Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVS

To examine the influence of Zr on the inclusions and microstructure of non-quenched and tempered F38MnVS steel, optical microscopy (OM), scanning electron microscopy (SEM), high-temperature laser confocal microscopy (HT-CLSM), transmission electron microscopy (TEM), and thermodynamic calculations am...

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Main Authors: Yucheng Wang, Yang Li, Zhouhua Jiang, Meng Sun, Shuai Ma, Yunqie Mao, Yanshuo Ma, Tianci Li, Dengyunfei Nie, Rui Yang
Format: Article
Language:English
Published: Elsevier 2025-03-01
Series:Journal of Materials Research and Technology
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Online Access:http://www.sciencedirect.com/science/article/pii/S2238785425001334
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author Yucheng Wang
Yang Li
Zhouhua Jiang
Meng Sun
Shuai Ma
Yunqie Mao
Yanshuo Ma
Tianci Li
Dengyunfei Nie
Rui Yang
author_facet Yucheng Wang
Yang Li
Zhouhua Jiang
Meng Sun
Shuai Ma
Yunqie Mao
Yanshuo Ma
Tianci Li
Dengyunfei Nie
Rui Yang
author_sort Yucheng Wang
collection DOAJ
description To examine the influence of Zr on the inclusions and microstructure of non-quenched and tempered F38MnVS steel, optical microscopy (OM), scanning electron microscopy (SEM), high-temperature laser confocal microscopy (HT-CLSM), transmission electron microscopy (TEM), and thermodynamic calculations among others are utilized. The obtained results reveal that adding Zr could alter the inclusions from Al2O3 to ZrO2, and ZrN appears with the increase of Zr content. Additionally, 220 ppm Zr exhibits the best impact on the inclusion size, reducing the average diameter of the inclusions from 5.04 μm to 2.87 μm. At the same time, the addition of Zr causes the austenite grain size to decrease and more intragranular ferrite appears. By appropriately evaluating the Zener pinning force, the Zener pinning force of the experimental group with a Zr content of 220 ppm is obtained as 0.034 J/mol, which possesses a more pronounced pinning effect on the austenite grain boundaries compared with 0 ppm Zr. By evaluating the mismatch degree, the mismatch degree between ZrO2 and α-Fe is predicted to be 6.9%, so it can be utilized as an effective heterogeneous nucleation core to induce α-Fe nucleation. In conjunction with the manganese-depleted zone theory, both of them jointly promote the nucleation of α-Fe. The findings of this study can serve as a fairly solid basis for using Zr treatment in the preparation of non-quenched and tempered steel for automotive applications.
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issn 2238-7854
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series Journal of Materials Research and Technology
spelling doaj-art-c404e2120d5e49c1aad93e369c9014ee2025-01-28T04:14:40ZengElsevierJournal of Materials Research and Technology2238-78542025-03-013520752086Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVSYucheng Wang0Yang Li1Zhouhua Jiang2Meng Sun3Shuai Ma4Yunqie Mao5Yanshuo Ma6Tianci Li7Dengyunfei Nie8Rui Yang9School of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaCorresponding author.; School of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaSchool of Metallurgy, Northeastern University, Shenyang, 110819, Liaoning, ChinaTo examine the influence of Zr on the inclusions and microstructure of non-quenched and tempered F38MnVS steel, optical microscopy (OM), scanning electron microscopy (SEM), high-temperature laser confocal microscopy (HT-CLSM), transmission electron microscopy (TEM), and thermodynamic calculations among others are utilized. The obtained results reveal that adding Zr could alter the inclusions from Al2O3 to ZrO2, and ZrN appears with the increase of Zr content. Additionally, 220 ppm Zr exhibits the best impact on the inclusion size, reducing the average diameter of the inclusions from 5.04 μm to 2.87 μm. At the same time, the addition of Zr causes the austenite grain size to decrease and more intragranular ferrite appears. By appropriately evaluating the Zener pinning force, the Zener pinning force of the experimental group with a Zr content of 220 ppm is obtained as 0.034 J/mol, which possesses a more pronounced pinning effect on the austenite grain boundaries compared with 0 ppm Zr. By evaluating the mismatch degree, the mismatch degree between ZrO2 and α-Fe is predicted to be 6.9%, so it can be utilized as an effective heterogeneous nucleation core to induce α-Fe nucleation. In conjunction with the manganese-depleted zone theory, both of them jointly promote the nucleation of α-Fe. The findings of this study can serve as a fairly solid basis for using Zr treatment in the preparation of non-quenched and tempered steel for automotive applications.http://www.sciencedirect.com/science/article/pii/S2238785425001334ZirconiumNon-quenched and tempered steelInclusionsMicrostructureMismatch degree
spellingShingle Yucheng Wang
Yang Li
Zhouhua Jiang
Meng Sun
Shuai Ma
Yunqie Mao
Yanshuo Ma
Tianci Li
Dengyunfei Nie
Rui Yang
Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVS
Journal of Materials Research and Technology
Zirconium
Non-quenched and tempered steel
Inclusions
Microstructure
Mismatch degree
title Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVS
title_full Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVS
title_fullStr Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVS
title_full_unstemmed Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVS
title_short Effect of Zr on inclusions and microstructure of non-quenched and tempered steel F38MnVS
title_sort effect of zr on inclusions and microstructure of non quenched and tempered steel f38mnvs
topic Zirconium
Non-quenched and tempered steel
Inclusions
Microstructure
Mismatch degree
url http://www.sciencedirect.com/science/article/pii/S2238785425001334
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