Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 System

An efficient and rapid method have been found using benzyltriphenylphosphonium dichromate (PhCH2PPh3)2Cr2O7 as an oxidant along with molecular iodine for the iodination of aromatic compounds. Iodination of a wide variety of alkyl benzenes were done under dichloromethane solvent system and high yield...

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Main Authors: R. Sathiyapriya, R. Joel Karunakaran
Format: Article
Language:English
Published: Wiley 2009-01-01
Series:E-Journal of Chemistry
Online Access:http://dx.doi.org/10.1155/2009/928040
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author R. Sathiyapriya
R. Joel Karunakaran
author_facet R. Sathiyapriya
R. Joel Karunakaran
author_sort R. Sathiyapriya
collection DOAJ
description An efficient and rapid method have been found using benzyltriphenylphosphonium dichromate (PhCH2PPh3)2Cr2O7 as an oxidant along with molecular iodine for the iodination of aromatic compounds. Iodination of a wide variety of alkyl benzenes were done under dichloromethane solvent system and high yields of iodo products were obtained
format Article
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institution Kabale University
issn 0973-4945
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publishDate 2009-01-01
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series E-Journal of Chemistry
spelling doaj-art-c0c177874dc3413382a442103227ef3b2025-02-03T06:00:34ZengWileyE-Journal of Chemistry0973-49452090-98102009-01-01641164116610.1155/2009/928040Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 SystemR. Sathiyapriya0R. Joel Karunakaran1Department of Chemistry, Madras Christian College, Tambaram, Chennai-600 059, Tamilnadu, IndiaDepartment of Chemistry, Madras Christian College, Tambaram, Chennai-600 059, Tamilnadu, IndiaAn efficient and rapid method have been found using benzyltriphenylphosphonium dichromate (PhCH2PPh3)2Cr2O7 as an oxidant along with molecular iodine for the iodination of aromatic compounds. Iodination of a wide variety of alkyl benzenes were done under dichloromethane solvent system and high yields of iodo products were obtainedhttp://dx.doi.org/10.1155/2009/928040
spellingShingle R. Sathiyapriya
R. Joel Karunakaran
Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 System
E-Journal of Chemistry
title Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 System
title_full Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 System
title_fullStr Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 System
title_full_unstemmed Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 System
title_short Iodination of Alkylbenzenes using Benzyltriphenylphosphonium Dichromate / I2 System
title_sort iodination of alkylbenzenes using benzyltriphenylphosphonium dichromate i2 system
url http://dx.doi.org/10.1155/2009/928040
work_keys_str_mv AT rsathiyapriya iodinationofalkylbenzenesusingbenzyltriphenylphosphoniumdichromatei2system
AT rjoelkarunakaran iodinationofalkylbenzenesusingbenzyltriphenylphosphoniumdichromatei2system