Characterization of Extruded Poly(lactic acid)/Pecan Nutshell Biocomposites

Pecan nutshells are a solid form of waste obtained from the pecan nut production and they have been explored as an inexpensive filler for incorporation by melt blending into the poly(lactic acid) (PLA) matrix. The pecan nutshells contain polyphenols, proteins, tannins, sugars, and lipids; some of th...

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Main Authors: C. R. Álvarez-Chávez, D. L. Sánchez-Acosta, J. C. Encinas-Encinas, J. Esquer, P. Quintana-Owen, T. J. Madera-Santana
Format: Article
Language:English
Published: Wiley 2017-01-01
Series:International Journal of Polymer Science
Online Access:http://dx.doi.org/10.1155/2017/3264098
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author C. R. Álvarez-Chávez
D. L. Sánchez-Acosta
J. C. Encinas-Encinas
J. Esquer
P. Quintana-Owen
T. J. Madera-Santana
author_facet C. R. Álvarez-Chávez
D. L. Sánchez-Acosta
J. C. Encinas-Encinas
J. Esquer
P. Quintana-Owen
T. J. Madera-Santana
author_sort C. R. Álvarez-Chávez
collection DOAJ
description Pecan nutshells are a solid form of waste obtained from the pecan nut production and they have been explored as an inexpensive filler for incorporation by melt blending into the poly(lactic acid) (PLA) matrix. The pecan nutshells contain polyphenols, proteins, tannins, sugars, and lipids; some of these components must be released in order to improve adhesion with a polymeric matrix. The physicochemical characterization of the extruded biocomposites of pecan nutshell powder (PNSP) at 0, 5, and 7.5% wt. with two treatments (untreated and defatted) into PLA is presented in this work. The incorporation of PNSP into the PLA matrix caused a variation in color and density and increased the water absorption. However, some mechanical and thermal parameters of the biocomposites showed a significant decrease. The morphological analysis showed good dispersion and adhesion of the PNSP to the PLA matrix. Based on the results of the characterization, biocomposites formulated with defatted PNSP have a potential to be used as sustainable fillers in PLA biocomposites. These biocomposites have a potential application as food containers, packaging trays, or disposable items.
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institution Kabale University
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publishDate 2017-01-01
publisher Wiley
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series International Journal of Polymer Science
spelling doaj-art-c11027defade400a81efae9e35dbb4982025-02-03T01:11:38ZengWileyInternational Journal of Polymer Science1687-94221687-94302017-01-01201710.1155/2017/32640983264098Characterization of Extruded Poly(lactic acid)/Pecan Nutshell BiocompositesC. R. Álvarez-Chávez0D. L. Sánchez-Acosta1J. C. Encinas-Encinas2J. Esquer3P. Quintana-Owen4T. J. Madera-Santana5Chemical and Biological Sciences Department, University of Sonora, Rosales y Luis Encinas, Col. Centro, 83000 Hermosillo, SON, MexicoSustainability Graduate Program, Industrial Engineering Department, University of Sonora, Hermosillo, SON, MexicoPolymers and Materials Research Department, University of Sonora, Hermosillo, SON, MexicoSustainability Graduate Program, Industrial Engineering Department, University of Sonora, Hermosillo, SON, MexicoResearch Center and Advanced Studies of IPN, Mérida Unit, Ant. Carr. a Progreso Km. 6, Apdo. Postal 73, Cordemex, 97310 Mérida, YUC, MexicoResearch Center for Food and Development, CTAOV, Hermosillo, SON, MexicoPecan nutshells are a solid form of waste obtained from the pecan nut production and they have been explored as an inexpensive filler for incorporation by melt blending into the poly(lactic acid) (PLA) matrix. The pecan nutshells contain polyphenols, proteins, tannins, sugars, and lipids; some of these components must be released in order to improve adhesion with a polymeric matrix. The physicochemical characterization of the extruded biocomposites of pecan nutshell powder (PNSP) at 0, 5, and 7.5% wt. with two treatments (untreated and defatted) into PLA is presented in this work. The incorporation of PNSP into the PLA matrix caused a variation in color and density and increased the water absorption. However, some mechanical and thermal parameters of the biocomposites showed a significant decrease. The morphological analysis showed good dispersion and adhesion of the PNSP to the PLA matrix. Based on the results of the characterization, biocomposites formulated with defatted PNSP have a potential to be used as sustainable fillers in PLA biocomposites. These biocomposites have a potential application as food containers, packaging trays, or disposable items.http://dx.doi.org/10.1155/2017/3264098
spellingShingle C. R. Álvarez-Chávez
D. L. Sánchez-Acosta
J. C. Encinas-Encinas
J. Esquer
P. Quintana-Owen
T. J. Madera-Santana
Characterization of Extruded Poly(lactic acid)/Pecan Nutshell Biocomposites
International Journal of Polymer Science
title Characterization of Extruded Poly(lactic acid)/Pecan Nutshell Biocomposites
title_full Characterization of Extruded Poly(lactic acid)/Pecan Nutshell Biocomposites
title_fullStr Characterization of Extruded Poly(lactic acid)/Pecan Nutshell Biocomposites
title_full_unstemmed Characterization of Extruded Poly(lactic acid)/Pecan Nutshell Biocomposites
title_short Characterization of Extruded Poly(lactic acid)/Pecan Nutshell Biocomposites
title_sort characterization of extruded poly lactic acid pecan nutshell biocomposites
url http://dx.doi.org/10.1155/2017/3264098
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