Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-Filters

In the quest to unveil alternative plasmonic elements overcoming noble metals for selected applications in photonics, we investigate, by numerical simulations, the near ultraviolet (UV)-to-near infrared optical response of solid and liquid Bi nanospheres embedded in a dielectric matrix. We also dete...

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Main Authors: Alexander Cuadrado, Johann Toudert, Rosalia Serna
Format: Article
Language:English
Published: IEEE 2016-01-01
Series:IEEE Photonics Journal
Subjects:
Online Access:https://ieeexplore.ieee.org/document/7482671/
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author Alexander Cuadrado
Johann Toudert
Rosalia Serna
author_facet Alexander Cuadrado
Johann Toudert
Rosalia Serna
author_sort Alexander Cuadrado
collection DOAJ
description In the quest to unveil alternative plasmonic elements overcoming noble metals for selected applications in photonics, we investigate, by numerical simulations, the near ultraviolet (UV)-to-near infrared optical response of solid and liquid Bi nanospheres embedded in a dielectric matrix. We also determine the resulting transmission contrast upon reversible solid–liquid phase transition to evaluate their potential for switchable optical filtering. The optical response of the solid (liquid) Bi nanospheres is ruled by localized polaritonic (plasmonic) resonances tunable by controlling the diameter. For a selected diameter between 20 and 50 nm, both solid and liquid nanospheres present a dipolar resonance, inducing a strong peak extinction in the near UV, however, at different photon energies. This enables a high transmission contrast at selected near UV photon energies. It is estimated that a 2-D assembly of 30-nm solid Bi nanospheres with a surface coverage of 32% will almost totally render extinct (transmission of 2%) a near UV 3.45-eV (359 nm) light beam, whereas upon phase transition, the resulting liquid Bi nanospheres will show a transmission of 30%. This paper is appealing for the fabrication of locally reconfigurable optical metamaterials for integrated switchable near-UV optics.
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spelling doaj-art-c0a3051af6c346e6867cefb1c3809e9b2025-08-20T03:32:32ZengIEEEIEEE Photonics Journal1943-06552016-01-018311110.1109/JPHOT.2016.25747777482671Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-FiltersAlexander Cuadrado0Johann Toudert1Rosalia Serna2 Laser Processing Group, Instituto de Óptica, CSIC, Madrid, Spain Laser Processing Group, Instituto de Óptica, CSIC, Madrid, Spain Laser Processing Group, Instituto de Óptica, CSIC, Madrid, SpainIn the quest to unveil alternative plasmonic elements overcoming noble metals for selected applications in photonics, we investigate, by numerical simulations, the near ultraviolet (UV)-to-near infrared optical response of solid and liquid Bi nanospheres embedded in a dielectric matrix. We also determine the resulting transmission contrast upon reversible solid–liquid phase transition to evaluate their potential for switchable optical filtering. The optical response of the solid (liquid) Bi nanospheres is ruled by localized polaritonic (plasmonic) resonances tunable by controlling the diameter. For a selected diameter between 20 and 50 nm, both solid and liquid nanospheres present a dipolar resonance, inducing a strong peak extinction in the near UV, however, at different photon energies. This enables a high transmission contrast at selected near UV photon energies. It is estimated that a 2-D assembly of 30-nm solid Bi nanospheres with a surface coverage of 32% will almost totally render extinct (transmission of 2%) a near UV 3.45-eV (359 nm) light beam, whereas upon phase transition, the resulting liquid Bi nanospheres will show a transmission of 30%. This paper is appealing for the fabrication of locally reconfigurable optical metamaterials for integrated switchable near-UV optics.https://ieeexplore.ieee.org/document/7482671/BismuthPlasmon ResonancePhase TransitionReconfigurable MetamaterialsUltraviolet
spellingShingle Alexander Cuadrado
Johann Toudert
Rosalia Serna
Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-Filters
IEEE Photonics Journal
Bismuth
Plasmon Resonance
Phase Transition
Reconfigurable Metamaterials
Ultraviolet
title Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-Filters
title_full Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-Filters
title_fullStr Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-Filters
title_full_unstemmed Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-Filters
title_short Polaritonic-to-Plasmonic Transition in Optically Resonant Bismuth Nanospheres for High-Contrast Switchable Ultraviolet Meta-Filters
title_sort polaritonic to plasmonic transition in optically resonant bismuth nanospheres for high contrast switchable ultraviolet meta filters
topic Bismuth
Plasmon Resonance
Phase Transition
Reconfigurable Metamaterials
Ultraviolet
url https://ieeexplore.ieee.org/document/7482671/
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AT rosaliaserna polaritonictoplasmonictransitioninopticallyresonantbismuthnanospheresforhighcontrastswitchableultravioletmetafilters