Laser Enhanced Hydrogen Passivation of Silicon Wafers

The application of lasers to enable advanced hydrogenation processes with charge state control is explored. Localised hydrogenation is realised through the use of lasers to achieve localised illumination and heating of the silicon material and hence spatially control the hydrogenation process. Impr...

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Main Authors: Lihui Song, Alison Wenham, Sisi Wang, Phillip Hamer, Mohammad Shakil Ahmmed, Brett Hallam, Ly Mai, Malcolm Abbott, Evatt R. Hawkes, CheeMun Chong, Stuart Wenham
Format: Article
Language:English
Published: Wiley 2015-01-01
Series:International Journal of Photoenergy
Online Access:http://dx.doi.org/10.1155/2015/193892
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author Lihui Song
Alison Wenham
Sisi Wang
Phillip Hamer
Mohammad Shakil Ahmmed
Brett Hallam
Ly Mai
Malcolm Abbott
Evatt R. Hawkes
CheeMun Chong
Stuart Wenham
author_facet Lihui Song
Alison Wenham
Sisi Wang
Phillip Hamer
Mohammad Shakil Ahmmed
Brett Hallam
Ly Mai
Malcolm Abbott
Evatt R. Hawkes
CheeMun Chong
Stuart Wenham
author_sort Lihui Song
collection DOAJ
description The application of lasers to enable advanced hydrogenation processes with charge state control is explored. Localised hydrogenation is realised through the use of lasers to achieve localised illumination and heating of the silicon material and hence spatially control the hydrogenation process. Improvements in minority carrier lifetime are confirmed in the laser hydrogenated regions using photoluminescence (PL) imaging. However with inappropriate laser settings a localised reduction in minority carrier lifetime can result. It is observed that high illumination intensities and rapid cooling are beneficial for achieving improvements in minority carrier lifetimes through laser hydrogenation. The laser hydrogenation process is then applied to finished screen-printed solar cells fabricated on seeded-cast quasi monocrystalline silicon wafers. The passivation of dislocation clusters is observed with clear improvements in quantum efficiency, open circuit voltage, and short circuit current density, leading to an improvement in efficiency of 0.6% absolute.
format Article
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institution Kabale University
issn 1110-662X
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language English
publishDate 2015-01-01
publisher Wiley
record_format Article
series International Journal of Photoenergy
spelling doaj-art-c0f7da7c8e4d43b8a9eb30d98eadf2b02025-02-03T01:01:04ZengWileyInternational Journal of Photoenergy1110-662X1687-529X2015-01-01201510.1155/2015/193892193892Laser Enhanced Hydrogen Passivation of Silicon WafersLihui Song0Alison Wenham1Sisi Wang2Phillip Hamer3Mohammad Shakil Ahmmed4Brett Hallam5Ly Mai6Malcolm Abbott7Evatt R. Hawkes8CheeMun Chong9Stuart Wenham10School of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Mechanical and Manufacturing Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaSchool of Photovoltaic and Renewable Energy Engineering, UNSW, Sydney, NSW 2052, AustraliaThe application of lasers to enable advanced hydrogenation processes with charge state control is explored. Localised hydrogenation is realised through the use of lasers to achieve localised illumination and heating of the silicon material and hence spatially control the hydrogenation process. Improvements in minority carrier lifetime are confirmed in the laser hydrogenated regions using photoluminescence (PL) imaging. However with inappropriate laser settings a localised reduction in minority carrier lifetime can result. It is observed that high illumination intensities and rapid cooling are beneficial for achieving improvements in minority carrier lifetimes through laser hydrogenation. The laser hydrogenation process is then applied to finished screen-printed solar cells fabricated on seeded-cast quasi monocrystalline silicon wafers. The passivation of dislocation clusters is observed with clear improvements in quantum efficiency, open circuit voltage, and short circuit current density, leading to an improvement in efficiency of 0.6% absolute.http://dx.doi.org/10.1155/2015/193892
spellingShingle Lihui Song
Alison Wenham
Sisi Wang
Phillip Hamer
Mohammad Shakil Ahmmed
Brett Hallam
Ly Mai
Malcolm Abbott
Evatt R. Hawkes
CheeMun Chong
Stuart Wenham
Laser Enhanced Hydrogen Passivation of Silicon Wafers
International Journal of Photoenergy
title Laser Enhanced Hydrogen Passivation of Silicon Wafers
title_full Laser Enhanced Hydrogen Passivation of Silicon Wafers
title_fullStr Laser Enhanced Hydrogen Passivation of Silicon Wafers
title_full_unstemmed Laser Enhanced Hydrogen Passivation of Silicon Wafers
title_short Laser Enhanced Hydrogen Passivation of Silicon Wafers
title_sort laser enhanced hydrogen passivation of silicon wafers
url http://dx.doi.org/10.1155/2015/193892
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