An Efficient Synthesis of a Variety of Substituted Pyridine-3-Thiols

A practical and convenient method for the synthesis of pyridine-3-thiols using substituted 3-iodopyridines as starting compounds has been developed. Based on the use of thiobenzoic acid as a sulfur donor in a two-step procedure, this approach made it possible to synthesize a number of pyridine-3-thi...

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Bibliographic Details
Main Authors: Oleksandr V. Borysov, Dmytro P. Bohdan
Format: Article
Language:English
Published: National University of Pharmacy (Kharkiv) 2025-04-01
Series:Журнал органічної та фармацевтичної хімії
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Online Access:https://ophcj.nuph.edu.ua/article/view/324523
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Summary:A practical and convenient method for the synthesis of pyridine-3-thiols using substituted 3-iodopyridines as starting compounds has been developed. Based on the use of thiobenzoic acid as a sulfur donor in a two-step procedure, this approach made it possible to synthesize a number of pyridine-3-thiols with F, Cl, Br, CH3, OCH3 substituents at various positions of the pyridine ring. The procedure presented gives high yields of the target products with a purity of 95% and is suitable for synthesis in tens of grams.
ISSN:2308-8303
2518-1548