Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A Review

Nut by-products, particularly shells, are a globally abundant agricultural residue. Their widespread accumulation poses a serious environmental challenge. However, nut shells are of great interest due to their inherent lignocellulosic composition. For instance, they are rich in cellulose, a high-val...

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Main Authors: Andrea Están, Mónica Umaña, Valeria S. Eim, Gabriela Clemente, Susana Simal
Format: Article
Language:English
Published: MDPI AG 2025-06-01
Series:Molecules
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Online Access:https://www.mdpi.com/1420-3049/30/12/2486
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author Andrea Están
Mónica Umaña
Valeria S. Eim
Gabriela Clemente
Susana Simal
author_facet Andrea Están
Mónica Umaña
Valeria S. Eim
Gabriela Clemente
Susana Simal
author_sort Andrea Están
collection DOAJ
description Nut by-products, particularly shells, are a globally abundant agricultural residue. Their widespread accumulation poses a serious environmental challenge. However, nut shells are of great interest due to their inherent lignocellulosic composition. For instance, they are rich in cellulose, a high-value biopolymer widely used in the production of bio-based materials. Therefore, this review critically analyses conventional and novel pre-treatment strategies for the extraction of cellulose from nut shells, emphasising the importance of optimising valorisation routes to minimise ecological impact. Various techniques—ranging from alkaline treatments to emerging approaches such as deep eutectic solvents and hydrothermal methods—have been examined and compared. The findings in cellulose purification through different strategies reveal that, while some methods are promising, others remain underexplored. Emphasis is placed on the necessity of comprehending the specific structural and chemical characteristics of each type of nut shell; as such, knowledge is fundamental to understanding the efficiency of the applied methods. This review highlights the growing interest in the valorisation of nut shell by-products as promising lignocellulosic resources of significant utility. Therefore, it also reveals the need for further research, focusing on process scalability, cost-efficiency, and environmental impact. Advancing in these areas is essential to enable the transition of nut shells from waste to a highly valuable resource.
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spelling doaj-art-c1f54ad6d5d3473da2b527d3dcad47482025-08-20T03:29:49ZengMDPI AGMolecules1420-30492025-06-013012248610.3390/molecules30122486Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A ReviewAndrea Están0Mónica Umaña1Valeria S. Eim2Gabriela Clemente3Susana Simal4Department of Chemistry, University of the Balearic Islands, Ctra. Valldemossa, km. 7.5, 07122 Palma de Mallorca, SpainDepartment of Chemistry, University of the Balearic Islands, Ctra. Valldemossa, km. 7.5, 07122 Palma de Mallorca, SpainDepartment of Chemistry, University of the Balearic Islands, Ctra. Valldemossa, km. 7.5, 07122 Palma de Mallorca, SpainAnalysis and Simulation of Agro-Food Processes Group, University Institute of Food Engineering, FoodUPV, Universitat Politècnica de València, Camino de Vera s/n, 46022 Valencia, SpainDepartment of Chemistry, University of the Balearic Islands, Ctra. Valldemossa, km. 7.5, 07122 Palma de Mallorca, SpainNut by-products, particularly shells, are a globally abundant agricultural residue. Their widespread accumulation poses a serious environmental challenge. However, nut shells are of great interest due to their inherent lignocellulosic composition. For instance, they are rich in cellulose, a high-value biopolymer widely used in the production of bio-based materials. Therefore, this review critically analyses conventional and novel pre-treatment strategies for the extraction of cellulose from nut shells, emphasising the importance of optimising valorisation routes to minimise ecological impact. Various techniques—ranging from alkaline treatments to emerging approaches such as deep eutectic solvents and hydrothermal methods—have been examined and compared. The findings in cellulose purification through different strategies reveal that, while some methods are promising, others remain underexplored. Emphasis is placed on the necessity of comprehending the specific structural and chemical characteristics of each type of nut shell; as such, knowledge is fundamental to understanding the efficiency of the applied methods. This review highlights the growing interest in the valorisation of nut shell by-products as promising lignocellulosic resources of significant utility. Therefore, it also reveals the need for further research, focusing on process scalability, cost-efficiency, and environmental impact. Advancing in these areas is essential to enable the transition of nut shells from waste to a highly valuable resource.https://www.mdpi.com/1420-3049/30/12/2486lignocellulosenut shellsnut by-productscelluloselignincellulose extraction
spellingShingle Andrea Están
Mónica Umaña
Valeria S. Eim
Gabriela Clemente
Susana Simal
Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A Review
Molecules
lignocellulose
nut shells
nut by-products
cellulose
lignin
cellulose extraction
title Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A Review
title_full Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A Review
title_fullStr Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A Review
title_full_unstemmed Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A Review
title_short Conventional and Novel Strategies for Cellulose Isolation from Nut Shells: A Review
title_sort conventional and novel strategies for cellulose isolation from nut shells a review
topic lignocellulose
nut shells
nut by-products
cellulose
lignin
cellulose extraction
url https://www.mdpi.com/1420-3049/30/12/2486
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