 |
| publisher | Wiley |
| record_format | Article |
| series | E-Journal of Chemistry |
| spelling | doaj-art-c4d2da8ada2b4c0f86a1f88d68cbdec72025-02-03T01:21:32ZengWileyE-Journal of Chemistry0973-49452090-98102010-01-01741170117310.1155/2010/451523Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl AcetateSangita Sharma0Bijal Vyas1Falguni Thakkar2Ketan Patel3J. J. Vora4Department of Chemistry, Hemchandracharya North Gujarat University, Patan-384265, Gujarat, IndiaDepartment of Chemistry, Hemchandracharya North Gujarat University, Patan-384265, Gujarat, IndiaDepartment of Chemistry, Hemchandracharya North Gujarat University, Patan-384265, Gujarat, IndiaDepartment of Chemistry, Hemchandracharya North Gujarat University, Patan-384265, Gujarat, IndiaDepartment of Chemistry, Hemchandracharya North Gujarat University, Patan-384265, Gujarat, IndiaSingh-Jha method is applied to calculate b* of Laidler-Landskroener equation, the distance of closed approach of solvent molecules to the activated complexes in alkaline hydrolysis of vinyl acetate. This method is applied to alkaline hydrolysis of vinyl acetate in water enriched ethanol between 30 °C and 35 °C. The rate of hydrolysis decreases with the increase of content of organic solvent at both temperatures. The size of transition state was found to be large as compared to the initial state. The b* was found to be 3.7693Å which is in agreement with the values obtained earlier.http://dx.doi.org/10.1155/2010/451523 |
| spellingShingle | Sangita Sharma Bijal Vyas Falguni Thakkar Ketan Patel J. J. Vora Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate E-Journal of Chemistry |
| title | Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate |
| title_full | Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate |
| title_fullStr | Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate |
| title_full_unstemmed | Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate |
| title_short | Application of Singh-Jha Equation in the Evaluation of b* Parameter of Laidler-Landskroener Equation in the Hydrolysis of Vinyl Acetate |
| title_sort | application of singh jha equation in the evaluation of b parameter of laidler landskroener equation in the hydrolysis of vinyl acetate |
| url | http://dx.doi.org/10.1155/2010/451523 |
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